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We report coupling between magnetic and electric orders for antiferromagnetic polycrystalline FeVO4 in which magnetism-induced polarization has been recently found in noncollinear antiferromagnetic state below the second antiferromagnetic…

Materials Science · Physics 2009-11-17 Bohdan Kundys , Christine Martin , Charles Simon

The magnetic properties of the high temperature alpha form of the CaCr2O4 compound have been investigated for the first time by magnetic susceptibility, specific heat and powder neutron diffraction. The system undergoes a unique magnetic…

Strongly Correlated Electrons · Physics 2015-05-19 L. C. Chapon , P. Manuel , F. Damay , P. Toledano , V. hardy , C. Martin

Neutron scattering studies and measurements of the dielectric susceptibility and ferroelectric polarization P have been carried out in various magnetic fields H for single-crystal samples of the multiferroic system LiVCuO4 with quasi…

Strongly Correlated Electrons · Physics 2015-05-13 Yukio Yasui , Yutaka Naito , Kenji Sato , Taketo Moyoshi , Masatoshi Sato* , Kazuhisa Kakurai

We have successfully synthesized three quasi-2D geometrically frustrated magnetic compounds (\alpha-MCr_2O_4, M=Ca, Sr, Ba) using the spark-plasma-sintering technique. All these members of the \alpha-MCr_2O_4 family consist of the stacking…

We study the magnetocapacitance (MC) effect and magnetoelectric (ME) coupling in spin-flop driven antiferromagnet Co4Ta2O9. The magnetocapacitance data at high magnetic fields are analyzed by phenomenological Ginzburg-landau theory of…

Materials Science · Physics 2017-07-12 S. Chaudhary , P. Srivastava , S. Patnaik

Synthesis and extensive structural, pyroelectric, magnetic, dielectric and magneto-electric characterizations are reported for polycrystalline Co4Nb2O9 towards unraveling the multiferroic state especially in reference to the magnetic spin…

Materials Science · Physics 2016-12-07 P. Srivastava , S. Chaudhary , J. Saha , S. Patnaik

The coupling of magnetic chiralities to the ferroelectric polarisation in multiferroic RbFe(MoO$_4$)$_2$ is investigated by neutron spherical polarimetry. Because of the axiality of the crystal structure below $T_\textrm{c}$ = 190 K,…

Magnetic susceptibility, specific heat, dielectric, and electric polarization of LiCuFe2(VO4)3 have been investigated. Two sequential antiferromagnetic transitions at TN1 ~ 9.95 K and TN2 ~ 8.17 K are observed under zero magnetic field.…

The number of magnetoelectric multiferroic materials reported to date is scarce, as magnetic structures that break inversion symmetry and induce an improper ferroelectric polarization typically arise through subtle competition between…

Our results describe an unprecedented example of change in the mechanism of magnetically-induced electric polarization from spin current to spin-dependent p-d hybridization model. We have followed the evolution of the magnetic structures of…

In rhombohedral CaMn7O12, an improper ferroelectric polarization of magnitude 2870 {\mu}C m-2 is induced by an incommensurate helical magnetic structure that evolves below TN1 = 90 K. The electric polarization was found to be constrained to…

Strongly Correlated Electrons · Physics 2015-05-30 R. D. Johnson , L. C. Chapon , D. D. Khalyavin , P. Manuel , P. G. Radaelli , C. Martin

(NH$_4$)$_2$[FeCl$_5$(H$_2$O)], a member of the family of antiferromagnetic $A_2$[Fe$X_5$(H$_2$O)] compounds ($X$ = halide ion, $A$ = alkali metal or ammonium ion) is classified as a new multiferroic material. We report the onset of…

Strongly Correlated Electrons · Physics 2015-06-16 M. Ackermann , D. Brüning , T. Lorenz , P. Becker , L. Bohatý

The single crystal study of CaBaCo4O7, a non collinear ferrimagnet (TC=64K), with a polar orthorhombic space group (Pbn21) between 4 K and 293 K, shows the appearance below TC of a large electric polarization along its c axis, reaching…

Materials Science · Physics 2015-06-15 V. Caignaert , A. Maignan , K. Singh , Ch. Simon , V. Pralong , B. Raveau , J. F. Mitchell , H. Zheng , A. Huq , L. Chapon

Co4Nb2O9 (CNO) having {\alpha}-Al2O3 crystal structure with Co chains along c-direction shows gigantic magnetoelelctric coupling below antiferromagnetic ordering temperature of 27 K but above a spin flop field of 1.6 T. We have investigated…

Materials Science · Physics 2016-06-16 C. Dhanasekhar , S. K. Mishra , R. Rawat , A. K. Das , A. Venimadhav

We report the discovery of a complete suppression of ferroelectricity in $MnWO_4$ by 10 % iron substitution and its restoration in external magnetic fields. The spontaneous polarization in $Mn_{0.9}Fe_{0.1}WO_4$ arises below 12 K in…

Strongly Correlated Electrons · Physics 2008-03-08 R. P. Chaudhury , B. Lorenz , Y. Q. Wang , Y. Y. Sun , C. W. Chu

The geometrically frustrated magnet Ni3V2O8 undergoes a series of competing magnetic ordering at low temperatures. Most importantly, one of the incommensurate phases has been reported to develop a ferroelectric correlation caused by spin…

Materials Science · Physics 2009-06-26 A. K. Singh , D. Jain , V. Ganesan , A. K. Nigam , S. Patnaik

Magnetoelectric coupling in the polycrystalline antiferromagnets CuFe0.95Rh0.05O2 and CuFeO2 has been investigated. For both samples, electric polarization was observed in the absence of an applied external magnetic field demonstrating that…

Materials Science · Physics 2009-05-27 B. Kundys , A. Maignan , D. Pelloquin , Ch. Simon

Magnetoelectric multiferroics in which ferroelectricity and magnetism coexist have attracted extensive attention because they provide great opportunities for the mutual control of electric polarization by magnetic fields and magnetization…

Materials Science · Physics 2013-04-25 Fen Wang , Tao Zou , Li-Qin Yan , Yi Liu , Young Sun

Apart from being so far the only known binary multiferroic compound, CuO has a much higher transition temperature into the multiferroic state, 230 K, than any other known material in which the electric polarization is induced by spontaneous…

We study the multiferroic properties in the distorted tetrahedral quasi-one dimensional spin system Cu$_3$Mo$_2$O$_9$, in which the effects of the low dimensionality and the magnetic frustration are expected to appear simultaneously. We…

Strongly Correlated Electrons · Physics 2015-06-03 T. Hosaka , S. Hachiuma , H. Kuroe , T. Sekine , M. Hase , K. Oka , T. Ito , H. Eisaki , M. Fujisawa , S. Okubo , H. Ohta
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