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A new mechanism is proposed to explain the origin of negative differential resistance (NDR) in a strongly coupled single molecule-metal junction. A first-principles quantum transport calculation in a Fe-terpyridine linker molecule…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Ranjit Pati , Mike McClain , Anirban Bandyopadhyay

Using self-consistent calculations based on Non-Equilibrium Green's Function (NEGF) formalism, the origin of negative differential resistance (NDR) in molecular junctions and quantum wires is investigated. Coupling of the molecule to…

Mesoscale and Nanoscale Physics · Physics 2008-08-21 Hosein Cheraghchi , Keivan Esfarjani

Negative differential resistance (NDR) is tuned at junctions of electronically different dimer and trimer of Rose Bengal on an atomic flat gold (111) surface. Isolated molecule did not show any NDR. But it was induced to show double NDR…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Anirban Bandyopadhyay , Y. Wakayama

We determine the conditions in which negative differential resistance (NDR) appears in the C$_{60}$-based molecular device of [Phys. Rev. Lett. {\bf 100}, 036807 (2008)] by means of ab-initio electron-transport simulations. Our calculations…

Mesoscale and Nanoscale Physics · Physics 2015-03-17 Frederico D. Novaes , Manuel Cobian , Alberto Garcia , Pablo Ordejon , Hiromu Ueba , Nicolas Lorente

Multipeak negative differential resistance (NDR) molecular devices are designed from first principles. The effect of NDR is associated with the non-linear Stark shifts and the electron localization within the conductive region and contacts.…

Mesoscale and Nanoscale Physics · Physics 2015-01-07 Mikolaj Sadek , Malgorzata Wierzbowska , Michal F. Rode , Andrzej L. Sobolewski

We propose and demonstrate through first-principles calculation a new spin-dependent negative differential resistance (NDR) mechanism in magnetic tunnel junctions (MTJ) with cubic cation disordered crystals (CCDC) AlO$_x$ or…

Materials Science · Physics 2016-05-25 Jun Jiang , X. -G. Zhang , X. F. Han

We unravel the critical role of vibrational mode softening in single-molecule electronic devices at high bias. Our theoretical analysis is carried out with a minimal model for molecular junctions, with mode softening arising due to…

Mesoscale and Nanoscale Physics · Physics 2020-08-18 Junjie Liu , Dvira Segal

Motivated by recent experiments, we have studied transport behavior of coupled quantum dot systems in the Coulomb blockade regime using the master (rate) equation approach. We explore how electron-electron interactions in a donor-acceptor…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Prakash Parida , S Lakshmi , Swapan K Pati

A negative differential resistance (NDR) in the nanotransport is often ascribed to electron correlations. We present a simple example which demonstrates that finite electrode bandwidths and energy dependent electrode density of states are…

Mesoscale and Nanoscale Physics · Physics 2010-05-12 Ioan Baldea , Horst Koppel

Negative differential resistance - a decrease in current with increasing bias voltage - is a counter-intuitive effect that is observed in various molecular junctions. Here, we present a novel mechanism that may be responsible for such an…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 Yonatan Dubi

Reaction currents in chemical networks usually increase when increasing their driving affinities. But far from equilibrium the opposite can also happen. We find that such negative differential response (NDR) occurs in reaction schemes of…

Statistical Mechanics · Physics 2019-07-24 Gianmaria Falasco , Tommaso Cossetto , Emanuele Penocchio , Massimiliano Esposito

We have observed tunable negative differential resistance (NDR) in scanning tunneling spectroscopy measurements of a double layer of C60 molecules on a metallic surface. Using a simple model we show that the observed NDR behavior is…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. Grobis , A. Wachowiak , R. Yamachika , M. F. Crommie

We investigate the atomic-scale tunneling characteristics of bilayer graphene on silicon carbide using the scanning tunneling microscopy. The high-resolution tunneling spectroscopy reveals an unexpected negative differential resistance…

We have carried out calculations of electron transport through a metal-molecule-metal junction with metal nanoclusters taking the part of electrodes. We show that negative differential resistance peaks could appear in the current-voltage…

Materials Science · Physics 2008-10-22 Natalya A. Zimbovskaya , Mark R. Pederson

The conductance-voltage spectrum of molecular nanostructures measured by scanning tunneling spectroscopy (STS) is generally assumed to reflect the local density of states of the molecule. This excludes the possibility of observing negative…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Yongqiang Xue , Supriyo Datta , Seunghun Hong , R. Reifenberger , Jason I. Henderson , Cliff P. Kubiak

Both experiments and theoretical studies have demonstrated that the interaction between the current carrying electrons and the induced polarization charge in single-molecule junctions leads to a strong renormalization of molecular charging…

Mesoscale and Nanoscale Physics · Physics 2013-11-22 K. Kaasbjerg , K. Flensberg

We demonstrate, based on low-temperature scanning tunneling microscopy (STM) and spectroscopy, a pronounced negative differential resistance (NDR) in spin-crossover (SCO) molecular devices, where a Fe$^{\text{II}}$ SCO molecule is deposited…

We present the appearance of negative differential resistance (NDR) in spin-dependent electron transport through a few-atom spin-chain. A chain of three antiferromagnetically coupled Fe atoms(Fe trimer) was positioned on a Cu2N/Cu(100)…

Nonlinear electrical properties, such as negative differential resistance (NDR), are essential in numerous electrical circuits, including memristors. Several physical origins have been proposed to lead to the NDR phenomena in semiconductor…

The effect of electric field, applied on systems in the nanoscale regime has attracted a lot of research in recent times. We highlight some of the recent results in the field of single molecule electronics and then move on to focus on some…

Materials Science · Physics 2008-10-11 S. Lakshmi , Sudipta Dutta , Swapan K. Pati
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