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A new method for solving the time-dependent two-center Dirac equation is developed. The time-dependent Dirac wave function is represented as a sum of atomic-like Dirac-Sturm orbitals, localized at the ions. The atomic orbitals are obtained…

We carry out first-principle calculations of scalar and tensor components of the static electric dipole polarizabilities of six low-lying states of lithium (Li), sodium (Na) and potassium (K) alkali atoms in the linear response approach.…

Atomic Physics · Physics 2025-04-22 A. Chakraborty , B. K. Sahoo

The adaptively compressed exchange (ACE) method provides an efficient way for solving Hartree-Fock-like equations in quantum physics, chemistry, and materials science. The key step of the ACE method is to adaptively compress an operator…

Numerical Analysis · Mathematics 2017-11-22 Lin Lin , Michael Lindsey

This paper is devoted to the investigation of long-time behaviour of solutions to wave equations with quadratic nonlinearity and cubic Dirac equations with Hartree-type nonlinearity. We consider the nonlinearity here with enough simplicity…

Analysis of PDEs · Mathematics 2022-07-07 Seokchang Hong

We present a novel form of relativistic quantum mechanics and demonstrate how to solve it using a recently derived unitary perturbation theory, within partial wave analysis. The theory is tested on a relativistic problem, with two spinless,…

Quantum Physics · Physics 2021-08-11 Scott E. Hoffmann

We present the first full-potential method that solves the fully relativistic 4-component Dirac-Kohn-Sham equation for materials in the solid state within the framework of atom-centered Gaussian-type orbitals (GTOs). Our GTO-based method…

Chemical Physics · Physics 2019-05-07 Marius Kadek , Michal Repisky , Kenneth Ruud

Self-consistent perturbation expansion up to the second order in the interaction strength is used to study a single-level quantum dot with local Coulomb repulsion attached asymmetrically to two generally different superconducting leads. At…

Mesoscale and Nanoscale Physics · Physics 2016-02-02 Martin Žonda , Vladislav Pokorný , Václav Janiš , Tomáš Novotný

The symmetry-projected Hartree--Fock ansatz for the electronic structure problem can efficiently account for static correlation in molecules, yet it is often unable to describe dynamic correlation in a balanced manner. Here, we consider a…

Strongly Correlated Electrons · Physics 2015-06-17 Carlos A. Jiménez-Hoyos , R. Rodríguez-Guzmán , Gustavo E. Scuseria

The Hartree-Fock based diagonalization is a computational method for the investigation of the low-energy properties of correlated electrons in disordered solids. The method is related to the quantum-chemical configuration interaction…

Disordered Systems and Neural Networks · Physics 2007-05-23 Michael Schreiber , Thomas Vojta

The adaptive perturbation method decomposes a Hamiltonian by the diagonal elements and non-diagonal elements of the Fock state. The diagonal elements of the Fock state are solvable but can contain the information about coupling constants.…

High Energy Physics - Theory · Physics 2020-12-25 Chen-Te Ma

Semi-Lagrangian methods have traditionally been developed in the framework of hyperbolic equations, but several extensions of the Semi-Lagrangian approach to diffusion and advection--diffusion problems have been proposed recently. These…

Numerical Analysis · Mathematics 2014-05-20 L. Bonaventura , R. Ferretti

Perturbation theory is used systematically to investigate the symmetries of the Dirac Hamiltonian and their breaking in atomic nuclei. Using the perturbation corrections to the single-particle energies and wave functions, the link between…

Nuclear Theory · Physics 2011-04-15 Haozhao Liang , Pengwei Zhao , Ying Zhang , Jie Meng , Nguyen Van Giai

Other than scattering problems where perturbation theory is applicable, there are basically two ways to solve problems in physics. One is to reduce the problem to harmonic oscillators, and the other is to formulate the problem in terms of…

Quantum Physics · Physics 2007-05-23 Y. S. Kim , Marilyn E. Noz

In this paper, we propose new linearly convergent second-order methods for minimizing convex quartic polynomials. This framework is applied for designing optimization schemes, which can solve general convex problems satisfying a new…

Optimization and Control · Mathematics 2022-01-14 Yurii Nesterov

We present an arbitrary-order spectral element method for general-purpose simulation of non-overturning water waves, described by fully nonlinear potential theory. The method can be viewed as a high-order extension of the classical finite…

Computational Physics · Physics 2016-06-22 Allan Peter Engsig-Karup , Claes Eskilsson , Daniele Bigoni

A previously proposed non-canonical coupled-perturbed Kohn-Sham density functional theory (KS-DFT)/Hartree-Fock (HF) treatment for spin-orbit coupling is here generalized to infinite periodic systems. The scalar-relativistic periodic…

Atomic polarization phenomena impinge upon a number of areas and processes in physics. The dielectric constant and refractive index of any gas are examples of macroscopic properties that are largely determined by the dipole polarizability.…

Atomic Physics · Physics 2015-05-18 J. Mitroy , M. S. Safronova , Charles W. Clark

We employ the closed-shell perturbed relativistic coupled-cluster (RCC) theory developed by us earlier [Phys. Rev. A {\bf 77}, 062516 (2008)] to evaluate the ground state static electric dipole polarizabilities (\alpha s) of several atomic…

Atomic Physics · Physics 2013-12-09 Yashpal Singh , B. K. Sahoo , B. P. Das

We consider the numerical solution of partial differential equations with coefficients that are strongly heterogeneous in space. We provide an overview of higher-order localized orthogonal decomposition (LOD) methods for the elliptic…

Numerical Analysis · Mathematics 2026-05-29 Balaje Kalyanaraman , Felix Krumbiegel , Roland Maier , Siyang Wang

We propose a novel Model Order Reduction framework that is able to handle solutions of hyperbolic problems characterized by multiple travelling discontinuities. By means of an optimization based approach, we introduce suitable calibration…

Numerical Analysis · Mathematics 2025-05-14 Monica Nonino , Davide Torlo