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We consider a single particle which is bound by a central potential and obeys the Dirac equation in d dimensions. We first apply the asymptotic iteration method to recover the known exact solutions for the pure Coulomb case. For a…

Mathematical Physics · Physics 2009-11-11 Hakan Ciftci , Richard L. Hall , Nasser Saad

We derive a formula that simplifies the original asymptotic iteration method formulation to find the energy eigenvalues for the analytically solvable cases. We then show that there is a connection between the asymptotic iteration and the…

Quantum Physics · Physics 2009-11-13 I. Boztosun , M. Karakoc

We argue that the results proposed recently for the $\mathrm{a}^3\Sigma_u^+$ electronic state of $^7\mathrm{Li}_2$ do not exhibit any physical utility because the canonical vibrational partition function for an excited electronic state…

Chemical Physics · Physics 2021-12-21 Francisco M. Fernández

The shifted Tietz-Wei (sTW) oscillator is as good as traditional Morse potential in simulating the atomic interaction in diatomic molecules. By using the Pekeris-type approximation to deal with the centrifugal term, we obtain the…

Chemical Physics · Physics 2015-04-22 Babatunde J. Falaye , Sameer M. Ikhdair , Majid Hamzavi

We generalize previous calculations to a fully relativistic treatment of adiabatic oscillations which are trapped in the inner regions of accretion disks by non-Newtonian gravitational effects of a black hole. We employ the Kerr geometry…

We analyze a system of two colliding ultracold atoms under strong harmonic confinement from the viewpoint of quantum defect theory and formulate a generalized self-consistent method for determining the allowed energies. We also present two…

Atomic Physics · Physics 2013-05-29 Gillian Peach , Ian B Whittingham , Timothy J Beams

We formulate the theory for a diatomic molecule in a spatially degenerate electronic state interacting with a non-resonant laser field and investigate its rovibrational structure in the presence of the field. We report on \textit{ab initio}…

The representation of the potential energy surfaces of atom molecule or molecular dimers interactions should account faithfully for the symmetry properties of the systems, preserving at the same time a compact analytical form. To this aim,…

We present a systematic understanding of the rotational structure of a long-range (vibrationally highly-excited) diatomic molecule. For example, we show that depending on a quantum defect, the least-bound vibrational state of a diatomic…

Atomic Physics · Physics 2009-11-10 Bo Gao

The radial time-independent Schr\"odinger equation is solved for the diatomic molecules: H2, LiH, HCl, CO, VH, CrH, CuLi, TiC, NiC, and ScN using the recently developed Nikiforov-Uvarov Functional Analysis (NUFA) method. A modified Morse…

Chemical Physics · Physics 2024-10-01 Raghav Sharma , Pragati Ashdhir , Amit Tanwar

Exact bound state solutions and the corresponding wave functions of the Schr\"odinger equation for some non-central potentials including Makarov potential, modified-Kratzer plus a ring-shaped potential, double ring-shaped Kratzer potential,…

Mathematical Physics · Physics 2012-05-09 Altug Arda , Ramazan Sever

In this work, we study the exact solution of Dirac equation in the hyper-spherical coordinate under influence of separable q-Deformed quantum potentials. The q-deformed hyperbolic Rosen-Morse potential is perturbed by q-deformed non-central…

Quantum Physics · Physics 2016-09-08 Subur Pramono , A Suparmi , Cari Cari

We show that the exact energy eigenvalues and eigenfunctions of the Schrodinger equation for charged particles moving in certain class of non-central potentials can be easily calculated analytically in a simple and elegant manner by using…

Quantum Physics · Physics 2009-11-13 Sameer M. Ikhdair , Ramazan Sever

We obtain Plancherel-Rotach type asymptotics valid in all regions of the complex plane for orthogonal polynomials with varying weights of the form $e^{-NV(x)}$ on the real line, assuming that $V$ has only two Lipschitz continuous…

Classical Analysis and ODEs · Mathematics 2008-05-15 K. T. -R. McLaughlin , P. D. Miller

We propose an accurate and efficient method to compute vibrational spectra of molecules, based on exact diagonalization of an algebraically calculated matrix based on powers of Morse coordinate. The present work focuses on the 1D potential…

Chemical Physics · Physics 2009-11-13 Andrea Bordoni , Nicola Manini

A new approach is described to the evaluation of the S-matrix in three-dimensional atom-diatom reactive quantum scattering theory. The theory is developed based on natural collision coordinates where progress along the reaction coordinate…

Chemical Physics · Physics 2007-05-23 Ashot S. Gevorkyan , Gabriel G. Balint-Kurti , Gunnar Nyman

We study a general problem of the translational/rotational/vibrational/electronic dynamics of a diatomic molecule exposed to an interaction with an arbitrary external electromagnetic field. The theory developed in this paper is relevant to…

Quantum Physics · Physics 2016-09-28 Milan Sindelka , Nimrod Moiseyev

The ordinary Schrodinger equation with minimal coupling for a nonrelativistic electron interacting with a single-mode photon field is not satisfied by the nonrelativistic limit of the exact solutions to the corresponding Dirac equation. A…

Atomic Physics · Physics 2009-10-31 Dong-Sheng Guo , R. R. Freeman , Yong-Shi Wu

We introduce the alchemical harmonic approximation (AHA) of the absolute electronic energy for charge-neutral iso-electronic diatomics at fixed interatomic distance $d_0$. To account for variations in distance, we combine AHA with this…

Chemical Physics · Physics 2024-12-10 Simon León Krug , Danish Khan , O. Anatole von Lilienfeld

We propose a q-deformed model of the anharmonic vibrations in diatomic molecules. We analyse the applicability of the model to the phenomenological Dunham's expansion by comparing with experimental data. Our methodology involves a global…

Statistical Mechanics · Physics 2011-12-20 Maia Angelova , Vladimir Dobrev , Alejandro Frank
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