Related papers: Deuteration as an evolutionary tracer in massive-s…
High degrees of deuterium fractionation are commonly found in cold prestellar cores and in the envelopes around young protostars. As it brings strong constraints to chemical models, deuterium chemistry is often used to infer core history or…
We present new models of the deuterium chemistry in protoplanetary disks, including, for the first time, multiply deuterated species. We use these models to explore whether observations in combination with models can give us clues as to…
To investigate how the abundance of N2H+ varies as massive clumps evolve, here we present a multi-wavelength study toward six molecular clouds. All of these clouds contain several massive clumps in different evolutionary stages of star…
Deuterium fractionation is known to enhance the [DCO+]/[HCO+] abundance ratio over the D/H elemental ratio of about 1e-5 in the cold and dense gas typically found in pre-stellar cores. We report the first detection and mapping of very…
Star formation activity in molecular clouds is often found to be correlated with the amount of material above a column density threshold of $\sim 10^{22} \, {\rm cm^{-2}}$. Attempts to connect this column density threshold to a ${\it…
Extremely high deuteration of several molecules have been observed around low mass protostars since a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply…
We have studied four complex organic molecules (COMs), methyl formate ($CH_3OCHO$), dimethyl ether ($CH_3OCH_3$), formamide ($NH_2CHO$), and ethyl cyanide ($C_2H_5CN$), towards a large sample of 39 high-mass star-forming regions…
Sulfur is one of the most abundant elements in the Universe, yet the sulfur budget inferred from the observed sulfur-bearing molecules in dense cores is significantly lower than expected. Starless and pre-stellar cores represent the…
The origin of the observed variability of the gas-phase D/H ratio in the local interstellar medium is still debated, and in particular the role of deuterium depletion onto dust grains. Here we extend the study of the relationship between…
A study of the chemical structure of the envelopes around a sample protostars is introduced. Physical models for the envelopes derived using 1D radiative transfer modeling of their dust continuum emission are used as input for Monte Carlo…
Deuterium fractionation becomes highly efficient in cold, dense cores where CO is frozen out. Cyclopropenylidene (c-C3H2), an early-formed carbon ring, and its deuterated isotopologues trace gas-phase deuteration in these environments. We…
The ratio between the two stable isotopes of nitrogen, $^{14}$N and $^{15}$N, is well measured in the terrestrial atmosphere ($\sim 272$), and in the pre-Solar nebula ($\sim 441$). Interestingly, some pristine Solar System materials show…
Although the deuterium fraction is known to be a powerful evolutionary tracer, its variation within individual molecular cloud cores is still poorly understood. The northern $\int$-shaped filament and 20 individual starless cores in the…
Observations of deuterium fractionation in the solar system, and in interstellar and circumstellar material, are commonly used to constrain the formation environment of volatiles. Toward protoplanetary disks, this approach has been limited…
The primordial abundance of deuterium (D/H) yields a measure of the density of baryons in the universe and is an important complement to determinations from cosmic microwave background (CMB) experiments. Indeed, the current small sample of…
We present the results of a single-pointing survey of 207 dense cores embedded in Planck Galactic Cold Clumps distributed in five different environments ($\lambda$ Orionis, Orion A, B, Galactic plane, and high latitudes) to identify dense…
We quantify the gas-phase abundance of deuterium and fractional contribution of stellar mass loss to the gas in cosmological zoom-in simulations from the Feedback In Realistic Environments project. At low metallicity, our simulations…
Context : Despite the low cosmic abundance of deuterium (D/H ~ 1e-5), large degrees of deuterium fractionation in molecules are observed in star forming regions with enhancements that can reach 13 orders of magnitude, which current models…
The 692 GHz para ground-state line of D2H+ has been detected at the Caltech Submillimeter Observatory towards the pre-stellar core 16293E. The derived D2H+ abundance is comparable to that of H2D+, as determined by observations of the 372…
The formation of singly and doubly deuterated isotopomers of formaldehyde and of singly, doubly, and multiply deuterated isotopomers of methanol on interstellar grain surfaces has been studied with a semi-empirical modified rate approach…