Related papers: Liquid heat capacity in the approach from the soli…
Thermo-elasticity couples the deformation of an elastic (solid) body to its temperature and vice-versa. It is a solid-like property. Highlighting such property in liquids is a paradigm shift: it requires long-range collective interactions…
The generalized Gibbs free energy and enthalpy is derived in the framework of nonextensive thermodynamics by using the so-called physical temperature and the physical pressure. Some thermodynamical relations are studied by considering the…
We monitor the transformation of a liquid into an amorphous solid in simulations of a glass forming liquid by measuring the variation of a structural order parameter with either changing temperature or potential energy to establish the…
Based on two assumptions, the surface layer is flexible, and the internal energy of the latent heat of vaporization is completely utilized by the atoms for overcoming on the surface resistance of the liquid, the enthalpy of vaporization was…
We consider the stochastic heat equation whose solution is observed discretely in space and time. An asymptotic analysis of power variations is presented including the proof of a central limit theorem. It generalizes the theory from…
In this paper we study properties of a variant of the $1/2$-caloric capacity, called $1/2$-symmetric caloric capacity. The latter is associated simultaneously with the $1/2$-fractional heat equation and its conjugate. We establish its…
At first glance, the title of this work seems to be improper. And the reason is well known. Since blackbody pressure depends only on temperature, one cannot take the derivative of the thermodynamic quantities with respect to one of them,…
The relativistic continuity equations for the extensive thermodynamic quantities are derived based on the divergence theorem in Minkowski space outlined by St\"uckelberg. This covariant approach leads to a relativistic formulation of the…
Starting for the Stillinger and Weber expression for the free energy of supercooled liquids, we extend the free energy to the case in which two time scales separate and the system is in quasi-equilibrium. The concept of an effective…
For free particles in a simple harmonic potential plus a weak anharmonicity, characterized by a set of anharmonic parameters, Newtonian mechanics asserts that there is a renormalization of the natural frequency of the periodic motion; and…
We demonstrate that the thermodynamics of a perfect fluid describing baryonic matter can, in certain limits, lead to an equation of state similar to that of dark energy. We keep the cosmic fluid equation of state quite general by just…
The one-dimensional problem of the nonlinear heat equation is considered. We assume that the heat flow in the origin of coordinates is the power function of time and the initial temperature is zero. Approximate solutions of the problem are…
An experimental proposal to test the existence of a liquid-liquid critical point in water, based on high pressure calorimetric measurements, is presented on this paper. Considering the existence of an intramolecular correlation in the water…
We obtain new constraints for the modular energy of general states by using the monotonicity property of relative entropy. In some cases, modular energy can be related to the energy density of states and these constraints lead to…
We investigate the equilibrium of a fluid in contact with a solid boundary through a density-functional theory. Depending on the conditions, the fluid can be in one phase, gas or liquid, or two phases, while the wall induces an external…
We study the heat capacity of a static system of self-gravitating radiations analytically in the context of general relativity. To avoid the complexity due to a conical singularity at the center, we excise the central part and replace it…
The heat flow between a quantum system and its reservoir is analyzed when initially both are in a separable thermal state and asymptotically approach a correlated equilibrium. General findings are illustrated for specific systems and…
In the present chapter, we discuss an approach for transition from discrete to continuum description of thermomechanical behavior of solids. The transition is carried out for several anharmonic systems: one-dimensional crystal,…
We present an accurate free-energy functional for liquid water written in terms of a set of effective potential fields in which fictitious noninteracting water molecules move. The functional contains an \emph{exact} expression of the…
We consider the amount of work which can be extracted from a heat bath using a bipartite state shared by two parties. In general it is less then the amount of work extractable when one party is in possession of the entire state. We derive…