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Using the virial theorem it is shown that the hypothesis of the existence of the universal density functional is invalid.

Statistical Mechanics · Physics 2015-05-20 V. B. Bobrov , S. A. Trigger

We discuss some of the challenges that the DFT community faces in its quest for the truly universal energy density functional applicable over the entire nuclear chart.

Nuclear Theory · Physics 2017-08-23 T. Duguet , K. Bennaceur , T. Lesinski , J. Meyer

It is shown that, contrary to widely held beliefs, the potentials of spin-density-functional theory (SDFT) are not unique functionals of the spin densities. Explicit examples of distinct sets of potentials with the same ground-state…

Materials Science · Physics 2009-10-31 K. Capelle , G. Vignale

We investigate a density-functional theory (DFT) approach for an unpolarized trapped dilute Fermi gas in the unitary limit . A reformulation of the recent work of T. Papenbrock [Phys. Rev. A, {\bf 72}, 041602(R) (2005)] in the language of…

Other Condensed Matter · Physics 2009-11-11 Brandon P. van Zyl , D. A. W. Hutchinson , Melodie Need

Density functional theory (DFT) is an incredible success story. The low computational cost, combined with useful (but not yet chemical) accuracy, has made DFT a standard technique in most branches of chemistry and materials science.…

Chemical Physics · Physics 2015-06-03 Kieron Burke

Density-corrected density functional theory (DC-DFT) is enjoying substantial success in improving semilocal DFT calculations in a wide variety of chemical problems. This paper provides the formal theoretical framework and assumptions for…

Chemical Physics · Physics 2019-08-19 Stefan Vuckovic , Suhwan Song , John Kozlowski , Eunji Sim , Kieron Burke

The logical structure and the basic theorems of time-dependent current density functional theory (TDCDFT) are analyzed and reconsidered from the point of view of recently proposed time-dependent deformation functional theory (TDDefFT). It…

Strongly Correlated Electrons · Physics 2019-03-27 I. V. Tokatly

A recent paper (Phys. Rev A. 75, 022513 (2007), arXiv:cond-mat/0602020) challenges exact time-dependent density functional theory (TDDFT) on several grounds. We explain why these criticisms are either irrelevant or incorrect, and that TDDFT…

Other Condensed Matter · Physics 2009-11-13 Neepa T. Maitra , Kieron Burke , Robert van Leeuwen

I summarize Density Functional Theory (DFT) in a language familiar to quantum field theorists, and introduce several apparently novel ideas for constructing {\it systematic} approximations for the density functional. I also note that, at…

Materials Science · Physics 2015-03-11 T. Banks

A cornerstone of current-density functional theory (CDFT) in its paramagnetic formulation is proven. After a brief outline of the mathematical structure of CDFT, the lower semi-continuity and expectation valuedness of the CDFT…

Chemical Physics · Physics 2020-11-11 Simen Kvaal , Andre Laestadius , Erik I. Tellgren , Trygve U. Helgaker

The extension of the density functional theory (DFT) to include pairing correlations without formal violation of the particle-number conservation condition is described. This version of the theory can be considered as a foundation of the…

Nuclear Theory · Physics 2007-05-23 S. Krewald , V. B. Soubbotin , V. I. Tselyaev , X. Vinas

In the article "Universal Densities Exist for Every Finite Reference Measure" (IEEE Trans. Inform. Theory, vol. 69, no. 8, pp. 5277--5288, 2023) we neglected to mention relevant contributions of Boris Ryabko. We cited a source by him that…

Information Theory · Computer Science 2023-11-16 Łukasz Dębowski

Density functional theory (DFT) is used in thousands of papers each year, yet lack of universality reduces DFT's predictive capacity, and functionals may produce energy-density imbalances. The absolute electronegativity (\chi) and hardness…

Chemical Physics · Physics 2020-07-15 Klaus A. Moltved , Kasper P. Kepp

Density functional theory (DFT), one of the most widely utilized methods available to computational chemistry, fails to describe systems with statically correlated electrons. To address this shortcoming, in previous work we transformed DFT…

Chemical Physics · Physics 2023-01-02 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

This article is a rough, quirky overview of both the history and present state of the art of density functional theory. The field is so huge that no attempt to be comprehensive is made. We focus on the underlying exact theory, the origin of…

Chemical Physics · Physics 2015-05-20 Aurora Pribram-Jones , David A. Gross , Kieron Burke

These brief comments on the article in Phys. Rev. B 93, 155116 (2016), address an inadvertent misrepresentation of the capabilities of density functional theory (DFT) and of its local density approximation (LDA) in describing electronic and…

Materials Science · Physics 2016-10-18 Diola Bagayoko , Yacouba Issa Diakité , Chinedu E. Ekuma , Lashounda Franklin

Density functional theory is a successful branch of numerical simulations of quantum systems. While the foundations are rigorously defined, the universal functional must be approximated resulting in a `semi'-ab initio approach. The search…

Quantum Physics · Physics 2017-11-22 James Daniel Whitfield , Norbert Schuch , Frank Verstraete

Reliable predictions of nuclear properties are needed as much to answer fundamental science questions as in applications such as reactor physics or data evaluation. Nuclear density functional theory is currently the only microscopic, global…

Nuclear Theory · Physics 2015-01-23 N. Schunck , J. D. McDonnell , D. Higdon , J. Sarich , S. Wild

This comment criticizes the above paper by Xiao-Yin Pan and Viraht Sahni. It is shown that their formulation of "Physical Current Density Functional Theory" is, at best, a garbled reformulation of the Vignale-Rasolt current-density…

Materials Science · Physics 2012-08-22 G. Vignale , C. A. Ullrich , Klaus Capelle

We construct a density-functional formalism adapted to uniform external magnetic fields that is intermediate between conventional Density Functional Theory and Current-Density Functional Theory (CDFT). In the intermediate theory, which we…

Chemical Physics · Physics 2018-02-14 Erik I. Tellgren , Andre Laestadius , Trygve Helgaker , Simen Kvaal , Andrew M. Teale
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