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Charge transfer is a fundamental phenomenon in biology and chemistry, and involves the movement of charge through a system driven by nuclear dynamics. Because of the involvement of nuclear motion, it is generally assumed that charge…

Chemical Physics · Physics 2024-08-27 Simon P. Neville , Martha Yaghoubi Jouybari , Michael S. Schuurman

It is often intriguing experimentally to take stock of how conformational changes in the device configuration may impact the overall charge transport behavior of single-molecule junctions. Based on the allied approach of density functional…

Mesoscale and Nanoscale Physics · Physics 2020-02-06 Talem Rebeda Roy , Arijit Sen

The non-equilibrium tunnel transport processes are considered in a square lattice of metallic nanogranules embedded into insulating host. Based on a simple model with three possible charging states (+,-, or 0) of a granule and three kinetic…

Materials Science · Physics 2007-05-23 Yu. G. Pogorelov , J. F. Polido

We describe the electro-thermal transport in metallic carbon nanotubes (m-CNTs) by a semi-classical approach that takes into account the high-field dynamical interdependence between charge carrier and phonon populations. Our model is based…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Marcelo A. Kuroda , Jean Pierre Leburton

The effect of electron-phonon interactions in the conductance through metallic atomic wires is theoretically analyzed. The proposed model allows to consider an atomic size region electrically and mechanically coupled to bulk electrodes. We…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 L. de la Vega , A. Martin-Rodero , N. Agrait , A. Levy Yeyati

Transport through molecular contacts with a sluggish intramolecular vibrational mode strongly coupled to excess charges is studied far from equilibrium. A Born-Oppenheimer approximation in steady state reveals voltage dependent energy…

Mesoscale and Nanoscale Physics · Physics 2012-06-27 Lars Kecke , Joachim Ankerhold

Partial atomic charges are a useful and intuitive concept for understanding molecular properties and chemical reaction mechanisms, showing how changes in molecular geometry can affect the flow of electronic charge within a molecule.…

Chemical Physics · Physics 2022-01-14 Ryan J. MacDonell , Serguei Patchkovskii , Michael S. Schuurman

Table of contents 1. Introduction 2. Non-Fermi-liquid features of Fermi liquids: 1D physics in higher dimensions 3. Dzyaloshinskii-Larkin solution of the Tomonaga-Luttinger model 4. Renormalization group for interacting fermions 5. Single…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Dmitrii L. Maslov

The transfer of heat between electrons and phonons plays a key role for thermal management in future nanowire-based devices, but only a few experimental measurements of electron-phonon (e-ph) coupling in nanowires are available. Here, we…

Mesoscale and Nanoscale Physics · Physics 2013-02-01 Jason Matthews , Eric A. Hoffmann , Carsten Weber , Andreas Wacker , Heiner Linke

A comprehensive description of molecular electron transfer reactions is essential for our understanding of fundamental phenomena in bio-energetics and molecular electronics. Experimental studies of molecular systems in condensed-phase…

Quantum Physics · Physics 2021-02-04 Frank Schlawin , Manuel Gessner , Andreas Buchleitner , Tobias Schaetz , Spiros S Skourtis

Models for same-material contact electrification in granular media often rely on a local charge-driving parameter whose spatial variations lead to a stochastic origin for charge exchange. Measuring the charge transfer from individual…

Soft Condensed Matter · Physics 2023-03-21 Galien Grosjean , Scott Waitukaitis

We introduce a rigorous, physically appealing, and practical way to measure distances between exchange-only correlations of interacting many-electron systems, which works regardless of their size and inhomogeneity. We show that this…

Materials Science · Physics 2017-10-18 Simone Marocchi , Stefano Pittalis , Irene D'Amico

Nucleic acids and proteins are not only biologically important polymers: They have recently been recognized as novel functional materials surpassing in many aspects the conventional ones. Although Herculean efforts have been undertaken to…

Soft Condensed Matter · Physics 2010-06-17 Waleed Shinwari , Jamal Deen , Evgeni Starikov , Gianaurelio Cuniberti

This mini review focuses on conductance measurements through molecular junctions containing few tens of molecules, which are fabricated along two approaches: (i) conducting atomic force microscope contacting a self-assembled monolayers on…

Applied Physics · Physics 2019-11-12 Dominique Vuillaume

Intermolecular charge-transfer is a highly important process in biology and energy-conversion applications where generated charges need to be transported over several moieties. However, its theoretical description is challenging since the…

Chemical Physics · Physics 2024-05-03 Nicola Bogo , Christopher J. Stein

We investigate the thermopower of a metal-molecule-metal junction taking into account thermal effects on the junction. Based on analytical expressions and numerical simulations we show that the thermoelectric potential reveals valuable…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Dvira Segal

Heat conduction by phonons is a ubiquitous process that incorporates a wide range of physics and plays an essential role in applications ranging from space power generation to LED lighting. Heat conduction has been studied for over two…

Mesoscale and Nanoscale Physics · Physics 2014-05-06 Austin J. Minnich

Force fields uniquely assign interatomic forces for a given set of atomic coordinates. The underlying assumption is that electrons are in their quantum-mechanical ground state or in thermal equilibrium. However, there is an abundance of…

Materials Science · Physics 2013-08-19 Wolf B. Dapp , Martin H. Müser

We consider a one-dimensional system of electrons interacting via a short-range repulsion and coupled to phonons close to the metal-insulator transition at half filling. We argue that the metal-insulator transition can be described as a…

Condensed Matter · Physics 2015-06-25 M. Fabrizio , C. Castellani , C. Di Castro

Transport through a one channel wire of length $L$ confined between two leads is examined when the 1D electron system has an energy gap $2M$: $M > T_L \equiv v_c/L$ induced by the interaction in charge mode ($v_c$: charge velocity in the…

Condensed Matter · Physics 2009-10-31 Vadim Ponomarenko , Naoto Nagaosa
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