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Level crossings in the ground state of ions occur when the nuclear charge Z and ion charge Z_ion are varied along an isoelectronic sequence until the two outermost shells are nearly degenerate. We examine all available level crossings in…

Atomic Physics · Physics 2012-09-11 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong

We evaluate the feasibility of using magnetic-dipole (M1) transitions in highly-charged ions as a basis of an optical atomic clockwork of exceptional accuracy. We consider a range of possibilities, including M1 transitions between clock…

Atomic Physics · Physics 2015-06-23 V. I. Yudin , A. V. Taichenachev , A. Derevianko

We review a number of highly charged ions which have optical transitions suitable for building extremely accurate atomic clocks. This includes ions from Hf$^{12+}$ to U$^{34+}$, which have the $4f^{12}$ configuration of valence electrons,…

Atomic Physics · Physics 2015-06-23 V. A. Dzuba , V. V. Flambaum

We study electronic transitions in highly-charged Cf ions that are within the frequency range of optical lasers and have very high sensitivity to potential variations in the fine-structure constant, alpha. The transitions are in the optical…

Atomic Physics · Physics 2012-09-11 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , A. Ong

We have developed a broadly-applicable approach that drastically increases the ability to accurately predict properties of complex atoms. We applied it to the case of Ir$^{17+}$, which is of particular interest for the development of novel…

Atomic Physics · Physics 2020-04-29 C. Cheung , M. S. Safronova , S. G. Porsev , M. G. Kozlov , I. I. Tupitsyn , A. I. Bondarev

We study atomic systems that are in the frequency range of optical atomic clocks and have enhanced sensitivity to potential time-variation of the fine structure constant, alpha. The high sensitivity is due to coherent contributions from…

Atomic Physics · Physics 2010-09-16 J. C. Berengut , V. A. Dzuba , V. V. Flambaum

We study transitions between ground and low-energy excited states of heavy ions corresponding to s-d single-electron transitions or s^2-d^2 double-electron transitions. The large nuclear charge Z and significant change in angular momentum…

Atomic Physics · Physics 2011-12-02 J. C. Berengut , V. A. Dzuba , V. V. Flambaum

We propose a novel class of atomic clocks based on highly charged ions. We consider highly-forbidden laser-accessible transitions within the $4f^{12}$ ground-state configurations of highly charged ions. Our evaluation of systematic effects…

Atomic Physics · Physics 2016-10-05 Andrei Derevianko , V. A. Dzuba , V. V. Flambaum

We examine energy level-crossings of fine-structure (FS) levels in the heavier highly charged ions (HCIs) with $d^6$ and $d^8$ configurations. From the analysis, we find that some of these HCIs are tailor-made for atomic clocks with quality…

Atomic Physics · Physics 2023-07-28 Yan-mei Yu , B. K. Sahoo

Theories unifying gravity with other interactions suggest spatial and temporal variation of fundamental "constants" in the Universe. A change in the fine structure constant, alpha, could be detected via shifts in the frequencies of atomic…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-20 J. C. Berengut , V. A. Dzuba , V. V. Flambaum , J. A. King , M. G. Kozlov , M. T. Murphy , J. K. Webb

Dependence of transition frequencies on the fine structure constant $\alpha=e^2/\hbar c$ is calculated for several many-electron systems which are used or planned to be used in the laboratory search for the time variation of the fine…

Atomic Physics · Physics 2009-11-13 V. A. Dzuba , V. V. Flambaum

Numerous few-electron atomic systems are considered which can be used effectively for observing a potential variation of the fine-structure constant $\alpha$ and the electron-proton mass ratio $m_e/m_p$. We examine optical magnetic dipole…

Motivated by recent measurements for several alkali-metal atoms and alkali-metal-like ions, we perform a detailed study of electric dipole (E1) transition amplitudes in K, Ca+, Rb, Sr+, Cs, Ba+, Fr, and Ra+, which are of interest for…

Atomic Physics · Physics 2023-06-01 B. M. Roberts , C. J. Fairhall , J. S. M. Ginges

We identify laser-accessible transitions in group 16-like highly charged ions as candidates for high-accuracy optical clocks, including S-, Se-, and Te-like systems. For this class of ions, the ground $^{3}P_{J}$ fine structure manifold…

Atomic Physics · Physics 2022-10-06 Saleh O. Allehabi , S. M. Brewer , V. A. Dzuba , V. V. Flambaum , K. Beloy

We use advanced computational techniques to study the electronic structure of the Hf$^{12+}$ ion, with the goal of assessing its potential for use in highly accurate atomic optical clocks and search for new physics. Such clocks should…

Atomic Physics · Physics 2025-11-04 Saleh O. Allehabi , V. A. Dzuba , V. V. Flambaum

Molecular ions can be held in a chain of laser-cooled atomic ions by sympathetic cooling. This system is ideal for performing high-precision molecular spectroscopy with applications in astrochemistry and fundamental physics. Here we show…

Atomic Physics · Physics 2015-08-20 Ncamiso B. Khanyile , Gang Shu , Kenneth R. Brown

Highly charged ions of heavy actinides from uranium to einsteinium are studied theoretically to find optical transitions sensitive to the variation of the fine structure constant. A number of promising transitions have been found in ions…

Atomic Physics · Physics 2024-05-21 V. A. Dzuba , V. V. Flambaum

We report precision spectroscopy of ionic-core transitions in alkaline-earth Rydberg atoms. We demonstrate high-resolution measurements of isotope shifts and hyperfine splitting of dipole transitions in ionic cores which have not been…

Atomic Physics · Physics 2026-05-20 Mitsuki Odahara , Shinsuke Haze

We propose 10 highly-charged ions as candidates for the development of next generation atomic clocks, quantum information, and search for $\alpha$-variation. They have long-lived metastable states with transition frequencies to the ground…

Atomic Physics · Physics 2015-06-19 M. S. Safronova , V. A. Dzuba , V. V. Flambaum , U. I. Safronova , S. G. Porsev , M. G. Kozlov

We estimate the nuclear polarizability correction to atomic transition frequencies in various helium isotopes. This effect is non-negligible for high precision tests of quantum electrodynamics or accurate determination of the nuclear charge…

Nuclear Theory · Physics 2015-06-26 K. Pachucki , A. M. Moro
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