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The Kullback-Leibler inequality is a way of comparing any two density matrices. A technique to set up the density matrix for a physical system is to use the maximum entropy principle, given the entropy as a functional of the density matrix,…

Statistical Mechanics · Physics 2009-11-07 A. K. Rajagopal , R. W. Rendell , Sumiyoshi Abe

In a previous paper [1] we considered the question, "What underlying property of nature is responsible for the second law?" A simple answer can be stated in terms of information: The fundamental loss of information gives rise to the second…

Statistical Mechanics · Physics 2012-02-21 T. L. Duncan , J. S. Semura

Starting from a classical thermodynamic approach, we derive rate-type equations to describe the behavior of heat flow in deformable media. Constitutive equations are defined in the material (Lagrangian) description where the standard time…

Mathematical Physics · Physics 2024-02-02 Claudio Giorgi , Angelo Morro , Federico Zullo

The experimental verification of the fluctuation theorem by Wang et al. is explained in terms of a simple Langevin dynamics. This implies that the entropy consuming trajectories found by Wang et al. are fluctuations generated by a random…

Statistical Mechanics · Physics 2007-05-23 S. Tasaki , I. Terasaki , T. Monnai

By using very general arguments, we show that the entropy loss conjecture at the glass transition violates the second law of thermodynamics and must be rejected.

Disordered Systems and Neural Networks · Physics 2009-09-02 P. D. Gujrati

With the usual definitions for the entropy and the temperature associated with the apparent horizon, we show that the unified first law on the apparent horizon is equivalent to the Friedmann equation for the scalar--tensor theory with…

General Relativity and Quantum Cosmology · Physics 2015-07-31 Yumei Huang , Yungui Gong , Dicong Liang , Zhu Yi

In this note we compare the entropy principle and the objectivity arguments in the methodologies of Dunn and Serrin [1] and in the more recent weakly nonlocal thermodynamic analysis of Korteweg-type fluids in [2]. It is concluded that the…

Statistical Mechanics · Physics 2026-01-06 Peter Ván

We derive the law of entropy non-decrease directly from the Kelvin-Planck principle for simple and compound systems without using the Clausius inequality. A key of the derivation is a new formulation of entropy in terms of work by a Carnot…

Statistical Mechanics · Physics 2025-10-21 Yuki Izumida

Compared to other formulations of the second law of thermodynamics, the Clausius statement that heat does not spontaneously flow from cold to hot concerns a system in non-equilibrium states, and in that respect is more ambitious but also…

Statistical Mechanics · Physics 2020-12-18 Alex V. Plyukhin

Using classical thermodynamics, we argue that Maxwell's demon loses its battle against Clausius as any temperature difference or other thermodynamic forces it creates is immediately compensated by spontaneous counterbalancing flows that…

Classical Physics · Physics 2022-01-03 P. D. Gujrati

Even after over 150 years of discussion, the interpretation of the second law of thermodynamics continues to be a source of confusion and controversy in physics. This confusion has been accentuated by recent challenges to the second law and…

Statistical Mechanics · Physics 2015-06-24 T. Duncan , J. Semura

We pointed out that the generalized second law of thermodynamics on a de Sitter universe whose energy density stochastically fluctuates due to quantum fluctuations is seemingly violated. We have shown that even in such a case, the…

General Relativity and Quantum Cosmology · Physics 2018-01-17 Naritaka Oshita

The second law of ordinary thermodynamics and the second law of steady state thermodynamics, as proposed by Oono and Paniconi, are investigated from the microscopic point of view for the open quantum system. Based on the H-theorem of…

Statistical Mechanics · Physics 2007-05-23 Satoshi Yukawa

We have made a simple and natural modification of a recent quantum refrigerator model presented by Cleuren et al. in Phys. Rev, Lett.108, 120603 (2012). The original model consist of two metal leads acting as heat baths, and a set of…

Statistical Mechanics · Physics 2016-03-09 Vegard B. Sørdal , Joakim Bergli , Y. M. Galperin

Based on recent data about the history of the Hubble factor, it is argued that the second law of thermodynamics holds at the largest scales accessible to observation. This is consistent with previous studies of the same question.

Cosmology and Nongalactic Astrophysics · Physics 2025-12-02 Narayan Banerjee , Purba Mukherjee , Diego Pavón

Thermodynamics, the branch of physics concerned with the description of macroscopic bodies, heat exchange and the conversion of different forms of energy is based on four laws: the zeroth law, which states that bodies in thermal contact…

Statistical Mechanics · Physics 2020-01-21 Dragos-Victor Anghel

The first law of thermodynamics, which governs energy conservation, is traditionally formulated as an equality. Surprisingly, we demonstrate that the first law alone implies a universal Landauer-like inequality linking changes in system…

Quantum Physics · Physics 2023-08-17 Junjie Liu , Hanlin Nie

In this article the Gordan theorem is applied to the thermodynamics of a chemical reaction network at steady state. From a theoretical viewpoint it is equivalent to the Clausius formulation of the second law for the out of equilibrium…

Statistical Mechanics · Physics 2013-05-15 Daniele De Martino

All current formulations of thermodynamics invoke some form of coarse-graining or ensembles as the supposed link between their own laws and the microscopic laws of motion. They deal only with ensemble-averages, expectation values,…

Classical Physics · Physics 2017-05-30 Chiara Marletto

This work investigates the validity of the generalized second law of thermodynamics in modified f(R) Horava-Lifshitz gravity proposed by Chaichian et al (2010) [Class. Quantum Grav. 27 (2010) 185021], which is invariant under…

General Physics · Physics 2016-12-09 Surajit Chattopadhyay , Rahul Ghosh
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