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We investigate the impact of combined electric and magnetic fields on the structure of ultralong-range polar Rydberg molecules. Our focus is hereby on the parallel as well as the crossed field configuration taking into account both the…

Atomic Physics · Physics 2014-09-11 Markus Kurz , Peter Schmelcher

Ultracold collisions of polar OH molecules are considered in the presence of an electrostatic field. The field exerts a strong influence on both elastic and state-changing inelastic collision rate constants, leading to clear experimental…

Atomic Physics · Physics 2009-11-07 Alexandr V. Avdeenkov , John L. Bohn

We theoretically investigate the properties of highly polar diatomic molecules containing $^2S$-state transition-metal atoms. We calculate potential energy curves, permanent electric dipole moments, spectroscopic constants, and leading…

Atomic Physics · Physics 2021-02-16 Michał Śmiałkowski , Michał Tomza

Ultracold collisions of the polyatomic species CaOH are considered, in internal states where the collisions should be dominated by long-range dipole-dipole interactions. The computed rate constants suggest that evaporative cooling can be…

Chemical Physics · Physics 2019-06-25 Lucie D. Augustovičová , John L. Bohn

The rapid development of experimental techniques to produce ultracold alkali molecules opens the ways to manipulate them and to control their dynamics using external electric fields. A prerequisite quantity for such studies is the knowledge…

In the extreme near-field, when the spatial extension of the atomic wavefunction is no longer negligible compared to the atom-surface distance, the dipole approximation is no longer sufficient to describe Casimir-Polder interactions. Here…

In this study, we reexamine the long-range interaction between two atoms placed in an equilibrium thermal radiation environment. Employing the formalism of quantum electrodynamics at finite temperatures, we derive an expression for the…

Atomic Physics · Physics 2023-12-19 T. Zalialiutdinov , D. Solovyev

Resonant dipole-dipole interaction modifies the energy and decay rate of electronic excitations for finite one dimensional chains of ultracold atoms in an optical lattice. We show that collective excited states of the atomic chain can be…

Quantum Physics · Physics 2012-12-07 Hashem Zoubi , Helmut Ritsch

We present an overview of our recent investigations of long-range interactions in an ultracold Cs Rydberg gas. These interactions are studied by high-resolution photoassociation spectroscopy, using excitation close to one-photon transitions…

Atomic Physics · Physics 2016-07-15 Heiner Saßmannshausen , Johannes Deiglmayr , Frédéric Merkt

The interaction of an electron with a local static charge distribution (e.g., an atom or molecule) is dominated at large distances by the radial 1/r Coulomb potential. The second order effect comes from the non-central electric dipole…

Quantum Physics · Physics 2023-02-08 A. D. Alhaidari , H. Bahlouli

We investigate the ultracold collisions of rotationally excited dipolar molecules in free-space, taking the hetero-nuclear bi-alkali molecule of KRb as an example. We show that we can sharply tune the elastic, inelastic and reactive rate…

Atomic Physics · Physics 2015-03-31 Gaoren Wang , Goulven Quéméner

The Hubbard model underlies our understanding of strongly correlated materials. While its standard form only comprises interaction between particles at the same lattice site, its extension to encompass long-range interaction, which…

Quantum Gases · Physics 2016-04-22 S. Baier , M. J. Mark , D. Petter , K. Aikawa , L. Chomaz , Zi Cai , M. Baranov , P. Zoller , F. Ferlaino

We show that the dipole-dipole interaction between three identical Rydberg atoms can give rise to bound trimer states. The microscopic origin of these states is fundamentally different from Efimov physics. Two stable trimer configurations…

Atomic Physics · Physics 2018-06-29 Martin Kiffner , Wenhui Li , Dieter Jaksch

We investigate the impact of an electric field on the structure of ultralong-range polar diatomic Rydberg molecules. Both the s-wave and p-wave interactions of the Rydberg electron and the neutral ground state atom are taken into account.…

Atomic Physics · Physics 2015-06-15 Markus Kurz , Peter Schmelcher

A Rydberg and a ground-state atom can form ultralong range diatomic molecules provided the interaction between the ground-state atom and the Rydberg electron is attractive [C. H. Greene, et al., Phys. Rev. Lett. 85, 2458 (2000)]. A…

Atomic Physics · Physics 2008-07-15 Ivan C. H. Liu , Jovica Stanojevic , Jan M. Rost

We show that the electric dipole-dipole interaction between a pair of polar molecules undergoes an all-out transformation when superimposed by a far-off resonant optical field. The combined interaction potential becomes tunable by variation…

Atomic Physics · Physics 2015-05-30 Mikhail Lemeshko , Bretislav Friedrich

Ultracold diatomic molecules find application in quantum studies ranging from controlled chemistry and precision measurement physics to quantum many-body simulation and potentially quantum computing. Accurate knowledge of molecular…

Atomic Physics · Physics 2024-05-14 Hela Ladjimi , Michał Tomza

We predict that pairs of polar molecules can be weakly bound together in an ultracold environment, provided that a dc electric field is present. The field that links the molecules together also strongly influences the basic properties of…

Atomic Physics · Physics 2009-11-07 A. V. Avdeenkov , J. L. Bohn

Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range, and spatially anisotropic. This is in stark contrast to the dilute gases of ultracold atoms, which have…

Atomic Physics · Physics 2015-05-18 K. -K. Ni , S. Ospelkaus , D. Wang , G. Quemener , B. Neyenhuis , M. H. G. de Miranda , J. L. Bohn , J. Ye , D. S. Jin

We consider ultralong-range polyatomic Rydberg molecules formed by combining a Rydberg cesium atom and a ground-state RbCs molecule. We explore the regime where the charge-dipole interaction due to the Rydberg electron with the diatomic…