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Various condensed phases of water, spanning from the liquid state to multiple ice phases, have been systematically investigated under extreme conditions of pressure and temperature to delineate their stability boundaries. This study focuses…

Chemical Physics · Physics 2024-05-29 Carlos P. Herrero , Rafael Ramirez

We perform lengthy molecular dynamics simulations of the SPC/E model of water to investigate the dynamics under pressure at many temperatures and compare with experimental measurements. We calculate the isochrones of the diffusion constant…

Condensed Matter · Physics 2009-10-31 Francis W. Starr , Stephen Harrington , Francesco Sciortino , H. Eugene Stanley

We analyze the nature of the structural order established in liquid TIP4P water in the framework provided by the multi-particle correlation expansion of the statistical entropy. Different regimes are mapped onto the phase diagram of the…

Materials Science · Physics 2011-10-25 Rubens Esposito , Franz Saija , A. Marco Saitta , Paolo V. Giaquinta

We have mapped the molecular-atomic transition in liquid hydrogen using first principles molecular dynamics. We predict that a molecular phase with short-range orientational order exists at pressures above 100 GPa. The presence of this…

Materials Science · Physics 2010-02-11 Isaac Tamblyn , Stanimir A. Bonev

Accurately simulating the properties of liquid water remains a central challenge in molecular simulations. In this work, we use machine learning potentials to investigate how the convergence settings of electronic structure calculations…

Chemical Physics · Physics 2026-03-24 Hubert Beck , Ondrej Marsalek

Understanding the pressure-dependent dielectric properties of water is crucial for a wide range of scientific and practical applications. In this study, we employ a deep neural network trained on density functional theory data to…

Materials Science · Physics 2026-03-31 Yizhi Song , Xifan Wu

Compressing or cooling a fluid typically enhances its static interparticle correlations. However, there are notable exceptions. Isothermal compression can reduce the translational order of fluids that exhibit anomalous waterlike trends in…

Soft Condensed Matter · Physics 2008-04-11 William P. Krekelberg , Jeetain Mittal , Venkat Ganesan , Thomas M. Truskett

We have investigated thermodynamic and dynamic properties as well as the dielectric constant of water-metha\-nol model mixtures in the entire range of composition by using constant pressure molecular dynamics simulations at ambient…

Soft Condensed Matter · Physics 2015-12-25 E. Galicia-Andrés , H. Dominguez , L. Pusztai , O. Pizio

Molecular dynamics simulations are performed to study the temperature-dependent dynamics and structures of the hydration shells of elastin-like and collagen-like peptides. For both model peptides, it is consistently observed that, upon…

Soft Condensed Matter · Physics 2009-02-23 Michael Vogel

We report the results of a computer simulation study of the thermodynamic properties and the thermal conductivity of supercooled water as a function of pressure and temperature using the TIP4P-2005 water model. The thermodynamic properties…

Statistical Mechanics · Physics 2015-06-19 F. Bresme , J. W. Biddle , J. V. Sengers , M. A. Anisimov

The anomalous properties of water in the supercooled state are numerous and well-known. Particularly striking are the strong changes in dynamic properties that appear to display divergences at temperatures close to -- but beyond -- the…

Statistical Mechanics · Physics 2007-05-23 Francis W. Starr , Srikanth Sastry , Francesco Sciortino , H. E. Stanley

We present results of \textit{ab initio} molecular dynamics study of a structural transformation occurring in hot liquid sulfur under high pressure, which corresponds to the chain-breakage phenomenon recently observed experimentally by Liu…

Chemical Physics · Physics 2015-06-23 Dušan Plašienka , Peter Cifra , Roman Martoňák

Molecular dynamics is a powerful method for studying the behaviour of materials at high temperature. In practice, however, its effectiveness in representing real systems is limited by the accuracy of the forces, finite size effects,…

Materials Science · Physics 2016-06-14 Graeme J Ackland , Ioan B Magdău

Understand the nature of liquid structure and its evolution under different conditions is a major challenge in condensed physics and materials science. Here, we report a pressure-induced structure change spanning a wide pressure range in…

Materials Science · Physics 2025-01-28 X. Z. Yan , Y. M. Chen , Hua Y. Geng , Y. F. Wang , Y. Sun , L. L. Zhang , H. Wang , Y. L. Xu

The results of the molecular dynamics simulation of the radiation influence on the structure and thermophysical properties of water are presented. The changes in the radial distribution functions, momentum distribution function and the…

Statistical Mechanics · Physics 2017-01-25 L. A. Bulavin , K. V. Cherevko , D. A. Gavryushenko , V. M. Sysoev , T. S. Vlasenko

We have investigated temperature trends of the microscopic structure of the SPC/E and TIP4P-Ew water models in terms of the pair distribution functions, coordination numbers, the average number of hydrogen bonds, the distribution of bonding…

Soft Condensed Matter · Physics 2016-08-08 E. Galicia-Andrés , H. Dominguez , O. Pizio

A molecular theory of liquid water is identified and studied on the basis of computer simulation of the TIP3P model of liquid water. This theory would be exact for models of liquid water in which the intermolecular interactions vanish…

Chemical Physics · Physics 2009-11-13 J. K. Shah , D. Asthagiri , L. R. Pratt , M. E. Paulaitis

We have revisited the composition dependence of principal properties of liquid water-DMSO mixtures by using the isobaric-isothermal molecular dynamics computer simulations. A set of non-polarizable semi-flexible models for the DMSO molecule…

Soft Condensed Matter · Physics 2022-10-10 M. Aguilar , H. Dominguez , O. Pizio

We use molecular dynamics simulations in two dimensions to investigate the possibility that a core-softened potential can reproduce static and dynamic anomalies found experimentally in liquid water: (i) the increase in specific volume upon…

Soft Condensed Matter · Physics 2009-10-31 A. Scala , M. Reza Sadr-Lahijany , N. Giovambattista , S. V. Buldyrev , H. E. Stanley

Controversy exists regarding the possible existence of a transition between the liquid and glassy states of water. Here we use experimental measurements of the entropy, specific heat, and enthalpy of both liquid and glassy water to…

Condensed Matter · Physics 2007-05-23 Francis W. Starr , C. Austen Angell , Robin J. Speedy , H. Eugene Stanley