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A thorough understanding of the electronic structure is a necessary first step for the design of nanoelectronics, chemical/bio-sensors, electrocatalysts, and nanoplasmonics using graphene. As such, theoretical spectroscopic techniques to…

Materials Science · Physics 2015-03-04 Duncan J. Mowbray

Spectroscopies that probe electronic excitations from core levels into unoccupied orbitals, such as X-ray absorption spectroscopy and electron energy loss spectroscopy, are widely used to gain insight into the electronic and chemical…

Materials Science · Physics 2022-09-12 Marcus Annegarn , Juhan Matthias Kahk , Johannes Lischner

The real-time electronic dynamics on material surfaces is critically important to a variety of applications. However, their simulations have remained challenging for conventional methods such as the time-dependent density-functional theory…

Chemical Physics · Physics 2015-06-16 Rulin Wang , Dong Hou , Xiao Zheng

Time-dependent density-functional theory (TDDFT) is widely used to describe electronic excitations in complex finite systems with large numbers of atoms, such as biomolecules and nanocrystals. The first part of this paper will give a simple…

Materials Science · Physics 2008-08-15 C. A. Ullrich , V. Turkowski

The engineering of the optical response of materials is a paradigm that demands microscopic-level accuracy and reliable predictive theoretical tools. Here we compare and contrast the dispersive permittivity tensor, using both a low-energy…

Materials Science · Physics 2021-09-29 Mohammad Alidoust , Erlend E. Isachsen , Klaus Halterman , Jaakko Akola

We develop a formalism to describe electron ejections from graphene-like targets by dark matter (DM) scattering for general forms of scalar and spin 1/2 DM-electron interactions and compare their applicability and accuracy within the…

High Energy Physics - Phenomenology · Physics 2023-03-29 Riccardo Catena , Timon Emken , Marek Matas , Nicola A. Spaldin , Einar Urdshals

We present a novel theoretical approach to simulate spin, time and angular-resolved photoelectron spectroscopy (ARPES) from first principles that is applicable to surfaces, thin films, few layer systems, and low-dimensional nanostructures.…

Computational Physics · Physics 2017-01-03 Umberto De Giovannini , Hannes Hübener , Angel Rubio

We show that time-dependent density functional theory (TDDFT) is applicable to coherent optical phonon generation by intense laser pulses in solids. The two mechanisms invoked in phenomenological theories, namely impulsively stimulated…

Materials Science · Physics 2010-06-22 Y. Shinohara , Y. Kawashita , K. Yabana , J. -I. Iwata , T. Obote , G. F. Bertsch

We review different computational methods for the calculation of photoelectron spectra and angular distributions of atoms and molecules when excited by laser pulses using time-dependent density-functional theory (TDDFT) that are suitable…

Chemical Physics · Physics 2017-03-28 Philipp Wopperer , Umberto De Giovannini , Angel Rubio

We outline a Kohn-Sham-Dirac density-functional-theory (DFT) scheme for graphene sheets that treats slowly-varying inhomogeneous external potentials and electron-electron interactions on an equal footing. The theory is able to account for…

Strongly Correlated Electrons · Physics 2008-09-23 Marco Polini , Andrea Tomadin , Reza Asgari , A. H. MacDonald

This paper reviews the theoretical work undertaken using density functional theory (DFT) to explore graphene's interactions with its surroundings. We look at the impact of substrates, gate dielectrics and edge effects on the properties of…

Mesoscale and Nanoscale Physics · Physics 2012-07-31 Priyamvada Jadaun , Bhagawan R. Sahu , Leonard F. Register , Sanjay K. Banerjee

Density functional theory (DFT) and many body perturbation theory at the G$_0$W$_0$ level are employed to study the electronic properties of polythiophene (PT) adsorbed on graphene surface. Analysis of charge density difference shows the…

Mesoscale and Nanoscale Physics · Physics 2017-09-07 F. Marsusi , I. A. Fedorov , S. Gerivani

In this paper, we calculated the dielectric function, the loss function, the magnetoplasmon dispersion relation and the temperature-induced transitions for graphene in a uniform perpendicular magnetic field B. The calculations were…

Mesoscale and Nanoscale Physics · Physics 2014-04-14 Jhao-Ying Wu , Szu-Chao Chen , Oleksiy Roslyak , Godfrey Gumbs , Ming-Fa Lin

We have recently developed a method based on relativistic time-dependent density functional theory (TD-DFT) that allows the calculation of electronic spectra in solution (Creutzberg, Hedeg{\aa}rd, J. Chem. Theory Comput.18, 2022, 3671).…

Chemical Physics · Physics 2023-04-04 Joel Creutzberg , Erik Donovan Hedegård

Raman spectroscopy of graphene is reviewed from a theoretical perspective. After an introduction of the building blocks (electronic band structure, phonon dispersion, electron-phonon interaction, electron-light coupling), Raman intensities…

Mesoscale and Nanoscale Physics · Physics 2017-03-23 Sven Reichardt , Ludger Wirtz

Using time dependent density functional theory (TDDFT) we examine the energy, angular and time-resolved photoelectron spectra (TRPES) of ethylene in a pump-probe setup. To simulate TRPES we expose ethylene to an ultraviolet (UV) femtosecond…

Atomic and Molecular Clusters · Physics 2014-08-28 Alison Crawford-Uranga , Umberto De Giovannini , Duncan John Mowbray , Stefan Kurth , Angel Rubio

The structural, dynamical, and thermodynamical properties of diamond, graphite and layered derivatives (graphene, rhombohedral graphite) are computed using a combination of density-functional theory (DFT) total-energy calculations and…

Materials Science · Physics 2009-11-10 Nicolas Mounet , Nicola Marzari

The time-dependent density functional theory (TDDFT) provides a unified description of the structure and reaction. The linear approximation leads to the random-phase approximation (RPA) which is capable of describing a variety of collective…

Nuclear Theory · Physics 2016-05-09 Kai Wen , Kouhei Washiyama , Ni Fang , Takashi Nakatsukasa

We evaluate the stopping and image forces on a charged particle moving parallel to a doped sheet of graphene by using the dielectric response formalism for graphene's $\pi$-electron bands in the random phase approximation (RPA). The forces…

Materials Science · Physics 2009-11-10 K. F. Allison , D. Borka , I. Radović , Lj. Hadžievski , Z. L. Mišković

Within the framework of ab initio time-dependent density-functional theory (TD-DFT), we propose a static approximation to the exchange-correlation kernel based on the jellium-with-gap model. This kernel accounts for electron-hole…

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