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The influence of molecular vibrations on dissociative adsorption is studied by six-dimensional quantum dynamical calculations. For the system H_2 at Pd(100), which possesses non-activated pathways, it is shown that large vibrational effects…

mtrl-th · Physics 2009-10-30 Axel Gross , Matthias Scheffler

We study the interplay between strong electron-electron and electron-phonon interactions within a two-orbital molecule coupled to metallic leads, taking into account Holstein-like coupling of a local phonon mode to the molecular charge as…

Strongly Correlated Electrons · Physics 2013-04-26 G. I. Luiz , E. Vernek , L. Deng , K. Ingersent , E. V. Anda

The rotational excitation of the three asymmetric-top molecular ion isotopologues H$_2$O$^+$, HDO$^+$, and D$_2$O$^+$ is studied theoretically using a combined framework of electron-molecule R-matrix scattering theory, multichannel…

Atomic Physics · Physics 2026-03-19 Joshua Forer

Electron-phonon and electron-electron interactions are in competition in determining the properties of molecular charge transfer conductors and superconductors. The direct influence of phonons on the electron-electron interaction was not…

Strongly Correlated Electrons · Physics 2009-10-31 M. Meneghetti

We show that individual vibrational modes in single-molecule junctions with asymmetric molecule-lead coupling can be selectively excited by applying an external bias voltage. Thereby, a non-statistical distribution of vibrational energy can…

Mesoscale and Nanoscale Physics · Physics 2017-09-13 R. Volkovich , R. Härtle , M. Thoss , U. Peskin

The influence of multiple vibrational modes on current fluctuations in electron transport through single-molecule junctions is investigated. Our analysis is based on a generic model of a molecular junction, which comprises a single…

Mesoscale and Nanoscale Physics · Physics 2014-09-26 C. Schinabeck , R. Härtle , H. B. Weber , M. Thoss

We study the coupling of internal electronic excitations to vibrational modes of the external motion of ultracold atoms in an optical lattice. For different ground and excited state potentials the on-site coupling of excitations and…

Quantum Physics · Physics 2009-08-11 Hashem Zoubi , Helmut Ritsch

Carbon $1s$ core-hole excitation of the molecular anion C$_2^-$ has been experimentally studied at high resolution by employing the photon-ion merged-beams technique at a synchrotron light source. The experimental cross section for…

We report first principles analysis of electron-phonon coupling in molecular devices under external bias voltage and during current flow. Our theory and computational framework are based carrying out density functional theory within the…

Materials Science · Physics 2009-11-11 N. Sergueev , D. Roubtsov , Hong Guo

Lattice vibrations of point defects are essential for understanding non-radiative electron and hole capture in semiconductors as they govern properties including persistent photoconductivity and Shockley-Read-Hall recombination rate.…

Materials Science · Physics 2019-08-07 Sunghyun Kim , Samantha N. Hood , Aron Walsh

Devices for nano- and molecular size electronics are currently a focus of research aimed at an efficient current rectification and switching. A few generic molecular scale devices are reviewed here on the basis of first-principles and model…

Soft Condensed Matter · Physics 2015-06-25 A. M. Bratkovsky

The interplay of electron-electron and electron-phonon interactions is studied analytically in the Kondo regime. A Holstein electron-phonon coupling is shown to produce a weakening of the gate voltage dependence of the Kondo temperature and…

Strongly Correlated Electrons · Physics 2007-05-23 C. A. Balseiro , P. S. Cornaglia , D. R. Grempel

We theoretically investigate the transport properties of a molecule embedded in one arm of a mesoscopic Aharonov-Bohm interferometer. Due to the presence of phonons the molecule level position ($\epsilon_d$) and the electron-electron…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Jong Soo Lim , Rosa Lopez , Gloria Platero , Pascal Simon

Electronic transport in diatomic molecules (two-level systems) connected to metallic contacts is analyzed in the presence of competing electron-electron and electron-phonon interactions. We show that phonon emission and absorption processes…

Mesoscale and Nanoscale Physics · Physics 2009-02-17 E. Vernek , E. V. Anda , S. E. Ulloa , N. Sandler

The interaction of electron-hole pairs with lattice vibrations exhibits a wealth of intriguing physical phenomena. The Kohn anomaly is a renowned example where electron-phonon coupling leads to non-analytic phonon dispersion at specific…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Jun Yan , Erik A. Henriksen , Philip Kim , Aron Pinczuk

A time-dependent electromagnetic field creates electron-hole excitations in a Fermi sea at low temperature. We show that the electron-hole pairs can be generated in a controlled way using harmonic and biharmonic time-dependent voltages…

Mesoscale and Nanoscale Physics · Physics 2013-01-01 Mihajlo Vanevic , Wolfgang Belzig

The transport properties of a octane-dithiol (ODT) molecule coupled to Au(001) leads are analyzed using density functional theory and non-equilibrium Green functions. It is shown that a symmetric molecule can turn into a diode under…

Mesoscale and Nanoscale Physics · Physics 2010-02-09 Tomasz Kostyrko , Víctor M. García-Suárez , Colin J. Lambert , Bogdan R. Bułka

We investigate quantum corrections to the conductivity due to the interference of electron-electron (electron-phonon) scattering and elastic electron scattering in weakly disordered conductors. The electron-electron interaction results in a…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. Sergeev , M. Yu. Reizer , V. Mitin

We investigate the influence of vibrational phonon modes on the entanglement through a quantum dot molecule under the bias voltage-driven field. The molecular quantum dot system can be realized by coupled quantum dots in the middle of the…

Quantum Physics · Physics 2020-01-06 Elaheh Afsaneh , Malek Bagheri Harouni

We analyze various limits of vibrationally coupled resonant electron transport in single-molecule junctions. Based on a master equation approach, we discuss analytic and numerical results for junctions under a high bias voltage or weak…

Mesoscale and Nanoscale Physics · Physics 2015-03-18 R. Härtle , M. Thoss