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Antirelaxation surface coatings allow long spin relaxation times in alkali-metal cells without buffer gas, enabling faster diffusion of the alkali atoms throughout the cell and giving larger signals due to narrower optical linewidths.…

Atomic Physics · Physics 2009-12-07 S. J. Seltzer , M. V. Romalis

A near-minimal instance of optical cooling is experimentally presented wherein the internal-state entropy of a single atom is reduced more than twofold by illuminating it with broadband, incoherent light. Since the rate of optical pumping…

Quantum Physics · Physics 2024-11-08 Amanda Younes , Randall Putnam , Paul Hamilton , Wesley C. Campbell

We demonstrate the mixing of rotational states in the ground electronic state using microwave radiation to enhance optical cycling in the molecule yttrium (II) monoxide (YO). This mixing technique is used in conjunction with a frequency…

A moderately intense $450$ fs laser pulse is used to create rotational wave packets in gas phase $\rm{I_2}$ molecules. The ensuing time-dependent alignment, measured by Coulomb explosion imaging with a delayed probe pulse, exhibits the…

We explore the role of laser induced anti-alignment in enhancing molecular orientation. A field-free enhanced orientation via anti-alignment scheme is presented, which combines a linearly polarized femtosecond laser pulse with a half-cycle…

Optics · Physics 2009-11-11 E. Gershnabel , I. Sh. Averbukh , Robert J. Gordon

Ultracold polar molecules offer strong electric dipole moments and rich internal structure, which makes them ideal building blocks to explore exotic quantum matter, implement novel quantum information schemes, or test fundamental symmetries…

Laser cooling to sub-Doppler temperatures by optical molasses is thought to be inhibited in atoms with unresolved, near-degenerate hyperfine structure in the excited state. We demonstrate that such cooling is possible in one to three…

Atomic Physics · Physics 2014-03-24 Paul Hamilton , Geena Kim , Trinity Joshi , Biswaroop Mukherjee , Daniel Tiarks , Holger Müller

Molecular ions can be held in a chain of laser-cooled atomic ions by sympathetic cooling. This system is ideal for performing high-precision molecular spectroscopy with applications in astrochemistry and fundamental physics. Here we show…

Atomic Physics · Physics 2015-08-20 Ncamiso B. Khanyile , Gang Shu , Kenneth R. Brown

We investigate laser cooling of an ensemble of atoms in an optical cavity. We demonstrate that when atomic dipoles are sychronized in the regime of steady-state superradiance, the motion of the atoms may be subject to a giant frictional…

Quantum Physics · Physics 2016-04-20 Minghui Xu , Simon B. Jäger , S. Schütz , J. Cooper , Giovanna Morigi , M. J. Holland

A general method for rotational microwave spectroscopy and control of polar molecular ions via direct microwave addressing is considered. Our method makes use of spatially varying AC Stark shifts, induced by far off-resonant, focused laser…

Atomic Physics · Physics 2015-06-16 M. Shi , P. F. Herskind , M. Drewsen , I. L. Chuang

A recent progress on laser cooling of molecules is summarized. Since the development during 1980s for atomic species, laser cooling has been the very beginning step to cool and trap atoms for frontier research on quantum simulations,…

Atomic Physics · Physics 2023-03-29 Eunmi Chae

We propose a method to reconstruct the vibrational quantum state of molecules excited by a general excitation laser pulse. Unlike existing methods, we do not require the molecules before excitation to be in a pure state, allowing us to…

Quantum Physics · Physics 2007-06-12 Anders S. Mouritzen , Olga Smirnova , Stefanie Grafe , Rune Lausten , Albert Stolow

We perform magnetically-assisted Sisyphus laser cooling of the triatomic free radical strontium monohydroxide (SrOH). This is achieved with principal optical cycling in the rotationally closed $P\left(N"=1\right)$ branch of either the…

Ultracold polar molecules are promising for quantum information processing and searches for physics beyond the Standard Model. Laser cooling to ultracold temperatures is an established technique for trapped diatomic and triatomic molecules.…

We investigate the prospects of creating broad rotational wave packets by means of molecular interaction with long sequences of intense femtosecond pulses. Using state-resolved rotational Raman spectroscopy of oxygen, subject to a sequence…

Quantum Physics · Physics 2016-01-27 M. Bitter , V. Milner

Recently a number of diatomic and polyatomics molecules has been identified as a prospective systems for Doppler/Sisyphus cooling. Doppler/Sisyphus cooling allows to decrease the kinetic energy of molecules down to microkelvin temperatures…

Chemical Physics · Physics 2017-11-22 T. A. Isaev , A. V. Zaitsevskii , E. Eliav

We propose a general method to cool the translational motion of molecules. Our method is an extension of single photon atomic cooling which was successfully implemented in our laboratory. Requiring a single event of absorption followed by a…

Chemical Physics · Physics 2015-05-13 Edvardas Narevicius , S. Travis Bannerman , Mark G. Raizen

We demonstrate a laser frequency stabilization technique for laser cooling of Potassium atoms, based on saturated absorption spectroscopy in the C-Band optical telecommunication window, using ro-vibrationel transitions of the acetylene…

Qubit coherence times are critical to the performance of any robust quantum computing platform. For quantum information processing using arrays of polar molecules, a key performance parameter is the molecular rotational coherence time. We…

A strong inhomogeneous static electric field is used to spatially disperse a supersonic beam of polar molecules, according to their quantum state. We show that the molecules residing in the lowest-lying rotational states can be selected and…

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