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We consider the reduced dynamics of a molecular chain weakly coupled to a phonon bath. With a small and constant inhomogeneity in the coupling, the excitation relaxation rates are obtained in closed form. They are dominated by transitions…

Statistical Mechanics · Physics 2021-04-16 B. A. Tay

In natural and artificial light-harvesting complexes (LHC) the resonant energy transfer (RET) between chromophores enables an efficient and directional transport of solar energy between collection and reaction centers. The detailed…

Rate equations are used to model spectroscopic observation of incoherent energy transfer in light-harvesting antenna systems based upon known structures. A two-parameter two-dimensional model is proposed. The transfer rates obtained, by…

Biological Physics · Physics 2009-10-31 Juhi-Lian Julian Ting

Computationally tractable and reliable, albeit approximate, methods for studying exciton transport in molecular aggregates immersed in structured bosonic environments have been actively developed. Going beyond the lowest-order (Born)…

Chemical Physics · Physics 2024-11-28 Veljko Janković , Tomáš Mančal

The energy-transfer efficiency of the natural photosynthesis system seems to be perfectly optimized during the evolution for millions of years. However, how to enhance the efficiency in the artificial light-harvesting systems is still…

Optics · Physics 2025-12-30 Jun Wang , Rui Li , Yi Li , Kai-Ya Zhang , Qing Ai

A generalized master equation (GME) governing quantum evolution of modular exciton density (MED) is derived for large scale light harvesting systems composed of weakly interacting modules of multiple chromophores. The GME-MED offers a…

Quantum Physics · Physics 2013-11-12 Seogjoo Jang , Stephan Hoyer , Graham Fleming , K. Birgitta Whaley

Heat dissipation is ubiquitous in living systems, which constantly convert distinct forms of energy into each other. The transport of thermal energy in liquids and even within proteins is well understood but kinetic energy transfer across a…

Soft Condensed Matter · Physics 2026-01-07 Brandon Neff , Matthias Heyden

We investigated the exciton transfer dynamics in photosynthetic light-harvesting complex 2 (LH2) coupled to an optical microcavity. Using computational simulations based on Redfield theory, we analyzed how microcavity coupling influences…

Atomic and Molecular Clusters · Physics 2025-12-30 Ilmari Rosenkampff , Tõnu Pullerits

The present review is devoted to our recent studies on the excitonic motion in photosynthetic systems. In photosynthesis, the light photon is absorbed to create an exciton in the antenna complex of the photosynthetic pigments. This exciton…

Statistical Mechanics · Physics 2012-03-02 Navinder Singh

Energy-harvesting and wireless power transfer in cooperative relaying networks have recently attracted a considerable amount of research attention. Most of the existing work on this topic however focuses on Rayleigh fading channels which…

Signal Processing · Electrical Eng. & Systems 2018-06-26 Khaled M. Rabie , Bamidele Adebisi , Mohamed-Slim Alouini

In the primary step of light-harvesting, the energy of a photon is captured in antenna chlorophyll as an exciton. Its efficient conversion to stored chemical potential occurs in the special pair reaction center, which has to be reached by…

Due the alarming rate of climate change, the implementation of efficient CO$_2$ capture has become crucial. This project aims to create an algorithm that predicts the uptake of CO$_2$ adsorbing Metal-Organic Frameworks (MOFs) by using…

Machine Learning · Computer Science 2021-10-13 Mahati Manda

Photosystem II (PSII) can achieve near-unity quantum efficiency of light harvesting in ideal conditions and can dissipate excess light energy as heat to prevent formation of reactive oxygen species under light stress. Understanding how this…

Chemical Physics · Physics 2024-12-18 Johanna L. Hall , Shiun-Jr Yang , David T. Limmer , Graham R. Fleming

We consider the dependence of the electron transfer in photosynthetic complexes on correlation properties of random fluctuations of the protein environment. The electron subsystem is modeled by a finite network of connected electron…

Biological Physics · Physics 2015-06-23 Alexander I. Nesterov , Gennady P. Berman

We explore various design principles for efficient excitation energy transport in complex quantum systems. We investigate energy transfer efficiency in randomly disordered geometries consisting of up to 20 chromophores to explore spatial…

Quantum Physics · Physics 2014-02-25 M. Mohseni , A. Shabani , S. Lloyd , Y. Omar , H. Rabitz

Usually the study of energy-transfer in the light harvesting complex is limited by a single-exciton motion along the antenna. Starting from the many-body Schr\"odinger equation, we derived Lindblad-type Master equations describing the…

Chemical Physics · Physics 2017-06-13 Shmuel Gurvitz , Gennady P. Berman , Richard T. Sayre

Organic/inorganic hybrid systems offer great potential for novel solar cell design combining the tunability of organic chromophore absorption properties with high charge carrier mobilities of inorganic semiconductors. However, often such…

Transition-metal-oxide (TMO) heterostructures are promising candidates for building photon-harvesting devices which can exploit optimal quantum transport of charge excitations generated by light absorption. Here we address the explicit role…

Quantum Physics · Physics 2020-04-22 Chahan M. Kropf , G. Luca Celardo , Claudio Giannetti , Fausto Borgonovi

Context: Thermal conductivity provides important contributions to the energy evolution of the upper solar atmosphere, behaving as a non-linear concentration-dependent diffusion equation. Recently, different methods have been offered as…

Solar and Stellar Astrophysics · Physics 2024-12-11 George Cherry , Boris Gudiksen , Mikolaj Szydlarski

Stunningly large exciton transfer rates in the light harvesting complex of photosynthesis, together with recent experimental 2D spectroscopic data, have spurred a vivid debate on the possible quantum origin of such efficiency. Here we show…

Quantum Physics · Physics 2011-08-29 Torsten Scholak , Thomas Wellens , Andreas Buchleitner