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We introduce a method for classical trajectory calculations to simulate collisions between atoms and large rigid asymmetric-top molecules. Using this method, we investigate the formation of molecule-helium complexes in buffer-gas cooling…

Chemical Physics · Physics 2015-06-03 Zhiying Li , Eric J. Heller

We explore the physical origin and the general validity of a propensity rule for the conservation of the hyperfine spin state in three-body recombination. This rule was recently discovered for the special case of $^{87}$Rb with its nearly…

This work aims to study the energy transfer and recombination processes in N$_{2}$$\left(^{1}\sum^{+}_{g}\right)$+N$\left(^{4}S_{u}\right)$ and O$_{2}$$\left(^{3}\sum^{+}_{g}\right)$+O$\left(^{3}P_{2}\right)$ chemical systems when the…

Chemical Physics · Physics 2025-07-15 Aakanksha Notey , Sung Min Jo , Marco Panesi

We develop a full multichannel spin model in momentum space to investigate three-body recombination of identical alkali-metal atoms colliding in a magnetic field. The model combines the exact three-atom spin structure and realistic pairwise…

Quantum Gases · Physics 2021-02-24 T. Secker , J. -L. Li , P. M. A. Mestrom , S. J. J. M. F. Kokkelmans

We report precision, orbital-resolved measurements of three-body recombination near the 159~G $p$-wave Feshbach resonance in an ultracold gas of $^{6}$Li atoms prepared in their lowest hyperfine state. Using a radio-frequency gated protocol…

Quantum Gases · Physics 2025-12-03 Shaokun Liu , Zhekang Xu , Shuai Peng , Sijia Peng , Tangqian Shu , Jiaming Li , Le Luo

We present a study of vibrational quenching and chemical processes of molecular ions immersed in an ultracold atomic gas by means of the quasi-classical trajectory (QCT) method. In particular, BaRb$^+(v)$ + Rb collisions are studied at cold…

Atomic Physics · Physics 2019-02-27 Jesús Pérez-Ríos

Molecular beam experiments that use low-temperature bolometers as (energy-) detectors are well suited to the study of physisorption and recombination of hydrogen on low-temperature surfaces. Experiments where this technique is combined with…

Chemical Physics · Physics 2007-05-23 Thomas Govers

Aiming at a microscopic description of heavy ion collisions in the beam energy region of about 10 A GeV, we extend the Giessen Boltzmann-Uehling-Uhlenbeck (GiBUU) transport model by including a relativistic mean field, in-medium…

Nuclear Theory · Physics 2008-11-26 A. B. Larionov , O. Buss , K. Gallmeister , U. Mosel

The hydronium cation plays a crucial role in interstellar oxygen and water chemistry. While its spectroscopy was extensively investigated earlier, the collisional excitation of H$_3$O$^+$ is not well studied yet. In this work we present…

Chemical Physics · Physics 2022-11-07 S. Demes , François Lique , Alexandre Faure , Floris van der Tak , Claire Rist , Pierre Hily-Blant

We have developed a new potential energy surface for spin-polarized K($^2$S) + K$_{2}(^3\Sigma^+_u)$ collisions and carried out quantum dynamical calculations of vibrational quenching at low and ultralow collision energies for both bosons…

Other Condensed Matter · Physics 2009-11-10 G. Quemener , P. Honvault , J. -M. Launay , P. Soldan , D. E. Potter , J. M. Hutson

We present accurate ab initio and quantum scattering calculations on a prototypical hybrid ion-atom system Yb$^+$-Rb, recently suggested as a promising candidate for the experimental study of open quantum systems, quantum information…

Atomic Physics · Physics 2016-09-29 Timur V. Tscherbul , Paul Brumer , Alexei A. Buchachenko

Rate coefficients for inelastic collisions between Li and H atoms covering all transitions between the asymptotic states Li(2s,2p,3s,3p,3d,4s,4p,4d,4f)+H(1s) and Li^+ +H^- are presented for the temperature range 2000-8000 K based on recent…

Astrophysics · Physics 2009-11-10 P. S. Barklem , A. K. Belyaev , M. Asplund

A further development of the evolutionary picture of A+A collisions, which we call the integrated HydroKinetic Model (iHKM), is proposed. The model comprises a generator of the initial state GLISSANDO, pre-thermal dynamics of A+A collisions…

High Energy Physics - Phenomenology · Physics 2016-02-08 V. Yu. Naboka , Iu. A. Karpenko , Yu. M. Sinyukov

The effect of conical intersections (CIs) on electronic relaxation, transitions from excited states to ground states, is well studied, but their influence on hyperfine quenching in a reactant molecule is not known. Here, we report on…

Chemical Physics · Physics 2021-01-29 Ming Li , Jacek Klos , Alexander Petrov , Hui Li , Svetlana Kotochigova

We analyze the formation of squeezed states in a condensate of ultracold bosonic atoms confined by a double-well potential. The emphasis is set on the dynamical formation of such states from initially coherent many-body quantum states. Two…

Quantum Gases · Physics 2012-09-04 B. Juliá-Díaz , T. Zibold , M. K. Oberthaler , M. Melé-Messeguer , J. Martorell , A. Polls

The reactive collisions of the CH$^+$ molecular ion with electrons is studied in the framework of the multichannel quantum defect theory, taking into account the contribution of the core-excited Rydberg states. In addition to the…

Instrumentation and Methods for Astrophysics · Physics 2024-05-01 K. Chakrabarti , J. Zs Mezei , O. Motapon , A. Faure , O. Dulieu , K. Hassouni , I. F. Schneider

We show that many aspects of ultracold three-body collisions can be controlled by choosing the mass ratio between the collision partners. In the ultracold regime, the scattering length dependence of the three-body rates can be substantially…

Atomic Physics · Physics 2009-11-11 J. P. D'Incao , B. D. Esry

We report a combined experimental and theoretical study of collision-induced dipolar relaxation in a cold spin-polarized gas of atomic nitrogen (N). We use buffer gas cooling to create trapped samples of 14N and 15N atoms with densities…

Atomic Physics · Physics 2011-03-07 T. V. Tscherbul , J. Klos , A. Dalgarno , B. Zygelman , Z. Pavlovic , M. T. Hummon , H-I Lu , E. Tsikata , J. M. Doyle

A numerically solvable two-dimensional (2D) model, employed by the authors to study the dissociative recombination of H$_2^+$ in the ungerade symmetry [Phys. Rev. A $\mathbf{98}$, 062706 (2018)], is extended to describe the collision…

Chemical Physics · Physics 2025-11-26 Dávid Hvizdoš , Roman Čurík , Chris H. Greene

We develop a rigorous quantum mechanical theory for collisions of polyatomic molecular radicals with S-state atoms in the presence of an external magnetic field. The theory is based on a fully uncoupled space-fixed basis set representation…

Chemical Physics · Physics 2012-09-17 T. V. Tscherbul , T. A. Grinev , H. -G. Yu , A. Dalgarno , Jacek Klos , Lifang Ma , Millard H. Alexander