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Chemical vapour deposition enables large-domain growth of ideal graphene, yet many applications of graphene require the controlled inclusion of specific defects. We present a one-step chemical vapour deposition procedure aimed at retaining…

Graphene stands as a promising material with vast potential across energy storage, electronics, etc. Here, we present a novel mechanical approach utilizing ultrasonic high-energy intercalation exfoliation to extract monolayer graphene from…

Materials Science · Physics 2025-01-15 Kaitong Sun , Si Wu , Junchao Xia , Yinghao Zhu , Guanping Xu , Hai-Feng Li

Highly Oriented Pyrolytic Graphite was exfoliated via pulsed discharge plasma in liquid nitrogen. The potential mechanisms involved were investigated by observing the treated surface of the graphitic material and the obtained particles.…

Graphene oxide (GO) raised substantial interest in the last two decades thanks to its unique properties beyond those of pristine graphene, including electronic energy band-gap, hydrophilic behavior and numerous anchoring sites required for…

Applied Physics · Physics 2021-04-07 O. Seri-Livni , C. Saguy , F. Horani , E. Lifshitz , D. Cheskis

Bulk quantities of graphene nanosheets and nanodots have been selectively fabricated by mechanical grinding exfoliation of natural graphite in a small quantity of ionic liquids. The resulting graphene sheets and dots are solvent free with…

Our first principles calculations reveal that oxidative cut of graphene is realized by forming epoxy and then carbonyl pairs. Direct forming carbonyl pair to tear graphene up from an edge position is not favorable in energy. This atomic…

Materials Science · Physics 2009-12-02 Zhenyu Li , * Wenhua Zhang , Yi Luo , Jinlong Yang , * , Jian Guo Hou

Graphene oxide (GO) is one of chemically modified graphenes and has been extensively studied worldwide. A monolayer sheet of GO which is chemically produced in solution can be deposited on various substrates. We have proved that use of…

Materials Science · Physics 2011-01-21 Seiji Obata , Hiroshige Tanaka , Koichiro Saiki

Hydrogenation of graphene on the \alpha-quartz (0001) SiO_2 substrate is studied, considering different surface terminations in order to take into account the amorphic nature of the material. Our ab initio calculations show that the…

Mesoscale and Nanoscale Physics · Physics 2012-01-16 P. Havu , M. Ijäs , A. Harju

In the present work, the use of a commercial ionic liquid as a convenient solvent medium for graphite exfoliation in mild and easy conditions without any chemical modification is presented. To confirm the presence of few layer graphene, its…

While freestanding clean graphene is essential for various applications, existing technologies for removing the polymer layer after transfer of graphene to the desired substrate still leave significant contaminations behind. We discovered a…

Materials Science · Physics 2015-06-11 Jean-Nicolas Longchamp , Conrad Escher , Hans-Werner Fink

We report reduced contact resistance of single-layer graphene devices by using ultraviolet ozone (UVO) treatment to modify the metal/graphene contact interface. The devices were fabricated from mechanically transferred, chemical vapor…

Resist residue from the device fabrication process is a general and significant source of the metal/graphene contact interface contamination. In this paper, Ultraviolet-Ozone (UVO) treatment is proven to be an effective way of cleaning the…

Mesoscale and Nanoscale Physics · Physics 2013-05-31 Wei Li , Christina A. Hacker , Yiran Liang , Curt A. Richter , David J. Gundlach , Xuelei Liang , Lianmao Peng

We have developed a novel method for crystalline hydrogenation of graphene on the nanoscale. Molecular hydrogen was physisorbed at 5 K onto pristine graphene islands grown on Cu(111) in ultrahigh vacuum. Field emission local to the tip of a…

Mesoscale and Nanoscale Physics · Physics 2017-06-06 S. J. Tjung , S. M. Hollen , G. A. Gambrel , N. M. Santagata , E. Johnston-Halperin , J. A. Gupta

We propose an innovative, easy-to-implement approach to synthesize large-area singlecrystalline graphene sheets by chemical vapor deposition on copper foil. This method doubly takes advantage of residual oxygen present in the gas phase.…

As a viable candidate for an all-carbon post-CMOS electronics revolution, epitaxial graphene has attracted significant attention. To realize its application potential, reliable methods for fabricating large-area single-crystalline graphene…

The adoption of graphene in electronics, optoelectronics and photonics is hindered by the difficulty in obtaining high quality material on technologically-relevant substrates, over wafer-scale sizes and with metal contamination levels…

A friction based method is proposed for obtaining graphite layers. Freestanding thin structures of graphite containing several layers of graphene are obtained by rubbing a graphite rod on the surfaces of NaCl substrate and then dissolving…

Materials Science · Physics 2014-11-26 Manuel Mailian , Kamran ul Hasan , Aram Mailian

The chemical production of graphene as well as its controlled wet- chemical modification is a challenge for synthetic chemists and the characterization of reaction products requires sophisticated analytic methods. In this review we first…

Chemical Physics · Physics 2018-05-09 Siegfried Eigler , Andreas Hirsch

Comprehensive first-principles calculations are performed on diverse arrangements of relevant chemical defects in fluorographene to provide accurate microscopic insights into the process of graphene fluorination. The minimum energy paths…

Mesoscale and Nanoscale Physics · Physics 2022-08-17 Tahereh Malakoutikhah , S. Javad Hashemifar , Mojtaba Alaei

Graphene, the one-atom-thick sp2 hybridized carbon crystal, displays unique electronic, structural and mechanical properties, which promise a large number of interesting applications in diverse high tech fields. Many of these applications…

Mesoscale and Nanoscale Physics · Physics 2016-09-27 Tommaso Cavallucci , Khatuna Kakhiani , Riccardo Farchioni , Valentina Tozzini