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Computational approaches to exploring "chemical universes", i.e., very large sets, potentially infinite sets of compounds that can be constructed by a prescribed collection of reaction mechanisms, in practice suffer from a combinatorial…

Formal Languages and Automata Theory · Computer Science 2014-04-16 Jakob L. Andersen , Christoph Flamm , Daniel Merkle , Peter F. Stadler

Generalizing response theory of open systems far from equilibrium is a central quest of nonequilibrium statistical physics. Using stochastic thermodynamics, we develop an algebraic method to study the response of nonequilibrium steady state…

Statistical Mechanics · Physics 2023-08-09 Timur Aslyamov , Massimiliano Esposito

A mesoscopic multi-particle collision model for fluid dynamics is generalized to incorporate the chemical reactions among species that may diffuse at different rates. This generalization provides a means to simulate reaction-diffusion…

Chemical Physics · Physics 2016-09-08 K. Tucci , R. Kapral

Equilibrium Constant Differential Equations (ECDE) are derived for several nanoconfined elemental bimolecular reactions in the frameworks of statistical mechanics and the ideal gas model. The ECDEs complement the well-known…

Chemical Physics · Physics 2020-07-15 Leonid Rubinovich , Micha Polak

The article compares traditional coefficients of thermodynamic activity as a parameter related to individual chemical species to newly introduced reduced chaotic temperatures as system characteristics, both regarding their usage in…

Chemical Physics · Physics 2007-05-23 B. Zilbergleyt

In the present paper we introduce generalized kinetic equations describing the dynamics of a system of interacting gas and photons obeying to a very general statistics. In the space homogeneous case we study the equilibrium state of the…

Statistical Mechanics · Physics 2009-11-10 A. Rossani , A. M. Scarfone

Sudden and abrupt changes can occur in a nonlinear system within many fields of science when such a system crosses a tipping point and rapid changes of the system occur in response to slow changes in an external forcing. These can occur…

Dynamical Systems · Mathematics 2025-09-05 Paul D. L. Ritchie , Robbin Bastiaansen , Anna S. von der Heydt , Peter Ashwin

We extend previous work on injectivity in chemical reaction networks to general interaction networks. Matrix- and graph-theoretic conditions for injectivity of these systems are presented. A particular signed, directed, labelled, bipartite…

Dynamical Systems · Mathematics 2009-10-15 Murad Banaji , Gheorghe Craciun

We study instabilities and pattern formation in reaction-diffusion layers that are diffusively coupled. For two-layer systems of identical two-component reactions, we analyze the stability of homogeneous steady states by exploiting the…

Pattern Formation and Solitons · Physics 2015-06-03 Anne J. Catlla , Amelia McNamara , Chad M. Topaz

The Lindblad equation describes the dissipative time evolution of a density matrix that characterizes an open quantum system in contact with its environment. The widespread ensemble interpretation of a density matrix requires its time…

Quantum Physics · Physics 2020-09-04 Bernd Fernengel , Barbara Drossel

We investigate a system of harmonically coupled identical nonlinear constituents subject to noise in different spatial arrangements. For global coupling we find for infinitely many constituents the coexistence of several ergodic components…

adap-org · Physics 2009-10-30 R. Muller , K. Lippert , A. Kuhnel , U. Behn

Explicit expressions, for efficient application in engineering practice, are derived for generalized displacements and stresses in simply supported multi-layered wide plates and beams subjected to steady-state thermal and mechanical…

Materials Science · Physics 2015-03-16 M. Pelassa , R. Massabo

Soft materials, such as liquids, polymers, foams, gels, colloids, granular materials, and most soft biological materials, play an important role in our daily lives. From a mechanical viewpoint, soft materials can easily achieve large…

Soft Condensed Matter · Physics 2022-12-16 Shengyou Yang , Pradeep Sharma

Various authors have shown that, near the onset of a period-doubling bifurcation, small perturbations in the control parameter may result in much larger disturbances in the response of the dynamical system. Such amplification of small…

Chaotic Dynamics · Physics 2007-05-23 Xiaopeng Zhao , David G. Schaeffer , Carolyn M. Berger , Daniel J. Gauthier

In recent years the theory of border collision bifurcations has been developed for piecewise smooth maps that are continuous across the border, and has been successfully applied to explain nonsmooth bifurcation phenomena in physical…

Chaotic Dynamics · Physics 2011-10-13 Biswambhar Rakshit , Manjul Apratim , Parag Jain , Soumitro Banerjee

Master equation could be applied to model various kinds of biochemical systems. A general theory for its time-dependent nonequilibrium thermodynamics is rigorously derived. We not only introduce a concept of general internal energy, but…

Statistical Mechanics · Physics 2009-04-16 Hao Ge

We use a combination of perturbation theory and numerical techniques to study the equilibration of two interacting fields which are initially at thermal equilibrium at different temperatures. Using standard rules of quantum field theory, we…

High Energy Physics - Phenomenology · Physics 2009-11-07 E. Vaz , M. E. Carrington , R. Kobes , G. Kunstatter

We present numerical solution of the chlorine dioxide-iodine-malonic acid reaction-diffusion system in two dimensions in a boundary-fed system using a realistic model. The bifurcation diagram for the transition from non-symmetry breaking…

patt-sol · Physics 2009-10-31 S. Setayeshgar , M. C. Cross

The analysis of non-equilibrium steady states of biochemical reaction networks relies on finding the configurations of fluxes and chemical potentials satisfying stoichiometric (mass balance) and thermodynamic (energy balance) constraints.…

Molecular Networks · Quantitative Biology 2011-07-13 Daniele De Martino , Matteo Figliuzzi , Andrea De Martino , Enzo Marinari

We report in this paper a complete analytical study on the bifurcations and chaotic phenomena observed in certain second-order, non-autonomous, dissipative chaotic systems. One-parameter bifurcation diagrams obtained from the analytical…

Chaotic Dynamics · Physics 2019-03-13 G. Sivaganesh , A. Arulgnanam , A. N. Seethalakshmi