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The general form of the electrostatic potential around an arbitrarily charged colloid at an interface between a dielectric and a screening phase (such as air and water, respectively) is analyzed in terms of a multipole expansion. The…

Soft Condensed Matter · Physics 2008-07-11 A. Dominguez , D. Frydel , M. Oettel

We study the phase diagram of a system of spherical particles interacting in three dimensions through a potential consisting of a strict hard core plus a linear repulsive shoulder at larger distances. The phase diagram (obtained…

Statistical Mechanics · Physics 2009-10-31 E. A. Jagla

Effect of ionic solute on a near-critical binary aqueous mixture confined between charged walls with different adsorption preferences is considered within a simple density functional theory. For the near-critical system containing small…

Soft Condensed Matter · Physics 2015-05-28 F. Pousaneh , A. Ciach

We consider an osmotic equilibrium between bulk solutions of polyelectrolyte bounded by semipermeable membranes and separated by a thin film of salt-free liquid. Although the membranes are neutral, the counter-ions of the polyelectrolyte…

Soft Condensed Matter · Physics 2012-01-19 Olga I. Vinogradova , Lyderic Bocquet , Artem N. Bogdanov , Roumen Tsekov , Vladimir Lobaskin

The effective potential between charged colloids trapped at water interfaces is analyzed. It consists of a repulsive electrostatic and an attractive capillary part which asymptotically both show dipole--like behavior. For sufficiently large…

Soft Condensed Matter · Physics 2016-08-31 M. Oettel , A. Dominguez , S. Dietrich

When two macromolecules come very near in a fluid, the surrounding molecules, having finite volume, are less likely to get in between. This leads to a pressure difference manifesting as an entropic attraction, called depletion force. Here…

Soft Condensed Matter · Physics 2020-02-26 Nathaniel Rupprecht , Dervis Can Vural

A quite straightforward approximation for the electrostatic interaction between two perfectly conducting surfaces suggests itself when the distance between them is much smaller than the characteristic lengths associated to their shapes.…

Classical Physics · Physics 2015-06-03 C. D. Fosco , F. C. Lombardo , F. D. Mazzitelli

We present the theory for retarded resonance interaction between two identical atoms at arbitrary positions near a metal surface. The dipole-dipole resonance interaction force that binds isotropically excited atom pairs together in free…

Materials Science · Physics 2013-04-10 Mathias Boström , Clas Persson , Barry W. Ninham , Patrick Norman , Bo E. Sernelius

We study two models of ringlike polyions which are two-dimensional versions of simple models for colloidal particles (model A) and for rodlike segments of DNA (model B), both in solution with counterions. The counterions may condensate on Z…

Statistical Mechanics · Physics 2009-11-07 Silvia Martins , Jurgen Stilck

We theoretically investigate electrostatic properties between two charged surfaces with a grafted polyelectrolyte layer in an aqueous electrolyte solution by using the Poisson-Boltzmann approach accounting for ion partitioning. In order to…

Soft Condensed Matter · Physics 2022-02-07 Jun-Sik Sin

The interaction between surface patches of proteins with different surface properties has a vital role to play driving conformational changes of proteins in different salt solutions. We demonstrate the existence of ion-specific attractive…

Soft Condensed Matter · Physics 2012-01-06 Eduardo R. A. Lima , Mathias Boström , Nadine Schwierz , Bo E. Sernelius , Frederico W. Tavares

We derive the energy of the surface between the normal and superfluid components of a mixed phase of a system composed of two particle species with different densities. The surface energy is obtained by the integration of the free energy…

Superconductivity · Physics 2009-11-11 Heron Caldas

We show that an electro-osmotic flow near the slippery hydrophobic surface depends strongly on the mobility of surface charges, which are balanced by counter-ions of the electrostatic diffuse layer. For a hydrophobic surface with immobile…

Fluid Dynamics · Physics 2015-04-03 S. R. Maduar , A. V. Belyaev , V. Lobaskin , O. I. Vinogradova

We investigate the interaction between highly charged lipid bilayers in the presence of monovalent counterions. Neutron and X-ray reflectivity experiments show that the water layer between like-charged bilayers is thinner than for…

We show that hydrophilic ions present in a confined, near-critical aqueous mixture can lead to an attraction between like charge surfaces with opposing preferential adsorption of the two species of the mixture, even though the corresponding…

Soft Condensed Matter · Physics 2016-03-27 Faezeh Pousaneh , Alina Ciach , Anna Maciołek

We study the interaction potential between two polyions inside a colloidal suspension. It is shown that at large separation the interaction potential is purely repulsive, with the induced attractive interactions being doubly screened. For…

Soft Condensed Matter · Physics 2015-06-25 Yan Levin

In solution, electrically like-charged particles can experience a strong and long-ranged attraction that leads to the formation of stable, slowly reorganizing clusters. The attractive force underpinning this spontaneous organization process…

Soft Condensed Matter · Physics 2026-01-14 Sida Wang , Angela Le , Rowan Walker-Gibbons , Madhavi Krishnan

We evaluate exactly the statistical integral for an inhomogeneous one-dimensional counterion-only Coulomb gas between two charged boundaries and from this compute the effective interaction, or disjoining pressure, between the bounding…

Statistical Mechanics · Physics 2009-08-10 David S. Dean , Ron R. Horgan , Ali Naji , Rudolf Podgornik

We calculate the force between two spherical metal nanoparticles of charge Q 1 and Q 2 in a dilute 1:1 electrolyte solution. Numerically solving the non-linear Poisson-Boltzmann equation, we find that metal nanoparticles with the same sign…

Soft Condensed Matter · Physics 2019-07-03 Alexandre P. dos Santos , Yan Levin

In this paper, we study electrostatic properties between two similar or oppositely charged surfaces immersed in an electrolyte solution by using mean-field approach accounting for solvent polarization and non-uniform size effect. Applying a…

Soft Condensed Matter · Physics 2022-02-11 Jun-Sik Sin