Related papers: Ionic phase transitions in non-ideal systems
We find that the Debye-H\"uckel nonideality of dilute aqueous electrolytes is sufficient to drive volume phase transitions and criticality, even in the absence of a self-attracting or elastic network. Our result follows from a Landau…
Ionic liquids are solvent-free electrolytes, some of which possess an intriguing self-assembly property. Using a mean-field framework (based on Onsager's relations) we show that bulk nano-structures arise via type-I and II phase transitions…
We uncover a finite-time dynamical phase transition in the thermal relaxation of a mean-field magnetic model. The phase transition manifests itself as a cusp singularity in the probability distribution of the magnetisation that forms at a…
A Landau-Ginzburg functional of two order parameters (charge-density $\phi$ and mass-density deviation $\eta$) is developed in order to yield a field theory relevant to ionic lattice gases as well as a family of off-lattice models of ionic…
The study of critical phenomena and phase transitions is an important part of modern condensed matter physics. In this regard, the phenomenological Landau theory has been extraordinarily useful. Hereby we present an alternative theoretical…
The nonlinear $\sigma$-model for disordered interacting electrons is studied in spatial dimensions $d>4$. The critical behavior at the metal-insulator transition is determined exactly, and found to be that of a standard…
The raise of the symmetry breaking mechanism by Landau[1] is a landmark in the studies of phase transitions. The Kosterlitz-Thouless phase transition[2-3] and the fractional quantum Hall effect[4], however, are believed to be induced by…
We examine how systems in non-equilibrium steady states close to a continuous phase transition can still be described by a Landau potential if one forgoes the assumption of analyticity. In a system simultaneously coupled to several baths at…
We investigate the quantum mechanical origin of resistive phase transitions in solids driven by a constant electric field in the vicinity of a metal-insulator transition. We perform a nonequilibrium mean-field analysis of a…
The paper presents a mean field theory of electrolyte solutions, extending the classical Debye-H\"{u}ckel-Onsager theory to provide a detailed description of the electrical conductivity in strong electrolyte solutions. The theory…
This paper presents an introduction to phase transitions and critical phenomena on the one hand, and nonequilibrium patterns on the other, using the Ginzburg-Landau theory as a unified language. In the first part, mean-field theory is…
We propose a mean-field theory for nonequilibrium phase transitions to a periodically oscillating state in spin models. A nonequilibrium generalization of the Landau free energy is obtained from the join distribution of the magnetization…
We investigate active electrolytes within the mean-field level of description. The focus is on how the double-layer structure of passive, thermalized charges is affected by active dynamics of all constituting ions. One feature of active…
While analyzing second order thermodynamical phase transitions, Lev Landau (the famous Russian physicist) introduced a very vital concept, the concept of an "order parameter". This not only amalgamated the previous fragmentary theoretical…
Ionic fluids under conductive confinement are central to technologies such as batteries, supercapacitors, and fuel cells. Their interfacial behavior governs energy storage and electrochemical processes. Despite their importance, the…
Since Hund's work on the ammonia molecule, the double well potential has formed a key paradigm in physics. Its importance is further underlined by the central role it plays in the Landau theory of phase transitions. Recently, the study of…
We look at the influence of external fields on systems described by generic free energy functional of the order parameter. The external force may have arbitrary spatial dependence, and the order parameter coupling may be nonlinear. The…
We study the interplay between an isostructural critical point and dislocation mediated two-dimensional melting, using a combination of Landau and continuum elasticity theory. If dislocations are excluded, coupling to the elastic degrees of…
Metal-ion doping can effectively regulate the metal-insulator transition temperature in $\mathrm{VO}_2$. Experiments found that the pentavalent and hexavalent ion doping dramatically reduces the transition temperature while the trivalent…
A class of systems exists in which dissipation, external drive and interactions compete and give rise to non equilibrium phases that would not exist without the drive. There, phase transitions could occur without the breaking of any…