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Two-dimensional melting transitions for model colloids in presence of a one-dimensional external periodic potential are investigated using Monte Carlo simulation and Finite Size Scaling techniques. Here we explore a hard disk system with…

Statistical Mechanics · Physics 2009-11-13 Florian Bürzle , Peter Nielaba

We study here how phase transitions are induced in colloidal suspensions by a point-like heat source, an optically trapped metal oxide particle absorbing light. We find that thermophoresis increases the number density of colloids around the…

Soft Condensed Matter · Physics 2019-11-26 Nicolas Bruot , Hajime Tanaka

Motivated by old experiments on colloidal suspensions, we report molecular dynamics simulations of assemblies of hard spheres, addressing crystallization and glass formation. The simulations cover wide ranges of polydispersity s (standard…

Materials Science · Physics 2015-05-13 P. N. Pusey , E. Zaccarelli , C. Valeriani , E. Sanz , W. C. K. Poon , M. E. Cates

The liquid-gas phase diagram for polydisperse dipolar hard-sphere fluid with polydispersity in the hard-sphere size and dipolar moment is calculated using extension of the recently proposed thermodynamic perturbation theory for central…

Soft Condensed Matter · Physics 2012-07-16 Yu. V. Kalyuzhnyi , S. Hlushak , P. T. Cummings

Using Monte Carlo simulations, we systematically investigate the effect of particle size distribution on the phase behaviour of polydisperse hard disks. Compared with the commonly used Gaussian-like polydisperse hard disks [Commun. Phys. 2,…

Soft Condensed Matter · Physics 2020-11-04 Pablo Sampedro Ruiz , Ran Ni

Monodispersed spherical cadmium sulfide particles were used as a model system in order to explain the size selection in the formation of colloids by aggregation of nanosize subunits. Several procedures of mixing the reactants were employed…

Materials Science · Physics 2010-10-12 Sergiy Libert , Vyacheslav Gorshkov , Vladimir Privman , Dan Goia , Egon Matijevic

In a previous paper (J. Zhang {\it et al.}, J. Chem. Phys. {\bf 110}, 5318 (1999)) we introduced a model for polydisperse hard sphere mixtures that is able to adjust its particle-size distribution. Here we give the explanation of the…

Soft Condensed Matter · Physics 2009-11-07 Ronald Blaak , Jose A. Cuesta

The first goal of this article is to study the validity of the Zwanzig model for liquid crystals to predict transitions to inhomogeneous phases (like smectic and columnar) and the way polydispersity affects these transitions. The second…

Soft Condensed Matter · Physics 2009-11-10 Yuri Martinez-Raton , Jose A. Cuesta

It has been experimentally established in numerous cases that precipitation of monodispersed colloids from homogeneous solutions is a complex process. Specifically, it was found that in many systems nuclei, produced rapidly in a…

Materials Science · Physics 2010-09-22 Vladimir Privman , Dan V. Goia , Jongsoon Park , Egon Matijevic

Monodisperse ensembles of particles that have cluster crystalline phases at low temperatures can model a number of physical systems, such as vortices in type-1.5 superconductors, colloidal suspensions and cold atoms. In this work we study a…

Soft Condensed Matter · Physics 2019-04-29 Wenlong Wang , Rogelio Díaz-Méndez , Mats Wallin , Jack Lidmar , Egor Babaev

We describe two distinct approaches to obtaining cloud point densities and coexistence properties of polydisperse fluid mixtures by Monte Carlo simulation within the grand canonical ensemble. The first method determines the chemical…

Statistical Mechanics · Physics 2009-11-11 Matteo Buzzacchi , Peter Sollich , Nigel B. Wilding , Marcus Mueller

We conduct molecular dynamics computer simulations of a system of Lennard-Jones particles, polydisperse in both size and mass, at a fixed density and temperature. We test for and quantify systematic changes in dynamical properties that…

Statistical Mechanics · Physics 2009-11-07 N. Kiriushcheva , Peter H. Poole

Hard spheres with a polydispersity above approximately 8% are shown to crystallise into two phase-separated solid phases. A polydispersity above 8% is too large to be tolerated by a single solid phase but phase separation produces two…

Soft Condensed Matter · Physics 2009-10-31 Richard P. Sear

We investigate polydispersity effects on the average structure factor of colloidal suspensions of neutral particles with surface adhesion. A sticky hard sphere model alternative to Baxter's one is considered. The choice of factorizable…

Statistical Mechanics · Physics 2009-11-07 Domenico Gazzillo , Achille Giacometti

We report a Monte Carlo simulation study of the properties of highly asymmetric binary hard sphere mixtures. This system is treated within an effective fluid approximation in which the large particles interact through a depletion potential…

Statistical Mechanics · Physics 2009-11-11 Julio Largo , Nigel B. Wilding

The phase behavior of a model suspension of colloidal polydisperse platelets is studied using density-functional theory. Platelets are modelled as parallel rectangular prisms of square section $l$ and height $h$, with length and height…

Soft Condensed Matter · Physics 2016-07-06 Enrique Velasco , Yuri Martinez-Raton

Understanding the phase behaviour of mixtures continues to pose challenges, even for systems that might be considered "simple". Here we consider a very simple mixture of two colloidal and one non-adsorbing polymer species which can be…

We report the nematic and smectic ordering in a new aqueous suspension of monolayer $\alpha$-Zirconium phosphate platelets possessing a high polydispersity in diameter but uniform thickness. We observe an isotropic--nematic transition as…

Soft Condensed Matter · Physics 2015-05-14 Dazhi Sun , Hung-Jue Sue , Zhengdong Cheng , Yuri Martinez-Raton , Enrique Velasco

Because of long-wavelength fluctuations, the nature of solids and phase transitions in 2D are different from those in 3D systems, and have been heavily debated in past decades, in which the focus was on the existence of hexatic phase. Here,…

Soft Condensed Matter · Physics 2019-05-29 Pablo Sampedro Ruiz , Qun-li Lei , Ran Ni

The structural properties of polydisperse hard spheres in the presence of a hard wall are investigated via Monte Carlo simulation and density functional theory (DFT). Attention is focussed on the local density distribution $\rho(\sigma,z)$,…

Soft Condensed Matter · Physics 2009-11-10 Matteo Buzzacchi , Ignacio Pagonabarraga , Nigel B. Wilding