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In a deviation from the conventional Hummers method, a spontaneous expansion approach was introduced with expanded graphite as the precursors. The intercalating agent (H2SO4) was able to penetrate into the expanded graphite; this had…

Materials Science · Physics 2013-07-30 Ling Sun , Bunshi Fugetsu

We investigate diffusion of a peptide drug through Graphene Oxide (GO) membranes that are modeled as a porous layered laminate constructed from aligned flakes of GO. Our experiments using a peptide drug show a tunable non-linear dependence…

Materials Science · Physics 2015-12-29 T. M. Puvirajesinghe , Z. L. Zhi , R. V. Craster , S. Guenneau

Graphene oxide (GO) is widely used in different applications, however once release into the environment it can change its structure and affect the transport of important contaminants such as arsenic. In this work we show that UV radiation,…

The adsorption of an alkali-metal submonolayer on graphene occupying every third hexagon of the honeycomb lattice in a commensurate $(\sqrt{3}\times\sqrt{3})R30^\circ$ arrangement induces an energy gap in the spectrum of graphene. To…

Materials Science · Physics 2009-01-27 M. Farjam , H. Rafii-Tabar

Electrolyte gating is a powerful means for tuning the carrier density and exploring the resultant modulation of novel properties on solid surfaces. However, the mechanism, especially its effect on the oxygen migration and electrostatic…

Silicon anodes offer high energy densities for next-generation lithium-ion batteries; however, their application is limited by severe volume expansion during cycling. Making silicon porous or nanostructured mitigates this expansion but…

In the quest for better energy storage solutions, the role of designing effective electrodes is crucial. Previous research has shown that using materials like single-side fluorinated graphene can improve the stability of ion insertion in…

Materials Science · Physics 2024-08-28 Yu-Hsiu Lin , Jose L. Mendoza-Cortes

This paper focuses on the performance of the storage of Li and the stability of the hybrid structure of different lattice planes of the silicon clusters and graphene by the first-principle theory. In this paper, we calculate the binding…

Mesoscale and Nanoscale Physics · Physics 2012-03-01 Wu Jiangbin , Qian Yao , Guo Xiaojie , Cui Xianhui , Miao Ling , Jiang Jianjun

We demonstrate top-gated field effect transistor made of reduced graphene oxide (RGO) monolayer (graphene) by dielectrophoresis. Raman spectrum of RGO flakes of typical size of 5{\mu}m x 5{\mu}m show a single 2D band at 2687 cm-1,…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 K. S. Vasu , Biswanath Chakraborty , S. Sampath , A. K. Sood

The electrical potential on the surface of $\sim 300$ nm thick SiO$_2$ grown on single crystalline Si substrates has been characterized at ambient conditions using electric field microscopy. Our results show an inhomogeneous potential…

Materials Science · Physics 2015-05-13 N. García , Zang Yan , A. Ballestar , J. Barzola-Quiquia , F. Bern , P. Esquinazi

The computational research that will be presented compares the coherent states of multiple layer graphene versus the coherent states of lithium ions diffused within this multilayer graphene. Unlike the prevailing research on graphene…

Mesoscale and Nanoscale Physics · Physics 2024-05-07 Donald C Boone

Developing applicable two-dimensional (2D) electrode materials with high performance, especially with high ion storage capacity, has become an ever more obsessive quest in recent years. Based on first-principles calculations, we report that…

Materials Science · Physics 2020-06-14 Xiaoming Zhang , Lei Jin , Xuefang Dai , Guifeng Chen , Guodong Liu

Separation of salt ions from seawater using graphene oxide (GO) membrane is an emerging desalination method. Here, we investigate the dynamic behavior of water, sodium, and chloride ions inside GO membrane using a computational approach.…

Chemical Physics · Physics 2021-08-25 One-Sun Lee

Methane, the primary constituent of natural gas, binds too weakly to nanostructured carbons to meet the targets set for on-board vehicular storage to be viable. We show, using density functional theory calculations, that replacing graphene…

Materials Science · Physics 2015-10-01 Rajiv K. Chouhan , Kanchan Ulman , Shobhana Narasimhan

With a swift progress in modern high-throughput communication systems, security, sensing and medicine utilizing THz range technologies, the demand for easy-to-fabricate, lightweight and high-performance absorbing materials has increased…

Materials Science · Physics 2025-07-30 A. Vasilev , M. Zhezhu , H. Parsamyan , G. Baghdasaryan , M. Sargsyan , D. A. Ghazaryan , H. Gharagulyan

Lithium titanium oxide Li$_4$Ti$_5$O$_{12}$ (LTO) is an intriguing anode material promising particularly long lived batteries, due to its remarkable phase stability during (dis)charging of the cell. However, its usage is limited by its low…

Materials Science · Physics 2020-01-03 Matthias Kick , Cristina Grosu , Markus Schuderer , Christoph Scheurer , Harald Oberhofer

Strain effects on the stabilization of Al ad-atom on graphene oxide(GO)nanosheet as well as its implications for NH3 storage have been investigated using first-principles calculations.The binding energy of Al ad-atom on GO is found to be a…

Materials Science · Physics 2015-06-05 Yunguo Li , Abir De Sarkar , Biswarup Pathak , Rajeev Ahuja

We develop a simple chemical method to obtain bulk quantities of N-doped, reduced graphene oxide (GO) sheets through thermal annealing of GO in ammonia. X-ray photoelectron spectroscopy (XPS) study of GO sheets annealed at various reaction…

Materials Science · Physics 2009-10-07 Xiaolin Li , Hailiang Wang , Joshua T. Robinson , Hernan Sanchez , Georgi Diankov , Hongjie Dai

The layer-by-layer (LbL) technique is adopted for the construction of multilayers encompassing chitosan and graphene oxide (GO) platelets capable of improving the flame retardant properties open cell PU foams. The LbL assembly follows a…

Chemical Physics · Physics 2018-06-29 Lorenza Maddalena , Federico Carosio , Julio Gomez , Guido Saracco , Alberto Fina

In the present study we investigate the irradiation-defects hybridized graphene scaffold as one potential building material for the anode of Li-ion batteries. Designating the Wigner V22 defect as a representative, we illustrate the…

Materials Science · Physics 2015-03-10 J. Song , B. Ouyang , N. V. Medhekar
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