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We report direct measurements of the frequency ratio of the 642 THz ${}^2S_{1/2} (F=0)$--${}^2F_{7/2} (F=3)$ electric octupole transition in ${}^{171}\mathrm{Yb}^+$ and the 429 THz ${}^1S_0$--${}^3P_0$ transition in ${}^{87}\mathrm{Sr}$. A…

An ultrastable optical clock based on neutral atoms trapped in an optical lattice is proposed. Complete control over the light shift is achieved by employing the $5s^2 {}^1S_0 \to 5s5p {}^3P_0$ transition of ${}^{87}{\rm Sr}$ atoms as a…

Atomic Physics · Physics 2009-11-10 Hidetoshi Katori , Masao Takamoto , V. G. Pal'chikov , V. D. Ovsiannikov

We describe experiments with an optical frequency standard based on a laser cooled $^{171}$Yb$^+$ ion confined in a radiofrequency Paul trap. The electric-quadrupole transition from the $^2S_{1/2}(F=0)$ ground state to the $^2D_{3/2}(F=2)$…

Atomic Physics · Physics 2007-05-23 E. Peik , B. Lipphardt , H. Schnatz , T. Schneider , Chr. Tamm , S. G. Karshenboim

Transition frequencies between low-lying energy levels in a single trapped $^{138}$Ba$^{+}$ ion have been measured with laser spectroscopy referenced to an optical frequency comb. By extracting the frequencies of one-photon and two-photon…

Atomic Physics · Physics 2016-01-29 E. A. Dijck , M. Nuñez Portela , A. T. Grier , K. Jungmann , A. Mohanty , N. Valappol , L. Willmann

We excite the 717 nm electric quadrupole 6$D_{3/2} $ $\leftrightarrow$ 7$S_{1/2}$ transition in a laser-cooled $^{232}$Th$^{3+}$ ion crystal. The transition frequency and the lifetime of the metastable 7$S_{1/2}$ level are measured to be…

Atomic Physics · Physics 2015-06-11 A. G. Radnaev , C. J. Campbell , A. Kuzmich

Transition frequencies of atoms and ions are among the most accurately accessible quantities in nature, playing important roles in pushing the frontiers of science by testing fundamental laws of physics, in addition to a wide range of…

It is shown that the dynamic differential scalar polarisability of the $S_{1/2}-D_{5/2}$ transition in $^{138}$Ba$^+$ can be determined to an inaccuracy below $0.5\%$ across a wide wavelength range ($\lambda>700\,\mathrm{nm}$). This can be…

Atomic Physics · Physics 2019-10-30 M. D. Barrett , K. J. Arnold , M. S. Safronova

The $5S_{1/2}\rightarrow 5D_{5/2}$ two-photon transition in Rb is of interest for the development of a compact optical atomic clock. Here we present a rigorous calculation of the 778.1~nm ac-Stark shift ($2.30(4)…

Divalent atoms and ions with a singlet $S$ ground state and triplet $P$ excited state form the basis of many high-precision optical atomic clocks. Along with the metastable $^{3}\mathrm{P}_{0}$ clock state, these atomic systems also have a…

We report a precise measurement of the isotope shifts in the $4^2$S$_{1/2} \rightarrow 3^2$D$_{5/2}$ electric quadrupole transition at 729~nm in the $^{40 - 42,44,48}$Ca$^+$. The measurement has been made via high-resolution laser…

Atomic Physics · Physics 2023-05-24 Felix W. Knollmann , Ashay N. Patel , S. Charles Doret

The systematic shifts of the transition frequencies in the molecular hydrogen ions are of relevance to ultra-high-resolution radio-frequency, microwave and optical spectroscopy of these systems, performed in ion traps. We develop the…

Atomic Physics · Physics 2015-06-16 Dimitar Bakalov , Stephan Schiller

Collisions with background gas can perturb the transition frequency of trapped ions in an optical atomic clock. We develop a non-perturbative framework based on a quantum channel description of the scattering process, and use it to derive a…

Atomic Physics · Physics 2017-09-01 Amar C. Vutha , Tom Kirchner , Pierre Dubé

We observe the electric-dipole forbidden $7s\rightarrow8s$ transition in the francium isotopes $^{208-211}$Fr and $^{213}$Fr using a two-photon excitation scheme. We collect the atoms online from an accelerator and confine them in a magneto…

We experimentally investigate an optical clock based on $^{171}$Yb ($I=1/2$) atoms confined in an optical lattice. We have evaluated all known frequency shifts to the clock transition, including a density-dependent collision shift, with a…

For the isotope $^{229}$Th we investigate the possibility of two-photon laser spectroscopy of the nuclear clock transition (148.38 nm) using intense monochromatic laser field at twice the wavelength (296.76 nm). Our estimates show that due…

Atomic clocks use atomic transitions as frequency references. The susceptibility of the atomic transition to external fields limits clock stability and introduces systematic frequency shifts. Here, we propose to realize an atomic clock that…

Atomic Physics · Physics 2017-09-06 Nitzan Akerman , Roee Ozeri

High-precision quasi-simultaneous collinear/anticollinear laser spectroscopy was performed to measure the $5s$ $^2S_{1/2}\rightarrow 5p$ $^2P_{1/2}$ (D1), the $5s$ $^2S_{1/2}\rightarrow 5p$ $^2P_{3/2}$ (D2), and the three $4d\rightarrow 5p$…

We experimentally demonstrate the cesium electric quadrupole transition from the 6S1/2 ground state to the 7D3/2,5/2 excited state through a virtual level by using a single laser at 767 nm. The excited state energy level population is…

Atomic Physics · Physics 2020-08-25 Sandan Wang , Jinpeng Yuan , Lirong Wang , Liantuan Xiao , Suotang Jia

We report the direct measurement of isotope shifts of the barium 6s$^2$ $^1$S$_0$ --5d6p $^3$D$^\text{o}_1$ 413-nm electric quadrupole transition, which is utilized for efficient barium ion trapping via photoionization using a single…

Atomic Physics · Physics 2024-10-03 Jungwoo Choi , Eunhwi Lee , Dahyun Yum , Kyoungwon An , Junki Kim

Optical transitions of highly charged ions can be very sensitive to hypothetical beyond-the-Standard-Model phenomena. Those near the $5s-4f$ level crossing, where the $5s$ and $4f$ are degenerate are especially promising. We present…