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A method was developed to calculate the free energy of 2D materials on substrates and was demonstrated by the system of graphene and {\gamma}-graphyne on copper substrate. The method works at least 3 orders faster than state-of-the-art…

Materials Science · Physics 2019-07-09 Yu-Peng Liu , Bo-Yuan Ning , Le-Cheng Gong , Tsu-Chien Weng , Xi-Jing Ning

Subatomic systems are pivotal for understanding fundamental baryonic interactions, as they provide direct access to quark-level degrees of freedom. In particular, introducing a strange quark adds "strangeness" as a new dimension, offering a…

We report fast atom diffraction through single-layer graphene using hydrogen atoms at kinetic energies from 150 to 1200 eV. High-resolution images reveal overlapping hexagonal patterns from coexisting monocrystalline domains. Time-of-flight…

One popular approach to prepare graphene is to grow them on transition metal substrates via chemical vapor deposition. By using the density functional theory with dispersion correction, we systematically investigate for the first time the…

Materials Science · Physics 2015-06-03 Jiaxin Zheng , Yangyang Wang , Lu Wang , Ruge Quhe , Zeyuan Ni , Wai-Ning Mei , Zhengxiang Gao , Dapeng Yu , Junjie Shi , Jing Lu

We have experimentally investigated the expansion mechanism induced by laser irradiation of H2SO4 intercalated graphite. Intercalated graphite materials irradiated by laser allows to study reactions occurring in confined chemical…

Materials Science · Physics 2014-07-24 G. Carotenuto , A. Longo , L. Nicolais , S. De Nicola , E. Pugliese , M. Ciofini , M. Locatelli , A. Lapucci , R. Meucci

The thermodynamic, kinetic and magnetic properties of the hydrogen monomer on doped graphene layers were studied by ab initio simulations. Electron doping was found to heighten the diffusion potential barrier, while hole doping lowers it.…

Materials Science · Physics 2011-08-17 Liang Feng Huang , Mei Yan Ni , Guo Ren Zhang , Wang Huai Zhou , Yong Gang Li , Xiao Hong Zheng , Zhi Zeng

Theoretical study of graphite (graphene) edge is done. The most stable edge orientation is calculated to be a zigzag [110] edge. Possible applications of the result to the formation of different graphitic structures are discussed.

Materials Science · Physics 2007-05-23 Slava V. Rotkin

Ferromagnetism in carbon-based materials is appealing for both applications and fundamental science purposes because carbon is a light and bio-compatible material that contains only s and p electrons in contrast to traditional ferromagnets…

Materials Science · Physics 2009-10-13 J. Cervenka , M. I. Katsnelson , C. F. J. Flipse

Chemisorption of hydrogen on graphene is studied using atomistic simulations with the second generation of reactive empirical bond order Brenner inter-atomic potential. The lowest energy adsorption sites and the most important metastable…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 Abdiravuf A. Dzhurakhalov , Francois M. Peeters

Graphynes are 2D porous structures deriving from graphene featuring triangular and regularly distributed subnanometer pores, which may be exploited to host small gaseous species. First principles adsorption energies of molecular hydrogen…

Chemical Physics · Physics 2015-10-06 Massimiliano Bartolomei , Estela Carmona-Novillo , Giacomo Giorgi

The recent discovery of superconductivity and magnetism in trilayer rhombohedral graphene (RG) establishes an ideal, untwisted platform to study strong correlation electronic phenomena. However, the correlated effects in multilayer RG have…

The electrolyte intercalation mechanism facilitates the insertion/extraction of charge into the electrode material in rechargeable batteries. Aluminum fluoride (AlF$_{3}$) has been used as an electrolyte in rechargeable aluminum batteries…

The interlayer hybridization (IH) of van der Waals (vdW) materials is thought to be mostly associated with the unignorable interlayer overlaps of wavefunctions ($t$) in real space. Here, we develop a more fundamental understanding of IH by…

Materials Science · Physics 2023-08-09 Bin Shao , Xiao Jiang , Jan Berges , Sheng Meng , Bing Huang

We present an accurate interatomic potential for graphene, constructed using the Gaussian Approximation Potential (GAP) machine learning methodology. This GAP model obtains a faithful representation of a density functional theory (DFT)…

Materials Science · Physics 2018-02-14 Patrick Rowe , Gábor Csányi , Dario Alfè , Angelos Michaelides

Bilayer graphene (BLG) with a tunable bandgap appears interesting as an alternative to graphene for practical applications, thus its transport properties are being actively pursued. Using density functional theory and perturbation analysis,…

Materials Science · Physics 2015-05-11 Changwon Park , Junga Ryou , Suklyun Hong , Bobby Sumpter , Gunn Kim , Mina Yoon

We have measured the temperature and magnetic field dependence of the Hall coefficient ($R_{\rm H}$) in three, several micrometer long multigraphene samples of thickness between $\sim 9~$to $\sim 30$~nm in the temperature range 0.1 to 200~K…

Superconductivity · Physics 2014-11-07 P. Esquinazi , J. Krüger , J. Barzola-Quiquia , R. Schönemann , T. Herrmannsdörfer , N. García

Multilayered graphitic materials are not suitable as load-bearers due to their inherent weak interlayer bonding (for example, graphite is a solid lubricant in certain applications). This situation is largely improved when two-dimensional…

We investigate the effect of pressure on the carbon dioxide (CO$_{2}$) hydrate-water interfacial free energy along its dissociation line using advanced computer simulation techniques. In previous works, we have determined the interfacial…

Density functional calculations of electronic structure, total energy, structural distortions, and magnetism for hydrogenated single-layer, bilayer, and multi-layer graphene are performed. It is found that hydrogen-induced magnetism can…

Materials Science · Physics 2008-01-24 D. W. Boukhvalov , M. I. Katsnelson , A. I. Lichtenstein

Chemical bondings of graphene oxides with oxygen concentration from 1\% to 50\% are investigated using first-principle calculations. Energy gaps are mainly determined by the competition of orbital hybridizations in C-C, O-O, and C-O bonds.…

Materials Science · Physics 2015-12-31 Ngoc Thanh Thuy Tran , Shih-Yang Lin , Olga E. Glukhova , Ming-Fa Lin