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Related papers: Exciton character in picene molecular solids

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We have examined the singlet excitons in two representatives of acene-type (tetracene and pentacene) and phenacene-type (chrysene and picene) molecular crystals, respectively, using electron energy-loss spectroscopy at low temperatures. We…

We have carried out electron energy-loss investigations of the lowest singlet excitons in pentacene at 20 K. Our studies allow to determine the full exciton band structure in the a*,b* reciprocal lattice plane. The lowest singlet exciton…

Materials Science · Physics 2012-06-01 Friedrich Roth , Roman Schuster , Andreas König , Martin Knupfer , Helmuth Berger

Mostly optical spectroscopies are used to investigate existence of excitons, Mott transitions and other exquisite excitonic condensed phases of matter. On the other hand, electrical signatures of excitons are hardly explored. Here we…

Mesoscale and Nanoscale Physics · Physics 2014-06-18 Kanika Bansal , Shouvik Datta

Using a combination of ultraviolet-vacuum ultraviolet reflectivity and spectroscopic ellipsometry, we observe a resonant exciton at an unusually high energy of 6.3eV in epitaxial graphene. Surprisingly, the resonant exciton occurs at room…

Excitons are bosonic quasiparticles with a variety of applications in optoelectronics, photosyn thesis, and dissipationless informatics, and their lifetime can become sufficiently long to form a quantum condensate. While exciton…

Strongly Correlated Electrons · Physics 2025-07-23 Siwon Lee , Kyung-Hwan Jin , SeongJin Kwon , Hyunjin Jung , Choongjae Won , Sang-Wook Cheong , Gil Young Cho , Jaeyoung Kim , Han Woong Yeom

Recently, a new organic superconductor, K-intercalated Picene with high transition temperatures $T_c$ (up to 18\,K) has been discovered. We have investigated the electronic properties of the undoped relative, solid picene, using a…

Excitons are spin integer particles that are predicted to condense into a coherent quantum state at sufficiently low temperature, and exciton condensates can be realized at much higher temperature than condensates of atoms because of strong…

We have studied the low energy electronic excitations of C60 using momentum dependent electron energy-loss spectroscopy in transmission. The momentum dependent intensity of the gap excitation allows the first direct experimental…

Strongly Correlated Electrons · Physics 2009-10-31 M. Knupfer , J. Fink

We performed electron energy-loss spectroscopy studies in order to get a deeper insight into the electronic properties of potassium intercalated picene, a recently discovered superconductor. A comparison of the loss function of the undoped…

Superconductivity · Physics 2011-04-05 Friedrich Roth , Benjamin Mahns , Bernd Büchner , Martin Knupfer

Using first principles many-body theory methods (GW+BSE) we demonstrate that optical properties of graphane are dominated by localized charge-transfer excitations governed by enhanced electron correlations in a two-dimensional dielectric…

Materials Science · Physics 2015-05-18 Pierluigi Cudazzo , Claudio Attacalite , Ilya V. Tokatly , Angel Rubio

An excitonic insulator phase is expected to arise from the spontaneous formation of electron-hole pairs (excitons) in semiconductors where the exciton binding energy exceeds the size of the electronic band gap. At low temperature, these…

Strongly Correlated Electrons · Physics 2022-09-02 Selene Mor , Marc Herzog , Claude Monney , Julia Stähler

Excitonic effects due to the correlation of electrons and holes in excited states of matter dominate the optical spectra of many interesting materials. They are usually studied in the long-wavelength limit. Here we investigate excitons at…

Materials Science · Physics 2023-04-18 Vitaly Gorelov , Lucia Reining , Matteo Gatti

The excited state dynamics in organic semiconductors plays an important role for many processes associated with light absorption and emission. We have studied the momentum dependence of the lowest singlet excitons in tetracene molecular…

Materials Science · Physics 2015-11-19 Friedrich Roth , Markus Nohr , Silke Hampel , Martin Knupfer

The electronic excitation spectra of undoped, and potassium as well as calcium doped phenantrene-type hydrocarbons have been investigated using electron energy-loss spectroscopy (EELS) in transmission. In the undoped materials, the lowest…

Materials Science · Physics 2015-02-26 Friedrich Roth , Martin Knupfer

Potassium-doped picene (K$_x$picene) has recently been reported to be a superconductor at $x=3$ with critical temperatures up to 18 K. Here we study the electronic structure of K-doped picene films by photoelectron spectroscopy and {\it ab…

Strongly Correlated Electrons · Physics 2015-06-11 Andreas Ruff , Michael Sing , Ralph Claessen , Hunpyo Lee , Milan Tomić , Harald O. Jeschke , Roser Valentí

The exciton dispersion is examined in the case of four selected prototypical molecular solids: pentacene,tetracene,picene,chrysene. The model parameters are determined by fitting to experimental data obtained by inelastic electron…

Excitons and plasmons are the two most fundamental types of collective electronic excitations occurring in solids. Traditionally, they have been studied separately using bulk techniques that probe their average energetic structure over…

Significant excitonic effects were observed in graphene by measuring its optical conductivity in a broad spectral range including the two-dimensional {\pi}-band saddle-point singularities in the electronic structure. The strong…

Materials Science · Physics 2015-05-20 Kin Fai Mak , Jie Shan , Tony F. Heinz

We investigate excitonic transitions in a h-BN encapsulated monolayer $\textrm{MoS}_2$ phototransistor by photocurrent spectroscopy at cryogenic temperature (T = 5 K). The spectra presents excitonic peaks with linewidths as low as 8 meV,…

Biased bilayer graphene (BBG) is a variable band gap semiconductor, with a strongly field-dependent band gap of up to $300 \, \text{meV}$, making it of particular interest for graphene-based nano-electronic and -photonic devices. The…

Mesoscale and Nanoscale Physics · Physics 2022-03-21 Mikkel Ohm Sauer , Thomas Garm Pedersen
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