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The Jarzynski equality (JE) is analyzed in regard to its validity for both quasi-static transformations in the thermodynamic limit and Hamiltonian evolutions of the work protocol. In the first case, we show that the JE holds for isothermal…

Statistical Mechanics · Physics 2020-05-15 Amilcare Porporato , Salvatore Calabrese

Almost 25 years ago, Jarzynski published a paper in which it was asserted: the work done, W, in driving a system from state A to state B, characterized by the Helmholtz free energies FA and FB, satisfies an equality in which an average over…

General Physics · Physics 2022-06-07 Ronald F. Fox

The special trajectory ensemble average (TEA), denoted by a subscript 0, in the Jarzynski Equality (JE) results in the Jensen inequality <R>_0 GT-EQ delta(F) for the work R done on the system, and not the thermodynamic work inequality <R>…

Statistical Mechanics · Physics 2018-02-23 P. D. Gujrati

Almost 25 years ago, Jarzynski published a paper in which it was asserted: the work done, W, in driving a system from state A to state B, characterized by the Helmholtz free energies FA and FB, satisfies an equality in which an average over…

General Physics · Physics 2021-08-25 Ronald F. Fox

A result of great theoretical and experimental interest, Jarzynski equality predicts a free energy change $\Delta F$ of a system at inverse temperature $\beta$ from an ensemble average of non-equilibrium exponential work, i.e., $\langle…

Statistical Mechanics · Physics 2017-10-18 Juan D. Jaramillo , Jiawen Deng , Jiangbin Gong

The well-known Jarzynski equality, often written in the form $e^{-\beta\Delta F}=\langle e^{-\beta W}\rangle$, provides a non-equilibrium means to measure the free energy difference $\Delta F$ of a system at the same inverse temperature…

Statistical Mechanics · Physics 2017-08-22 Jiawen Deng , Juan D. Jaramillo , Peter Hanggi , Jiangbin Gong

Responses of small open oscillator systems to applied external forces have been studied with the use of an exactly solvable classical Caldeira-Leggett (CL) model in which a harmonic oscillator (system) is coupled to finite $N$-body…

Statistical Mechanics · Physics 2015-05-27 Hideo Hasegawa

The Jarzynski equality (JE), which relates works of non-equilibrium trajectories to the free energy difference of the initial and final states of the non-equilibrium process, provides an efficient way to calculate free energies of systems…

Soft Condensed Matter · Physics 2016-04-20 Biao Wan , Cheng Yang , Yanting Wang , Xin Zhou

The Jarzynski equality (JE) is known as an exact identity for nonequillibrium systems. The JE was originally formulated for isolated and isothermal systems, while Adib reported an JE extended to an isoenergetic process. In this paper, we…

Statistical Mechanics · Physics 2015-05-27 Hitoshi Katsuda , Masayuki Ohzeki

We have studied dynamical responses and the Jarzynski equality (JE) of classical open systems described by the generalized Caldeira-Leggett model with the nonlocal system-bath coupling. In the derived non-Markovian Langevin equation, the…

Statistical Mechanics · Physics 2015-05-30 Hideo Hasegawa

The Jarzynski equality is a cornerstone of nonequilibrium thermodynamics, linking work statistics to equilibrium free-energy differences. Although it has been extensively verified in classical and quantum Hermitian settings, its status in…

Quantum Physics · Physics 2026-05-12 Zongru Yang , Teng Liu , Xiaodong Tan , Feng Zhu , Le Luo

The transition between a regime in which thermodynamic relations apply only to ensembles of small systems coupled to a large environment and a regime in which they can be used to characterize individual macroscopic systems is analyzed in…

Statistical Mechanics · Physics 2015-05-30 Alberto Suárez , Robert Silbey , Irwin Oppenheim

The Jarzynski equality (JE), which connects the equilibrium free energy with non-equilibrium work statistics, plays a crucial role in quantum thermodynamics. Although practical quantum systems are usually multi-level systems, most tests of…

Quantum Physics · Physics 2023-10-26 Wenquan Liu , Zhibo Niu , Wei Cheng , Xin Li , Chang-Kui Duan , Zhangqi Yin , Xing Rong , Jiangfeng Du

We study the non-equilibrium work in a pedagogical model of relativistic ideal gas. We obtain the exact work distribution and verify the Jarzynski's equality. In the non-relativistic limit, our results recover the non-relativistic results…

Statistical Mechanics · Physics 2025-11-21 Xianghang Zhang , Tingzhang Shi , H. T. Quan

Jarzynski's equality (JE) allows us to compute free energy differences from distributions of work. In molecular dynamics simulations, the traditional way of constructing work distributions is to perform as many pulling simulations as…

Computational Physics · Physics 2012-05-07 Van Ngo

We derive the differential equation describing the time evolution of the work probability distribution function of a stochastic system which is driven out of equilibrium by the manipulation of a parameter. We consider both systems described…

Statistical Mechanics · Physics 2007-05-23 A. Imparato , L. Peliti

The fluctuation theorems, and in particular, the Jarzynski equality, are the most important pillars of modern non-equilibrium statistical mechanics. We extend the quantum Jarzynski equality together with the Two-Time Measurement Formalism…

Statistical Mechanics · Physics 2018-03-01 Anthony Bartolotta , Sebastian Deffner

The Jarzynski relation is a recently discovered result relating the average exponential of the work done under nonequilibrium conditions to an equilibrium free energy difference. We illustrate this remarkable relation by considering the…

Statistical Mechanics · Physics 2007-05-23 Rhonald C. Lua

Jarzynski's theorem is a well-known equality in statistical mechanics, which relates fluctuations in the work performed during a non-equilibrium transformation of a system, to the free-energy difference between two equilibrium ensembles. In…

High Energy Physics - Lattice · Physics 2016-08-16 Michele Caselle , Gianluca Costagliola , Alessandro Nada , Marco Panero , Arianna Toniato

We show how Jarzynski relation can be exploited to analyze the nature of order-disorder and a bifurcation type dynamical transition in terms of a response function derived on the basis of work distribution over non-equilibrium paths between…

Chemical Physics · Physics 2015-06-05 Pulak Kumar Ghosh , Deb Shankar Ray
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