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We demonstrate how to determine numerically nearly exact orthonormal orbitals that are optimal for evaluation of the energy of arbitrary (correlated) states of atoms and molecules by minimization of the energy Lagrangian. Orbitals are…

Rational Krylov subspaces have become a reference tool in dimension reduction procedures for several application problems. When data matrices are symmetric, a short-term recurrence can be used to generate an associated orthonormal basis. In…

Numerical Analysis · Mathematics 2021-12-21 Davide Palitta , Stefano Pozza , Valeria Simoncini

Currently, existing tensor recovery methods fail to recognize the impact of tensor scale variations on their structural characteristics. Furthermore, existing studies face prohibitive computational costs when dealing with large-scale…

Machine Learning · Computer Science 2025-07-09 Wenjin Qin , Hailin Wang , Jingyao Hou , Jianjun Wang

The numerical simulation of structural mechanics applications via finite elements usually requires the solution of large-size and ill-conditioned linear systems, especially when accurate results are sought for derived variables interpolated…

Numerical Analysis · Mathematics 2019-06-26 Andrea Franceschini , Victor A. Paludetto Magri , Gianluca Mazzucco , Nicolò Spiezia , Carlo Janna

Mixed-effects models are widely used to model data with hierarchical grouping structures and high-cardinality categorical predictor variables. However, for high-dimensional crossed random effects, current standard computations relying on…

Methodology · Statistics 2026-05-15 Pascal Kündig , Fabio Sigrist

With the recent realization of exascale performace by Oak Ridge National Laboratory's Frontier supercomputer, reducing communication in kernels like QR factorization has become even more imperative. Low-synchronization Gram-Schmidt methods,…

Numerical Analysis · Mathematics 2023-02-21 Kathryn Lund

The numerical simulation of the physical systems has become in recent years a fundamental tool to perform analyses and predictions in several application fields, spanning from industry to the academy. As far as large scale simulations are…

Numerical Analysis · Mathematics 2021-02-16 Giovanni Isotton , Matteo Frigo , Nicolò Spiezia , Carlo Janna

Fundamental theories and practical methods for large-scale electronic structure calculations are given, in which the computational cost is proportional to the system size. Accuracy controlling methods for microscopic freedoms are focused on…

Materials Science · Physics 2009-11-11 Takeo Hoshi , Takeo Fujiwara

The Lanczos algorithm is evaluated for solving the time-independent as well as the time-dependent Dirac equation with arbitrary electromagnetic fields. We demonstrate that the Lanczos algorithm can yield very precise eigenenergies and…

Computational Physics · Physics 2015-01-05 Randolf Beerwerth , Heiko Bauke

When applying Hamiltonian operator splitting methods for the time integration of multi-species Vlasov-Maxwell-Landau systems, the reliable and efficient numerical approximation of the Landau equation represents a fundamental component of…

Numerical Analysis · Mathematics 2025-12-23 Jose Antonio Carrillo , Mechthild Thalhammer

Recent advancements in quantum computing and quantum-inspired algorithms have sparked renewed interest in binary optimization. These hardware and software innovations promise to revolutionize solution times for complex problems. In this…

The Lanczos method is one of the most powerful and fundamental techniques for solving an extremal symmetric eigenvalue problem. Convergence-based error estimates depend heavily on the eigenvalue gap. In practice, this gap is often…

Numerical Analysis · Mathematics 2020-09-17 John C. Urschel

A previously proposed computational procedure for constructing a set of nonorthogonal strongly localised one-electron molecular orbitals (O. Danyliv, L. Kantorovich - physics/0401107) is applied to a perfect $\alpha$-quartz crystal…

Chemical Physics · Physics 2009-11-10 Oleh Danyliv , Lev Kantorovich

Quadratic forms of Hermitian matrix resolvents involve the solutions of shifted linear systems. Efficient iterative solutions use the shift-invariance property of Krylov subspaces The Hermitian Lanczos method reduces a given vector and…

Numerical Analysis · Mathematics 2020-10-15 Keiichi Morikuni

We present a parallel computation scheme based on the Arnoldi algorithm for exact diagonalization of quantum-electron models. It contains a selective data transferring method and distributed storage format for efficient computing of the…

Computational Physics · Physics 2010-04-21 S. N. Iskakov , V. V. Mazurenko

This work is on a user-friendly reduced basis method for solving a family of parametric PDEs by preconditioned Krylov subspace methods including the conjugate gradient method, generalized minimum residual method, and bi-conjugate gradient…

Numerical Analysis · Mathematics 2026-02-24 Yuwen Li , Ludmil T. Zikatanov , Cheng Zuo

This paper considers large scale constrained convex programs, which are usually not solvable by interior point methods or other Newton-type methods due to the prohibitive computation and storage complexity for Hessians and matrix…

Optimization and Control · Mathematics 2016-08-02 Hao Yu , Michael J. Neely

This paper introduces an efficient algorithm for finding the dominant generalized eigenvectors of a pair of symmetric matrices. Combining tools from approximation theory and convex optimization, we develop a simple scalable algorithm with…

Optimization and Control · Mathematics 2019-06-26 Vien V. Mai , Mikael Johansson

We present an efficient \textit{ab initio} method for calculating the electronic structure and total energy of strongly correlated electron systems. The method extends the traditional Gutzwiller approximation for one-particle operators to…

Strongly Correlated Electrons · Physics 2014-07-01 Y. X. Yao , J. Liu , C. Liu , W. C. Lu , C. Z. Wang , K. M. Ho

We consider the approximation of $B^T (A+sI)^{-1} B$ where $A\in\mathbb{R}^{n\times n}$ is large, symmetric positive definite, and has a dense spectrum, and $B\in\mathbb{R}^{n\times p}$, $p\ll n$. Our target application is the computation…

Numerical Analysis · Mathematics 2026-02-13 Jörn Zimmerling , Vladimir Druskin