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Nucleation and growth mechanisms of short chains of carbon atoms on single-layer, hexagonal boron nitride (h-BN), and short BN chains on graphene are investigated using first-principles plane wave calculations. Our analysis starts with the…

Mesoscale and Nanoscale Physics · Physics 2013-01-17 V. Ongun Özçelik , S. Ciraci

Graphene, a hexagonal sheet of $sp^2$-bonded carbon atoms, has extraordinary properties which hold immense promise for future nanoelectronic applications. Unfortunately, the popular preparation methods of micromechanical cleavage and…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Andrew Zangwill , Dimitri D. Vvedensky

The formation of one-dimensional carbon chains from graphene nanoribbons is investigated using it ab initio molecular dynamics. We show under what conditions it is possible to obtain a linear atomic chain via pulling of the graphene…

Materials Science · Physics 2015-05-14 Edwin Hobi , Renato B. Pontes , A. Fazzio , Antonio J. R. da Silva

As a two-dimensional material, graphene can be naturally obtained via epitaxial growth on a suitable substrate. Growth condition optimization usually requires an atomistic level understanding of the growth mechanism. In this article, we…

Materials Science · Physics 2012-04-06 Ping Wu , Huijun Jiang , Wenhua Zhang , Zhenyu Li , Zhonghuai Hou , Jinlong Yang

We investigate the growth of the recently demonstrated composite material composed of vertically aligned carbon nanotubes capped by few graphene layers. We show that the carbon nanotubes grow epitaxially under the few graphene layers. By…

Materials Science · Physics 2011-03-24 V. Jousseaume , J. Cuzzocrea , N. Bernier , Vincent Thomas Francois Renard

Linear chains of about 10-13 carbon atoms were predicted to be the most favorable phase on different metal surfaces prior to graphene nucleation. However, unlike the graphene that widely studied both theoretically and experimentally, carbon…

Mesoscale and Nanoscale Physics · Physics 2017-12-15 T. V. Pavlova , S. L. Kovalenko , K. N. Eltsov

Recent years witnessed a rapid growth of interest of scientific and engineering communities to thermal properties of materials. Carbon allotropes and derivatives occupy a unique place in terms of their ability to conduct heat. The…

Materials Science · Physics 2015-05-28 Alexander A. Balandin

We report a technique which allows self-assembly of conducting nanoparticles into long continuous chains. Transport properties of such chains have been studied at low temperatures. At low bias voltages, the charges are pinned and the chain…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 A. Bezryadin , R. M. Westervelt , M. Tinkham

Thermal decomposition of silicon carbide is a promising approach for the fabrication of graphene. However, the atomistic growth mechanism of graphene remains unclear. This paper describes the development of a new charge-transfer interatomic…

Materials Science · Physics 2018-03-13 So Takamoto , Takahiro Yamasaki , Jun Nara , Takahisa Ohno , Chioko Kaneta , Asuka Hatano , Satoshi Izumi

Three typical one-dimensional (1D)/quasi-1D nanocarbons, linear carbon chains, carbon nanotubes, and graphene nanoribbons have been proven to grow inside single-wall carbon nanotubes. This gives rise to three types of hybrid materials whose…

Materials Science · Physics 2021-01-29 Weili Cui , Takeshi Saito , Paola Ayala , Thomas Pichler , Lei Shi

Fundamentally new families of carbon single walled nanotubes are proposed. These nanotubes, called graphynes, result from the elongation of covalent interconnections of graphite-based nanotubes by the introduction of yne groups. Similarly…

Materials Science · Physics 2007-05-23 V R. Coluci , S F Braga , S B Legoas , D S Galvao , R H Baughman

Carbon is one of the most intriguing elements in the Periodic Table. It forms many allotropes, some being known from ancient times (diamond and graphite) and some discovered ten to twenty years ago (fullerenes, nanotubes). Quite…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. I. Katsnelson

The discovery of graphene, a single layer of covalently bonded carbon atoms, has attracted intense interests. Initial studies using mechanically exfoliated graphene unveiled its remarkable electronic, mechanical and thermal properties.…

Materials Science · Physics 2013-07-23 Ting Fung Chung , Tian Shen , Helin Cao , Luis A. Jauregui , Wei Wu , Qingkai Yu , David Newell , Yong P. Chen

Graphene forms from a relatively dense, tightly-bound C-adatom gas, when elemental C is deposited on or segregates to the Ru(0001) surface. Nonlinearity of the graphene growth rate with C adatom density suggests that growth proceeds by…

Materials Science · Physics 2010-12-14 E. Loginova , N. C. Bartelt , P. J. Feibelman , K. F. McCarty

An atomic carbon chain joining two graphene flakes was recently realized in a ground-breaking experiment by Jin {\it et al.}, Phys. Rev. Lett. {\bf 102}, 205501 (2009). We present {\it ab initio} results for the electron transport…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Joachim A. Fuerst , Mads Brandbyge , Antti-Pekka Jauho

The development of wafer-scale continuous single-crystal graphene layers is key in view of its prospective applications. To this end, here we pave the way for a graphene growth model in the framework of the Langmuir adsorption theory and…

Materials Science · Physics 2013-05-14 HoKwon Kim , Eduardo Saiz , Manish Chhowalla , Cecilia Mattevi

Graphene, a single atomic layer of graphitic carbon, has attracted intense attention due to its extraordinary properties that make it a suitable material for a wide range of technological applications. Large-area graphene films, which are…

Mesoscale and Nanoscale Physics · Physics 2015-02-18 Oleg V. Yazyev , Yong P. Chen

Although the corresponding carbon-metal interactions can be very different, a similar nonlinear growth behavior of graphene has been observed for different metal substrates. To understand this interesting experimental observation, a…

Materials Science · Physics 2013-09-10 Huijun Jiang , Ping Wu , Zhonghuai Hou , Zhenyu Li , Jinlong Yang

Large-area graphene is a new material with properties that make it desirable for advanced scaled electronic devices1. Recently, chemical vapor deposition (CVD) of graphene and few-layer graphene using hydrocarbons on metal substrates such…

Materials Science · Physics 2015-05-13 Xuesong Li , Weiwei Cai , Luigi Colombo , Rodney S. Ruoff

The power of polymorphism in carbon is vividly manifested by the numerous applications of carbon-based nano-materials. Ranging from environmental issues to biomedical applications, it has the potential to address many of today's dire…

Materials Science · Physics 2017-03-28 Obaidur Rahaman , Bohayra Mortazavi , Arezoo Dianat , Gianaurelio Cuniberti , Timon Rabczuk
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