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We develop a geometric foundation of microcanonical thermodynamics in which entropy and its derivatives are determined from the geometry of phase space, rather than being introduced through an a priori ensemble postulate. Once the minimal…

Statistical Mechanics · Physics 2025-12-30 Loris Di Cairano

Introduced by Boltzmann under the name "monode," the microcanonical ensemble serves as the fundamental representation of equilibrium thermodynamics in statistical mechanics by counting all possible realizations of a system's states.…

Statistical Mechanics · Physics 2026-01-27 Roman Belousov , Jenna Elliott , Florian Berger , Lamberto Rondoni , Anna Erzberger

Five different methods which can be used to analytically calculate entropies that are nonconcave as functions of the energy in the thermodynamic limit are discussed and compared. The five methods are based on the following ideas and…

Statistical Mechanics · Physics 2010-05-17 Hugo Touchette

Symmetry properties of the microcanonical entropy surface as a function of the energy and the order parameter are deduced from the invariance group of the Hamiltonian of the physical system. The consequences of these symmetries for the…

Statistical Mechanics · Physics 2009-11-10 Hans Behringer

We investigate the p-spin model with Gaussian-distributed random interactions in the microcanonical ensemble using the replica theory. For p=2, there are only second-order phase transitions and we recover the results of Sherrington and…

Statistical Mechanics · Physics 2014-09-08 Zsolt Bertalan , Hidethoshi Nishimori

We derive mean-field equations for a general class of ferromagnetic spin systems with an explicit error bound in finite volumes. The proof is based on a link between the mean-field equation and the free convolution formalism of random…

Mathematical Physics · Physics 2021-08-10 Christian Brennecke , Per von Soosten

A large deviation technique is applied to the mean-field phi4-model, providing an exact expression for the configurational entropy s(v,m) as a function of the potential energy v and the magnetization m. Although a continuous phase…

Statistical Mechanics · Physics 2007-05-23 Ingo Hahn , Michael Kastner

The microcanonical properties of a two dimensional system of N classical particles interacting via a smoothed Newtonian potential as a function of the total energy E and the total angular momentum L are discussed. In order to estimate…

Statistical Mechanics · Physics 2009-11-07 Olivier Fliegans , D. H. E. Gross

We study the configurational probability distribution of a mono-atomic gas with a finite number of particles N in the micro-canonical ensemble. We give two arguments why the thermodynamic entropy of the configurational subsystem involves…

Statistical Mechanics · Physics 2015-05-19 Maarten Baeten , Jan Naudts

We explore ensemble inequivalence in long-range interacting systems by studying an XY model of classical spins with ferromagnetic and nematic coupling. We demonstrate the inequivalence by mapping the microcanonical phase diagram onto the…

It has recently been shown, by application of statistical mechanical methods to determine the canonical ensemble governing the equilibrium distribution of operator initial values, that complex quantum field theory can emerge as a…

High Energy Physics - Theory · Physics 2009-10-30 Stephen L. Adler , L. P. Horwitz

We show how to generalise the zero temperature Lanczos method for calculating dynamical correlation functions to finite temperatures. The key is the microcanonical ensemble, which allows us to replace the involved canonical ensemble with a…

Strongly Correlated Electrons · Physics 2009-11-10 M. W. Long , P. Prelovsek , S. El Shawish , J. Karadamoglou , X. Zotos

Single crystals of $\alpha$-MnTe were synthesized by chemical vapor transport using iodine as the transport reagent. Structural characterization by powder x-ray diffraction confirmed the hexagonal structure (space group P6$_{3}$/mmc).…

It has been proved for a class of mean-field and long-range systems that the concavity of the thermodynamic entropy determines whether the microcanonical and canonical ensembles are equivalent at the level of their equilibrium states, i.e.,…

Statistical Mechanics · Physics 2011-11-29 Hugo Touchette

Microcanonical description is characterized by the presence of an internal symmetry closely related with the dynamical origin of this ensemble: the reparametrization invariance. Such symmetry possibilities the development of a non…

Statistical Mechanics · Physics 2007-05-23 L. Velazquez , F. Guzman

We present an exact microcanonical formulation, in the thermodynamic limit, for a system of $N$ noninteracting particles with $p$ equally spaced energy levels $\{0,\epsilon,2\epsilon,\ldots,(p-1)\epsilon\}$. Writing the microcanonical…

Statistical Mechanics · Physics 2026-05-05 J. Ricardo de Sousa

In this paper we give a complete analysis of the phase transitions in the mean-field Blume-Emery-Griffiths lattice-spin model with respect to the canonical ensemble, showing both a second-order, continuous phase transition and a…

Probability · Mathematics 2007-05-23 Richard S. Ellis , Peter T. Otto , Hugo Touchette

Several approximations are made to study the microcanonical formalism that are valid in the thermodynamics limit. Usually it is assumed that: 1)Stirling approximation can be used to evaluate the number of microstates; 2) the surface entropy…

General Physics · Physics 2015-10-07 E. N. Miranda , Dalia S. Bertoldi

In the paper a study of a model magnetoelastic solid system is presented. The system of interest is a mean-field magnet with nearest-neighbour ferromagnetic interactions and the underlying s.c. crystalline lattice with the long-range Morse…

Statistical Mechanics · Physics 2017-09-15 K. Szałowski , T. Balcerzak , M. Jaščur

In this paper we give a complete analysis of the phase transitions in the mean-field Blume-Emery-Griffiths lattice-spin model with respect to the canonical ensemble, showing both a second-order, continuous phase transition and a…

Statistical Mechanics · Physics 2007-05-23 R. S. Ellis , P. Otto , H. Touchette