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Spectroscopic measurements of the rotational distribution of $^{84}$Sr and $^{86}$Sr 5sns $^1S_0$ ultralong-range Rydberg molecular dimers created via photoassociation in a cold gas are reported. The dimers are produced by two-photon…

Atomic Physics · Physics 2024-06-14 C. Wang , Y. Lu , S. K. Kanungo , F. B. Dunning , T. C. Killian , S. Yoshida

We present a method to design a finite decay rate for excited rotational states in polar molecules. The setup is based on a hybrid system of polar molecules with atoms driven into a Rydberg state. The atoms and molecules are coupled via the…

Quantum Gases · Physics 2012-05-15 Sebastian D. Huber , Hans Peter Büchler

We investigate the dynamical formation of crystalline states with systems of polar molecules or Rydberg atoms loaded into a deep optical lattice. External fields in these systems can be used to couple the atoms or molecules between two…

Quantum Gases · Physics 2015-03-13 J. Schachenmayer , I. Lesanovsky , A. Micheli , A. J. Daley

We investigate polyatomic ultralong-range Rydberg molecules consisting of three ground state atoms bound to a Rydberg atom via $s$- and $p$-wave interactions. By employing the finite basis set representation of the unperturbed Rydberg…

Atomic Physics · Physics 2016-08-03 Christian Fey , Markus Kurz , Peter Schmelcher

We show the existence of ultra-long-range giant dipole molecules formed by a neutral alkali ground state atom that is bound to the decentered electronic wave function of a giant dipole atom. The adiabatic potential surfaces emerging from…

Atomic Physics · Physics 2012-03-14 Markus Kurz , Michael Mayle , Peter Schmelcher

In a combined experimental and theoretical effort, we demonstrate a novel type of dipolar system made of ultracold bosonic dipolar molecules with large magnetic dipole moments. Our dipolar molecules are formed in weakly bound Feshbach…

Ultracold Rydberg molecules have been extensively studied both theoretically and ex-perimentally. Here the authors review the recent realizations of various ultralong-range Rydberg molecules and macrodimers, and explore their potential for…

Atomic Physics · Physics 2018-07-04 J. P. Shaffer , S. T. Rittenhouse , H. R Sadeghpour

Rydberg atoms represent a platform underpinning many recent developments in quantum computation, simulation, sensing, and metrology. They further facilitate optical nonlinearity at the single-photon level when coupled to photons propagating…

We investigate the non-adiabatic quantum dynamics of ultralong-range Rydberg molecules using a vibronically coupled two-channel treatment. The two channels are composed of coupled trilobite and butterfly electronic states, formed as a…

Atomic Physics · Physics 2026-03-17 Felix Giering , Rohan Srikumar , Peter Schmelcher

It is common knowledge that atoms can form molecules if they attract each other. Here, we show that it is possible to create molecules where bound states of the atoms are not the result of attractive interactions but have the topological…

Quantum Physics · Physics 2022-09-05 Ali Emami Kopaei , Xuedong Tian , Krzysztof Giergiel , Krzysztof Sacha

We have studied the associative ionization of a Rydberg atom and a ground state atom in an ultracold Rydberg gas. The measured scattering cross section is three orders of magnitude larger than the geometrical size of the produced molecule.…

Atomic Physics · Physics 2017-08-24 Thomas Niederprüm , Oliver Thomas , Torsten Manthey , Tobias M. Weber , Herwig Ott

Rydberg excitons (analogues of Rydberg atoms in condensed matter systems) are highly excited bound electron-hole states with large Bohr radii. The interaction between them as well as exciton coupling to light may lead to strong optical…

We have performed high resolution photoassociation spectroscopy of rubidium ultra long-range Rydberg molecules in the vicinity of the 25$P$ state. Due to the hyperfine interaction in the ground state perturber atom, the emerging mixed…

Atomic Physics · Physics 2017-08-24 Thomas Niederprüm , Oliver Thomas , Tanita Eichert , Herwig Ott

The ability to control and tune interactions in ultracold atomic gases has paved the way towards the realization of new phases of matter. Whereas experiments have so far achieved a high degree of control over short-ranged interactions, the…

A highly sensitive, general, and preferably nondestructive technique to detect polar molecules would greatly advance a number of fields, in particular quantum science with cold and ultracold molecules. Here, we propose using resonant energy…

Atomic Physics · Physics 2017-06-23 Martin Zeppenfeld

Divalent atoms have emerged as powerful alternatives to alkalis in ultracold atom platforms, offering unique advantages arising from their two-electron structure. Among these species, ytterbium (Yb) is especially promising, yet its anionic…

Resonant electric dipole-dipole interactions between cold Rydberg atoms were observed using microwave spectroscopy. Laser-cooled Rb atoms in a magneto-optical trap were optically excited to 45d Rydberg states using a pulsed laser. A…

Atomic Physics · Physics 2007-05-23 K. Afrousheh , P. Z. Bohlouli , D. Vagale , A. Mugford , M. Fedorov , J. D. D. Martin

We propose to sympathetically slow and cool polar molecules in a cold, low-density beam using laser-cooled Rydberg atoms. The elastic collision cross sections between molecules and Rydberg atoms are large enough to efficiently thermalize…

We propose an experimentally realizable scheme to produce triatomic ultralong-range Rydberg molecules (TURM), formed in ultracold KRb traps. A near resonant coupling of the non-zero quantum defect Rydberg levels with the KRb molecule in N=0…

A three-level atomic medium can be made transparent to a resonant probe field in the presence of a strong control field acting on an adjacent atomic transition to a long-lived state, which can be represented by a highly excited Rydberg…

Quantum Physics · Physics 2017-03-16 David Petrosyan