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Magnetocaloric effect in Mn4FeGe3-xSix compounds has been studied by dc magnetization measurements. For the parent compound Mn4FeGe3, the paramagnetic to ferromagnetic transition temperature TC is above room temperature (320 K), which…

Materials Science · Physics 2013-04-10 Madhumita Halder , S. M. Yusuf , A. K. Nigam

Giant magnetocaloric effect is widely achieved in hexagonal MnMX-based (M = Co or Ni, X = Si or Ge) ferromagnets at their first-order magnetostructural transition. However, the thermal hysteresis and the low sensitivity of the…

A systematic study of magnetic properties of Ni2+xMn1-xGa (0 \le x \le 0.19) Heusler alloys undergoing structural martensite-austenite transformations while in ferromagnetic state has been performed. From measurements of spontaneous…

Materials Science · Physics 2009-11-10 V. V. Khovailo , V. Novosad , T. Takagi , D. A. Filippov , R. Z. Levitin , A. N. Vasilev

This work reports an experimental investigation of the magneto-elastic coupling and polarization character of magnetic phases of the orthorhombic Eu1-xYxMnO3 system at low temperatures. The temperature dependence of the polarization…

Two magnetic ordering transitions are found in InMnO3, the paramagnetic to antiferromagnetic transition near ~118 K and a lower possible spin rotation transition near ~42 K. Multiple length scale structural measurements reveal enhanced…

Materials Science · Physics 2015-06-22 T. Yu , T. A. Tyson , P. Gao , T. Wu , X. Hong , S. Ghose , Y. -S. Chen

The all-d-metal Mn2-based Heusler ferromagnetic shape memory alloys Mn50Ni40-xCoxTi10 (x = 8 and 9.5) are realized. With a generic comparison between d-metal Ti and main-group elements in lowering the transformation temperature, the…

Materials Science · Physics 2016-08-24 Z. Y. Wei , E. K. Liu , Y. Li , X. L. Han , Z. W. Du , H. Z. Luo , G. D. Liu , X. K. Xi , H. W. Zhang , W. H. Wang , G. H. Wu

It is shown that a temperature window between the Curie temperatures of martensite and austenite phases around the room temperature can be obtained by a vacancy-tuning strategy in Mn-poor Mn1-xCoGe alloys (0 <= x <= 0.050). Based on this, a…

Materials Science · Physics 2010-07-22 E. K. Liu , W. Zhu , L. Feng , J. L. Chen , W. H. Wang , G. H. Wu , H. Y. Liu , F. B. Meng , H. Z. Luo , Y. X. Li

The irreversibility of the martensite transition in magnetic shape memory alloys (MSMAs) with respect to external magnetic field is one of the biggest challenges that limits their application as giant caloric materials. This transition is a…

Magnetoelectric coupling permits a magnetic order parameter to be addressed electrically or vice versa, and could find use in data storage, field sensors and actuators. Coupling constants for single phase materials such as chromium dioxide,…

Materials Science · Physics 2007-05-23 W. Eerenstein , M. Wiora , J. L. Prieto , J. F. Scott , N. D. Mathur

Polycrystalline samples of Co$_{1-x}$Cu$_x$MnGe ($x=0.05, 0.10, 0.15, 0.22$ and 0.35), prepared by arc melting under argon atmosphere, have been annealed at 1123 K with final furnace cooling. The samples have been investigated by powder…

Materials Science · Physics 2022-07-12 Ryszard Duraj , Aleksandra Deptuch , Andrzej Szytuła , Bogusław Penc , Stanisław Baran

An attempt was made to tailor the magnetostructural transitions (MSTs) over a wide temperature range under the principle of isostructural alloying. A series of wide Curie-temperature windows (CTWs) with a maximal width of 377 K between 69…

Materials Science · Physics 2016-07-19 Y. Li , Z. Y. Wei , H. G. Zhang , E. K. Liu , H. Z. Luo , G. D. Liu , X. K. Xi , S. G. Wang , W. H. Wang , M. Yue , G. H. Wu , X. X. Zhang

Ferromagnetic solids acquire nontrivial magnetic and caloric properties when the temperature of the structural phase transition approaches the Curie point. Deciphering magneto-structural transitions, i.e. determining their characteristic…

The first order magneto-structural transition ($T_t\simeq95$ K) and magnetocaloric effect in MnNiGe$_{0.9}$Ga$_{0.1}$ are studied via powder x-ray diffraction and magnetization measurements. Temperature dependent x-ray diffraction…

Materials Science · Physics 2018-01-17 Pallab Bag , R. Nath

We have studied the effect of magnetic field on a non-stoichiometric Heusler alloy Ni$_{50}$Mn$_{35}$In$_{15}$ that undergoes a martensitic as well as a magnetic transition near room temperature. Temperature dependent magnetization…

Materials Science · Physics 2009-11-13 P. A. Bhobe , K. R. Priolkar , A. K. Nigam

Co10Ge3O16 crystallizes in an intergrowth structure featuring alternating layers of spinel and rock salt. Variable-temperature powder synchrotron X-ray and neutron diffraction, magnetometry, and heat capacity experiments reveal a…

Materials Science · Physics 2013-07-12 Phillip T. Barton , Ram Seshadri , Anna Llobet , Matthew R. Suchomel

In the present work, two successive magneto-structural transformations (MSTs) consisting of martensitic and intermartensitic transitions have been reported in polycrystalline Ni55.8Mn18.1Ga26.1 Heusler alloy. Benefiting from the additional…

Materials Science · Physics 2015-09-25 Z. Li , K. Xu , Y. L. Zhang , C. Tao , D. Zheng , C. Jing

We report on structural, magnetic and magnetocaloric properties of MnxFe1.95-xP0.50Si0.50 (x > 1.10) compounds. With increasing the Mn:Fe ratio, a first-order magneto-elastic transition gradually changes into a first-order…

Materials Science · Physics 2012-06-01 N. H. Dung , L. Zhang , Z. Q. Ou , E. Brück

The effects of magnetic field on the martensitic transition have been studied in Ni45Co5Mn38Sb12. We find a large field-induced irreversibility in this system, as revealed by the field dependence of resistivity, magnetization, and heat…

Strongly Correlated Electrons · Physics 2010-06-02 Ajaya K. Nayak , K. G. Suresh , A. K. Nigam

The isostructural alloying of two compounds with extremely different magnetic and thermo-structural properties has resulted in a new system, (MnNiSi)1-x(FeCoGe)x, that exhibits extraordinary magnetocaloric properties with an acute…

One important aspect of the magneto-structural transition in MnCoGe and related materials is the reduction in saturation magnetization from the orthorhombic to the hexagonal phase. Here, by combining an element specific magnetization probe…

Strongly Correlated Electrons · Physics 2016-04-20 F. Guillou , F. Wilhelm , O. Tegus , A. Rogalev