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Related papers: A quantum Monte Carlo study of the ground state ch…

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We study the one-band Hubbard model on the honeycomb lattice using a combination of quantum Monte Carlo (QMC) simulations and static as well as dynamical mean-field theory (DMFT). This model is known to show a quantum phase transition…

Strongly Correlated Electrons · Physics 2020-03-09 Marcin Raczkowski , Robert Peters , Th\d{i} Thu Phùng , Nayuta Takemori , Fakher F. Assaad , Andreas Honecker , Javad Vahedi

The Diffusion Monte Carlo (DMC) method is applied to compute the ground state energies of the water monomer and dimer and their D 2 O isotopomers using MB-pol; the most recent and most accurate ab inito- based potential energy surface…

Chemical Physics · Physics 2015-10-28 Joel Mallory , Vladimir Mandelshtam

We investigate how the fixed-node diffusion Monte Carlo energy of solids depends on single-particle orbitals used in Slater--Jastrow wave functions. We demonstrate that the dependence can be significant, in particular in the case of 3d…

Materials Science · Physics 2010-09-09 Jindrich Kolorenc , Shuming Hu , Lubos Mitas

The quantum Monte Carlo (QMC) is one of the most promising many-body electronic structure approaches. It employs stochastic techniques for solving the stationary Schr\" odinger equation and for evaluation of expectation values. The key…

Other Condensed Matter · Physics 2007-12-20 Michal Bajdich

The real-space variation quantum Monte Carlo (VMC) and diffusion quantum Monte Carlo (DMC) are used to calculate the quasiparticle energy bands and the quasiparticle effective mass of the paramagnetic and ferromagnetic two-dimensional…

Strongly Correlated Electrons · Physics 2025-11-07 S. Azadi , N. D. Drummond , A. Principi , R. V. Belosludov , M. S. Bahramy

We report results of both Diffusion Quantum Monte Carlo(DMC) method and Reptation Quantum Monte Carlo(RMC) method on the potential energy curve of the helium dimer. We show that it is possible to obtain a highly accurate description of the…

Chemical Physics · Physics 2015-05-18 Xuebin Wu , Xianru Hu , Chenlei Du , Yunchuan Dai , Shibin Chu , Leibo Hu , Jianbo Deng , Yuanping Feng

We have carried out quantum Monte Carlo (QMC) calculations of silicon crystal focusing on the accuracy and systematic biases that affect the electronic structure characteristics. The results show that 64 and 216 atom supercells provide an…

Materials Science · Physics 2021-05-26 Abdulgani Annaberdiyev , Guangming Wang , Cody A. Melton , M. Chandler Bennett , Lubos Mitas

The search for two-dimensional (2D) magnetic materials has attracted a great deal of attention because of the experimental synthesis of 2D CrI$_3$, which has a measured Curie temperature of 45 K. Often times, these monolayers have a higher…

Strongly Correlated Electrons · Physics 2023-01-16 Daniel Wines , Kamal Choudhary , Francesca Tavazza

Diffusion Monte Carlo (DMC) is one of the most accurate techniques available for calculating the electronic properties of molecules and materials, yet it often remains a challenge to economically compute forces using this technique. As a…

Chemical Physics · Physics 2022-11-15 Cancan Huang , Brenda M. Rubenstein

On the base of Diffusion Monte-Carlo method it is developed a new Complex Diffusion Monte-Carlo (CDMC) method allowing to simulate the quantum systems with complex wave function. There are no approximations on the calculation of modulus and…

Condensed Matter · Physics 2007-05-23 B. Abdullaev , M. Musakhanov , A. Nakamura

We have used diffusion quantum Monte Carlo (DMC) calculations to study the pressure-induced phase transition from the diamond to $\beta$-tin structure in silicon. The calculations employ the pseudopotential technique and systematically…

Materials Science · Physics 2016-08-16 D. Alfè , M. J. Gillan , M. D. Towler , R. J. Needs

Bond stretching mimics different levels of electron correlation and provides a challenging testbed for approximate many-body computational methods. Using the recently developed phaseless auxiliary-field quantum Monte Carlo (AF QMC) method,…

Computational Physics · Physics 2007-10-10 W. A. Al-Saidi , Shiwei Zhang , Henry Krakauer

We have used the variational and diffusion quantum Monte Carlo methods to calculate the energy, pair correlation function, static structure factor, and momentum density of the ground state of the two-dimensional homogeneous electron gas. We…

Mesoscale and Nanoscale Physics · Physics 2010-03-02 N. D. Drummond , R. J. Needs

Diffusion Monte Carlo (DMC) is being recognized as a higher-accuracy, albeit more computationally expensive, alternative to Density Functional Theory (DFT) for energy predictions of catalytic systems. A major computational bottleneck in the…

Materials Science · Physics 2022-10-12 Gopal R. Iyer , Brenda M. Rubenstein

The self-healing diffusion Monte Carlo algorithm (SHDMC) [Phys. Rev. B {\bf 79}, 195117 (2009), {\it ibid.} {\bf 80}, 125110 (2009)] is shown to be an accurate and robust method for calculating the ground state of atoms and molecules. By…

Strongly Correlated Electrons · Physics 2015-05-14 Michal Bajdich , Murilo L. Tiago , Randolph Q. Hood , Paul R. C. Kent , Fernando A. Reboredo

Accurately predicting the formation energy of a compound, which describes its thermodynamic stability, is a key challenge in materials physics. Here, we employ many-body quantum Monte Carlo (QMC) with single-reference trial functions to…

We present clear numerical evidence for the coexistence of metallic and insulating dynamical mean field theory(DMFT) solutions in a half-filled single-band Hubbard model with bare semicircular density of states at finite temperatures.…

Strongly Correlated Electrons · Physics 2009-10-31 Jaewook Joo , Viktor Oudovenko

We have used diffusion Monte Carlo (DMC) simulations to calculate the energy barrier for H$_2$ dissociation on the Mg(0001) surface. The calculations employ pseudopotentials and systematically improvable B-spline basis sets to expand the…

Materials Science · Physics 2009-11-13 M. Pozzo , D. Alfe`

In this paper we apply the time-dependent quantum Monte Carlo (TDQMC) method to explore a midified single- and double-slit diffraction of matter waves. By using a simplified model of two electrons prepared in the ground state of an atom…

Quantum Physics · Physics 2025-02-07 Ivan P. Christov

Over 90 % of all chemical manufacture uses a solid catalyst. Related work thus responds to major societal demand. This study is of water-gas shift on platinum for hydrogen production. The close-packed Pt(111) surface catalyses this process.…

Materials Science · Physics 2020-04-23 Rajesh O. Sharma , Tapio T Rantala , Philip E Hoggan
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