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The stability of graphene nanoribbons in the presence of typical atmospheric molecules is systematically investigated by means of density functional theory. We calculate the edge formation free energy of five different edge configurations…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 M. Vanin , J. Gath , K. S. Thygesen , K. W. Jacobsen

The band structures of strained graphene nanoribbons (GNRs) are examined by a tight binding Hamiltonian that is directly related to the type and strength of strains. Compared to the two-dimensional graphene whose band gap remains close to…

Mesoscale and Nanoscale Physics · Physics 2010-01-20 Yang Lu , Jing Guo

We investigate high-harmonic generation in graphene heterostructures consisting of metallic nanoribbons separated from a graphene sheet by either a few-nanometer layer of aluminum oxide or an atomic monolayer of hexagonal boron nitride. The…

The structural similarity between hexagonal boron nitride (h-BN) and graphene nanoribbons allows for the formation of heterojunctions with small chain stress. The combination of the insulation nature of the former and the quasi-metallic…

It is now possible to produce graphene nanoribbons (GNRs) with atomically defined widths. GNRs offer many opportunities for electronic devices and composites, if it is possible to establish the link between edge structure and…

Graphene has many advantageous properties, but its lack of an electronic band gap makes this two dimensional material impractical for many nanoelectronic applications, for example field effect transistors. This problem can be circumvented…

Mesoscale and Nanoscale Physics · Physics 2009-12-17 Peter Nemes Incze , Gabor Magda , Katalin Kamaras , Laszlo Peter Biro

We investigate the electronic band structure of an undoped graphene armchair nanoribbon. We demonstrate that such nanoribbon always has a gap in its electronic spectrum. Indeed, even in the situations where simple single-electron…

Mesoscale and Nanoscale Physics · Physics 2009-09-30 A. V. Rozhkov , S. Savel'ev , Franco Nori

We examine the electronic structure of recently fabricated in-plane heterojunctions of zigzag graphene nanoribbons embedded in hexagonal boron nitride. We focus on hitherto unexplored interface configurations in which both edges of the…

Mesoscale and Nanoscale Physics · Physics 2024-06-03 Michele Pizzochero , Nikita V. Tepliakov , Johannes Lischner , Arash A. Mostofi , Efthimios Kaxiras

We determine, by means of density functional theory, the stability and the structure of graphene nanoribbon (GNR) edges in presence of molecules such as oxygen, water, ammonia, and carbon dioxide. As in the case of hydrogen-terminated…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 Ari P. Seitsonen , A. Marco Saitta , Tobias Wassmann , Michele Lazzeri , Francesco Mauri

Carbon-based magnetic structures promise significantly longer coherence times than traditional magnetic materials, which is of fundamental importance for spintronic applications. An elegant way of achieving carbon-based magnetic moments is…

Mesoscale and Nanoscale Physics · Physics 2023-07-19 Qiang Sun , Xuelin Yao , Oliver Groning , Kristjan Eimre , Carlo A. Pignedoli , Klaus Müllen , Akimitsu Narita , Roman Fasel , Pascal Ruffieux

We investigate how parameters of the model of semi-infinite graphene based on a graphene nanoribbon under periodic boundary conditions affect the accuracy of ab initio calculations of reactions at graphene edges by the example of the first…

Mesoscale and Nanoscale Physics · Physics 2022-11-09 Yulia G. Polynskaya , Irina V. Lebedeva , Andrey A. Knizhnik , Andrey M. Popov

Several experiments have recently found room-temperature ferromagnetism in graphite-like carbon based materials. This paper offers a model explaining such ferromagnetism by using an asymmetric nano-graphene. Our first typical model is…

Mesoscale and Nanoscale Physics · Physics 2011-01-28 Norio Ota , Narjes Gorjizadeh , Yoshiyuki Kawazoe

Spin-ordered electronic states in hydrogen-terminated zigzag nanographene give rise to magnetic quantum phenomena that have sparked renewed interest in carbon-based spintronics. Zigzag graphene nanoribbons (ZGNRs), quasi one-dimensional…

Edge-induced gap states in finite phosphorene layers are examined using analytical models and density functional theory. The nature of such gap states depends on the direction of the cut. Armchair nanoribbons are insulating, whereas…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 A. Carvalho , A. S. Rodin , A. H. Castro Neto

Herein, we investigate the structural, electronic and mechanical properties of zigzag graphene nanoribbons upon the presence of stress applying Density Functional Theory within the GGA-PBE approximation. The uniaxial stress is applied along…

Materials Science · Physics 2015-05-13 Ricardo Faccio , Pablo A. Denis , Helena Pardo , Cecilia Goyenola , Alvaro W. Mombru

We propose a new class of semiconducting graphene-based nanostructures: hydrogenated graphene nanoripples (HGNRs), based on continuum-mechanics analysis and first principles calculations. They are formed via a two-step combinatorial…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Z. F. Wang , Yu Zhang , Feng Liu

We investigated the vibrational properties of graphene nanoribbons by means of first-principles calculations on the basis of density functional theory. We confirm that the phonon modes of graphene nanoribbons with armchair and zigzag type…

Materials Science · Physics 2015-05-13 Roland Gillen , Marcel Mohr , Janina Maultzsch , Christian Thomsen

Graphene is the extreme material for molecular sensory and hydrogen storage applications because of its two-dimensional geometry and unique structure-property relationship. In this Letter, hydrogenation of graphene is discussed in the…

Materials Science · Physics 2010-02-10 Zhiping Xu , Kun Xue

It is a challenge to synthesize graphene nanoribbons (GNRs) with narrow widths and smooth edges in large scale. Our first principles study on the hydrogenation of GNRs shows that the hydrogenation starts from the edges of GNRs and proceeds…

Materials Science · Physics 2009-09-30 Hongjun Xiang , Erjun Kan , Su-Huai Wei , Myung-Hwan Whangbo , Jinlong Yang

An odd number of zigzag edges in armchair graphene nanoribbons and their mechanical properties (e.g., Young's modulus, Poisson ratio and shear modulus) have potential interest for bandgap engineering in graphene based optoelectronic…

Mesoscale and Nanoscale Physics · Physics 2019-01-04 Sanjay Prabhakar , Roderick Melnik