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Continuum electrolyte models represent a practical tool to account for the presence of the diffuse layer at electrochemical interfaces. However, despite the increasing popularity of these in the field of materials science it remains unclear…

Computational Physics · Physics 2019-01-18 Francesco Nattino , Matthew Truscott , Nicola Marzari , Oliviero Andreussi

We introduce a local machine-learning method for predicting the electron densities of periodic systems. The framework is based on a numerical, atom-centred auxiliary basis, which enables an accurate expansion of the all-electron density in…

Chemical Physics · Physics 2021-11-10 Alan M. Lewis , Andrea Grisafi , Michele Ceriotti , Mariana Rossi

The absolute L subshell specific electron impact ionization cross sections near the ionization threshold (16 < E < 45 keV) of Lead and Thorium are obtained from the measured L X-ray production cross sections. Monte Carlo simulation is done…

Atomic Physics · Physics 2015-08-26 H. V. Rahangdale , P. K. Das , S. De , J. P. Santos , D. Mitra , M. Guerra , S. Saha

In the past two decades, the electron-ion merged-beams technique has extensively been exploited at heavy-ion storage rings equipped with electron coolers for spectroscopic studies of highly charged ions as well as for measuring absolute…

Atomic Physics · Physics 2015-01-22 Stefan Schippers

The mathematical P2D model is a system of strongly coupled nonlinear parabolic-elliptic equations that describes the electrodynamics of lithium-ion batteries. In this paper, we present the numerical analysis of a finite element-implicit…

Numerical Analysis · Mathematics 2021-09-23 Rodolfo Bermejo

Electron elastic-scattering phase shifts and cross sections along with the differential and total cross sections and polarization of low-frequency bremsstrahlung upon low-energy electron collision with endohedral fullerenes $A$@C$_{60}$ are…

Atomic Physics · Physics 2015-02-26 V. K. Dolmatov , C. Bayens , M. B. Cooper , M. E. Hunter

(Abridged) Electron-molecule interaction is a fundamental process in radiation-driven chemistry in space, from the interstellar medium to comets. Therefore, knowledge of interaction cross-sections is key. While there has been a plethora of…

The electric double layer (EDL) formed around charged nanostructures at the liquid-solid interface determines their electrochemical activity and influences their electrical and optical polarizability. We experimentally demonstrate that…

Soft Condensed Matter · Physics 2020-04-29 Kevin Namink , Xuanhui Meng , Marc T. M. Koper , Philipp Kukura , Sanli Faez

A semiclassical impact parameter version of the continuum distorted wave-Eikonal initial state theory is developed to study the differential ionization of $Li$ atoms in collisions with $Li^{2+}$ ions. Both post and prior forms of the…

Atomic Physics · Physics 2018-05-09 Omid Ghorbani , Ebrahim Ghanbari-Adivi , Marcelo Fabian Ciappina

Backscattering is a sensitive probe of the accuracy of electron scattering algorithms implemented in Monte Carlo codes. The capability of the Geant4 toolkit to describe realistically the fraction of electrons backscattered from a target…

Understanding ion-matter interactions at the atomistic level is key to advancing materials for the semiconductor industry, space systems, and nuclear fusion technologies. However, most atomistic frameworks still rely on simplified…

Materials Science · Physics 2026-03-12 Evgeniia Ponomareva , Artur Tamm , Andrea E. Sand

A new supersymmetric model for electrons with generalized hopping terms and Hubbard interaction on a one-dimensional lattice is solved by means of the Bethe Ansatz. We investigate the phase diagram of this model by studying the ground state…

Condensed Matter · Physics 2009-10-28 Gerald Bedürftig , Holger Frahm

Understanding nuclear effects is essential for improving the sensitivity of neutrino oscillation measurements. Validating nuclear models solely through neutrino scattering data is challenging due to limited statistics and the broad energy…

High Energy Physics - Phenomenology · Physics 2025-02-25 Seisho Abe

We apply a recently introduced model for an independent-atom-like calculation of ion-impact electron transfer and ionization cross sections to proton collisions from water, neon, and carbon clusters. The model is based on a geometrical…

Atomic and Molecular Clusters · Physics 2018-12-20 Hans Jürgen Lüdde , Marko Horbatsch , Tom Kirchner

We present a new semi-empirical model for calculating electron transport in atomic-scale devices. The model is an extension of the Extended H\"uckel method with a self-consistent Hartree potential. This potential models the effect of an…

Mesoscale and Nanoscale Physics · Physics 2012-04-04 Kurt Stokbro , Dan Erik Petersen , Søren Smidstrup , Anders Blom , Mads Ipsen , Kristen Kaasbjerg

The interfaces between metal electrodes and liquid electrolytes are prototypical in electrochemistry. That is why it is crucial to have a molecular and dynamical understating of such interfaces for both electrical properties and chemical…

Chemical Physics · Physics 2023-10-06 Linnéa Andersson , Chao Zhang

Net ionization and net capture cross-section calculations are presented for proton collisions from methane molecules and the DNA/RNA nucleobases adenine, cytosine, guanine, thymine, and uracil. We use the recently introduced…

Atomic and Molecular Clusters · Physics 2019-12-11 Hans Juergen Luedde , Marko Horbatsch , Tom Kirchner

The electron density of a molecule or material has recently received major attention as a target quantity of machine-learning models. A natural choice to construct a model that yields transferable and linear-scaling predictions is to…

Chemical Physics · Physics 2022-06-29 Andrea Grisafi , Alan M. Lewis , Mariana Rossi , Michele Ceriotti

Modelling electrolytes accurately on both a nanoscale and cell level can contribute to improving battery chemistries.[Armand and Tarascon, Nature, 2008, 451, 652-657] We previously presented a thermodynamic continuum model for…

Chemical Physics · Physics 2024-08-09 Constantin Schwetlick , Max Schammer , Arnulf Latz , Birger Horstmann

The purpose of this study is to provide data for the primitive model of the electrical double layer, where ions are modeled as charged hard spheres, the solvent as an implicit dielectric background (with dielectric constant $\epsilon=…

Soft Condensed Matter · Physics 2017-12-01 Mónika Valiskó , Tamás Kristóf , Dirk Gillespie , Dezső Boda