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We use x-ray photon correlation spectroscopy to investigate the dynamics of a high volume fraction emulsion creaming under gravity. The dodecane-in-water emulsion has interfaces stabilized solely by colloidal particles (silica). The samples…

Soft Condensed Matter · Physics 2009-11-13 E. M. Herzig , A. Robert , D. D. van 't Zand , L. Cipelletti , P. N. Pusey , P. S. Clegg

Binary mixture of oppositely charged of colloids can be used to stabilize water-in-oil or oil-in-water emulsions. A Monte Carlo simulation study to address the effect of charge ratio of colloids on the stability of Pickering emulsions is…

Soft Condensed Matter · Physics 2015-12-09 Sam David Christdoss Pushpam , Madivala G. Basavaraj , Ethayaraja Mani

Nanostructured materials formed via kinetically controlled self-assembly processes gather more interest nowadays. Bicontinuous emulsion gels stabilized by colloidal particles, called bijels, are attractive materials in soft-matter as they…

Molecular dynamics simulations are used to demonstrate that a binary solvent can be used to stratify colloidal mixtures when the suspension is rapidly dried. The solvent consists of two components, one more volatile than the other. When…

Soft Condensed Matter · Physics 2023-11-01 Binghan Liu , Gary S. Grest , Shengfeng Cheng

We demonstrate that the formation of bicontinuous emulsions stabilized by interfacial particles (bijels) is more robust when nanoparticles rather than microparticles are used. Emulsification via spinodal demixing in the presence of nearly…

Soft Condensed Matter · Physics 2015-09-30 M. Reeves , A. T. Brown , A. B. Schofield , M. E. Cates , J. H. J. Thijssen

Spontaneous phase separation, or demixing, is important in biological phenomena such as cell sorting. In particle-based models, an open question is whether differences in diffusivity can drive such demixing. While…

Soft Condensed Matter · Physics 2023-07-10 Erin McCarthy , Ojan Damavandi , Raj Kumar Manna , M. Lisa Manning

This paper presents the results of a rheological study of thermotropic nematic colloids aggregated into cellular structures. Small sterically stabilised PMMA particles dispersed in a liquid crystal matrix densely pack on cell interfaces,…

Soft Condensed Matter · Physics 2009-10-31 V. J. Anderson , E. M. Terentjev

Creating amorphous solid states by randomly bonding an ensemble of dense liquid monomers is a common procedure which is applied to create a variety of materials such as epoxy resins, colloidal gels, and vitrimers. The properties of the…

Soft Condensed Matter · Physics 2024-01-26 Misaki Ozawa , Jean-Louis Barrat , Walter Kob , Francesco Zamponi

We explore the conditions under which colloids can be stabilized by the addition of smaller particles. The largest repulsive barriers between colloids occur when the added particles repel each other with soft interactions, leading to an…

Soft Condensed Matter · Physics 2007-05-23 S. Karanikas , A. A. Louis

Locally (re)structuring colloidal gels $\unicode{x2013}$ micron-sized particles forming a connected network with arrested dynamics $\unicode{x2013}$ enables precise tuning of the micromechanical and -rheological properties of the system. A…

Soft Condensed Matter · Physics 2022-11-07 Kim William Torre , Joost de Graaf

We investigate the behavior of a mixture of asymmetric colloidal dumbbells and emulsion droplets by means of kinetic Monte Carlo simulations. The evaporation of the droplets and the competition between droplet-colloid attraction and…

Soft Condensed Matter · Physics 2016-05-24 Hai Pham Van , Andrea Fortini , Matthias Schmidt

Computer modeling and simulations are performed to investigate capillary bridges spontaneously formed between closely packed colloidal particles in phase separating liquids. The simulations reveal a self-stabilization mechanism that…

Materials Science · Physics 2013-02-08 Tian-Le Cheng , Yu U. Wang

We study a chemically active binary mixture undergoing phase separation and show that under non-equilibrium conditions, stable liquid spherical shells can form via a spinodal instability in the droplet center. A single liquid shell tends to…

Soft Condensed Matter · Physics 2023-06-21 Jonathan Bauermann , Giacomo Bartolucci , Job Boekhoven , Christoph A. Weber , Frank Jülicher

We study the transition of a granular packing from liquid to solid bonding in the course of drying. The particles are initially wetted by a liquid brine and the cohesion of the packing is ensured by capillary forces, but the crystallization…

Soft Condensed Matter · Physics 2012-04-16 Jean-Yves Delenne , Fabien Soulié , Moulay Saïd El Youssoufi , Farhang Radjaï

We demonstrate a novel route of spatially organizing the colloid arrangements on the polymer-grafted substrate by use of self-consistent field and density functional theories. We find that grafting of polymers onto a substrate can…

Soft Condensed Matter · Physics 2007-05-23 Kang Chen , Yu-qiang Ma

We study the non-equilibrium coarsening dynamics of a binary liquid solvent around a colloidal particle in a presence of a time-dependent temperature gradient that emerges after temperature quench of a suitably coated colloid surface. The…

Soft Condensed Matter · Physics 2018-11-30 Sutapa Roy , Anna Maciolek

Interactions between colloidal particles have hitherto usually been fixed by the suspension composition. Recent experimental developments now enable the control of interactions \emph{in-situ}. Here we use Brownian dynamics simulations to…

Soft Condensed Matter · Physics 2017-02-08 C. Patrick Royall , Alex Malins

We investigate sedimentation of model hard sphere-like colloidal dispersions confined in horizontal capillaries using laser scanning confocal microscopy, dynamical density functional theory, and Brownian dynamics computer simulations. For…

Soft Condensed Matter · Physics 2009-11-13 C. Patrick Royall , Joachim Dzubiella , Matthias Schmidt , Alfons van Blaaderen

Attractive colloidal particles can form a disordered elastic solid or gel when quenched into a two-phase region, if the volume fraction is sufficiently large. When the interactions are comparable to thermal energies the stress-bearing…

Soft Condensed Matter · Physics 2014-03-13 Lisa J. Teece , James M. Hart , Kerry Yen Ni Hsu , Stephen Gilligan , Malcolm A. Faers , Paul Bartlett

The assembly of colloidal particles at liquid/liquid or air/liquid interfaces is a versatile procedure to create microstructured monolayers and study their behavior under compression. When combined with soft and deformable particles such as…

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