Related papers: Electrostatic interactions in critical solvents
The normal and the lateral Casimir interactions between corrugated ideal metallic plates in the presence of an amplifying or an absorptive dielectric slab has been studied by the path-integral quantization technique. The effect of the…
Two thin conducting, electrically neutral, parallel plates forming an isolated system in vacuum exert attracting force on each other, whose origin is the quantum electrodynamical interaction. This theoretical hypothesis, known as Casimir…
Spatial confinement of a near-critical medium changes its fluctuation spectrum and modifies the corresponding order parameter distribution. These effects result in effective, so-called critical Casimir forces (CCFs) acting on the confining…
To study the critical Casimir force between chemically structured boundaries immersed in a binary mixture at its demixing transition, we consider a strip of Ising spins subject to alternating fixed spin boundary conditions. The system…
Among the various kinds of effective forces in soft matter, the spatial range and the direction of the so-called critical Casimir force - which is generated by the enhanced thermal fluctuations close to a continuous phase transition - can…
A quite straightforward approximation for the electrostatic interaction between two perfectly conducting surfaces suggests itself when the distance between them is much smaller than the characteristic lengths associated to their shapes.…
We study the electrostatic Casimir effect and related phenomena in equilibrium statistical mechanics of classical (non-quantum) charged fluids. The prototype model consists of two identical dielectric slabs in empty space (the pure Casimir…
Colloids immersed in a critical or near-critical binary liquid mixture and close to a chemically patterned substrate are subject to normal and lateral critical Casimir forces of dominating strength. For a single colloid we calculate these…
Vacuum fluctuations are a fundamental and irremovable property of a quantized electromagnetic field. These fluctuations are the cause of the Casimir effect -- mutual attraction of two electrically neutral metallic plates in vacuum in the…
Effect of ionic solute on a near-critical binary aqueous mixture confined between charged walls with different adsorption preferences is considered within a simple density functional theory. For the near-critical system containing small…
Motivated by recent experiments with confined binary liquid mixtures near their continous demixing phase transition we study the critical behavior of a system, which belongs to the Ising universality class, for the film geometry with one…
The critical Casimir effect provides a thermodynamic analogue of the well-known quantum mechanical Casimir effect. It acts between two surfaces immersed in a critical binary liquid mixture, and results from the confinement of concentration…
Colloids immersed in a critical binary liquid mixture are subject to critical Casimir forces (CCFs) because they confine its concentration fluctuations and influence the latter via effective surface fields. To date, CCFs have only been…
We report a numerical investigation of two colloids immersed in a critical solvent, with the aim of quantifying the effective colloid-colloid interaction potential. By turning on an attraction between the colloid and the solvent particles…
The interaction between charged objects in solution is generally expected to recapitulate two central principles of electromagnetics: (i) like-charged objects repel, and (ii) they do so regardless of the sign of their electrical charge.…
The exact critical Casimir force between periodically deformed boundaries of a 2D semi-infinite strip is obtained for conformally invariant classical systems. Only two parameters (conformal charge and scaling dimension of a boundary…
Casimir interactions are not pair-wise additive. This property leads to collective effects that we study for a pair of objects near a conducting wall. We employ a scattering approach to compute the interaction in terms of fluctuating…
We investigate the pseudo-Casimir force acting between two charged surfaces confining a single polyelectrolyte chain with opposite charge. We expand the exact free energy to the second order in the local electrostatic field as well as the…
The electrostatic interaction between colloidal particles trapped at the interface between two immiscible electrolyte solutions is studied in the limit of small inter-particle distances. Within an appropriate model exact analytic…
Charged soft-matter systems--such as colloidal dispersions and charged polymers--are dominated by attractive forces between constituent like-charged particles when neutralizing counterions of high charge valency are introduced. Such…