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We report first principles calculations of the phonon dispersions of PbTe both for its observed structure and under compression. At the experimental lattice parameter we find a near instability of the optic branch at the zone center, in…

Materials Science · Physics 2008-10-27 Jiming An , Alaska Subedi , David J. Singh

Crystals of tetracene have been studied by means of lattice phonon Raman spectroscopy as a function of temperature and pressure. Two different phases (polymorphs I and II) have been obtained, depending on sample preparation and history.…

We use a hybrid strategy to obtain anharmonic frequency shifts and lifetimes of phonon quasi-particles from first principles molecular dynamics simulations in modest size supercells. This approach is effective irrespective of crystal…

Materials Science · Physics 2015-06-18 Dong-Bo Zhang , Tao Sun , Renata M. Wentzcovitch

The diffusion of large databases collecting different kind of material properties from high-throughput density functional theory calculations has opened new paths in the study of materials science thanks to data mining and machine learning…

Materials Science · Physics 2018-01-04 Guido Petretto , Xavier Gonze , Geoffroy Hautier , Gian-Marco Rignanese

We formulate a first-principle scheme for structural optimization at finite temperature ($T$) based on the self-consistent phonon (SCP) theory, which accurately takes into account the effect of strong phonon anharmonicity. The…

Materials Science · Physics 2022-12-20 Ryota Masuki , Takuya Nomoto , Ryotaro Arita , Terumasa Tadano

Phonons, quantized vibrations of the atomic lattice, are fundamental to understanding thermal transport, structural stability, and phase behavior in crystalline solids. Despite advances in computational materials science, most predictions…

Materials Science · Physics 2026-01-15 Huiju Lee , Zhi Li , Jiangang he , Yi Xia

While the vibrational thermodynamics of materials with small anharmonicity at low temperatures has been understood well based on the harmonic phonons approximation; at high temperatures, this understanding must accommodate how phonons…

Materials Science · Physics 2015-10-20 Tian Lan

This article reviews the theory of electron-phonon interactions in solids from the point of view of ab-initio calculations. While the electron-phonon interaction has been studied for almost a century, predictive non-empirical calculations…

Materials Science · Physics 2017-03-08 Feliciano Giustino

Structural phase transitions and soft phonon modes pose a longstanding challenge to computing electron-phonon (e-ph) interactions in strongly anharmonic crystals. Here we develop a first-principles approach to compute e-ph scattering and…

Materials Science · Physics 2018-12-04 Jin-Jian Zhou , Olle Hellman , Marco Bernardi

{\it Ab initio\} calculations have been successfully used for evaluating lattice dynamical properties of solids within the (quasi-)harmonic approximation (i.e., assuming non-interacting phonons with infinite lifetimes), but it remains…

Computational Physics · Physics 2019-11-25 Fei Zhou , Weston Nielson , Yi Xia , Vidvuds Ozolins

We compute the phonon dispersion, density of states, and the Gr\"uneisen parameters of bulk palladium in the combined density functional theory (DFT) and dynamical mean-field theory (DMFT). We find good agreement with experimental results…

Strongly Correlated Electrons · Physics 2020-02-20 W. H. Appelt , A. Östlin , I. Di Marco , I. Leonov , M. Sekania , D. Vollhardt , L. Chioncel

Using the two-temperature model for ultrafast matter (UFM), we compare the equation of state, pair-distribution functions $g(r)$, and phonons using the neutral pseudoatom (NPA) model with results from density-functional theory (DFT) codes…

Materials Science · Physics 2017-04-12 Louis Harbour , Chandre M. Dharma-wardana , Dennis D. Klug , Laurent J. Lewis

We report first principles linear response calculations on NaCoO$_2$. Phonon frequencies and eigenvectors are obtained throughout the Brillouin zone for two geometries with different Na site occupancies. While most of the phonon modes are…

Materials Science · Physics 2007-05-23 Zhenyu Li , Jinlong Yang , J. G. Hou , Qingshi Zhu

In this work, we present a software package in Python for high-throughput first-principles calculations of thermodynamic properties at finite temperatures, which we refer to as DFTTK (Density Functional Theory Tool Kit). DFTTK is based on…

We present a first principles molecular dynamics approach that is based on time-reversible ex- tended Lagrangian Born-Oppenheimer molecular dynamics [Phys. Rev. Lett. 100, 123004 (2008)] in the limit of vanishing self-consistent field…

Chemical Physics · Physics 2015-06-18 Petros Souvatzis , Anders M. N. Niklasson

As a fundamental physical quantity of thermal phonons, temporal coherence participates in a broad range of thermal and phononic processes, while a clear methodology for the measurement of phonon coherence is still lacking. In this Lettter,…

Applied Physics · Physics 2023-05-03 Zhongwei Zhang , Yangyu Guo , Marc Bescond , Masahiro Nomura , Sebastian Volz , Jie Chen

Phonon modes within pristine crystalline resonators now routinely reach the quantum ground state. Such systems are attractive for quantum information science applications, as advanced fabrication and processing can enable relatively long…

Mesoscale and Nanoscale Physics · Physics 2026-02-26 Ryan O. Behunin , Taylor Ray , Dylan Chapman , Andrew J. Shepherd , Yizhi Luo , Peter T. Rakich

We determine the survival probability and first-passage time (FPT) to capture for a harmonically trapped particle, diffusing outside an absorbing spherical boundary by directly solving the differential equation for the survival probability.…

Mathematical Physics · Physics 2025-06-18 Tianyu Yuan , Ivan Surovtsev , Megan C. King , Simon G. J. Mochrie

In this paper the phonon self energy produced by anharmonicity is calculated using second order many body perturbation theory for all bcc, fcc and hcp transition metals. The symmetry properties of the phonon interactions are used to obtain…

Materials Science · Physics 2015-05-27 Laurent Chaput , Atsushi Togo , Isao Tanaka , Gilles Hug

Effective harmonic methods allow for calculating temperature dependent phonon frequencies by incorporating the anharmonic contributions into an effective harmonic Hamiltonian. The systematic errors arising from such an approximation are…

Materials Science · Physics 2019-06-05 Erki Metsanurk , Mattias Klintenberg
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