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We study structural properties of a ring polymeric melt confined in a film in comparison to a linear counterpart using molecular dynamics simulations. Local structure orderings of ring and linear polymers in the vicinity of the surface are…
In this review we provide an organized summary of the theoretical and computational results which are available for polymers subject to spatial or topological constraints. Because of the interdisciplinary character of the topic, we provide…
Fragmentation can be observed in nature and in everyday life on a wide range of length scales and for all kinds of technical applications. Most studies on dynamic failure focus on the behaviour of bulk systems in one, two and three…
In this article we study the trapped motion of a molecule undergoing diffusivity fluctuations inside a harmonic potential. For the same diffusing-diffusivity process, we investigate two possible interpretations. Depending on whether…
We consider the trapping reaction, $A+B\to B$, where $A$ and $B$ particles have a diffusive dynamics characterized by diffusion constants $D_A$ and $D_B$. The interaction with $B$ particles can be formally incorporated in an effective…
The structure of lamellar phases of symmetric $AB$ diblock copolymers in a thin film is investigated. We quantitatively compare the composition profiles and profiles of individual segments in self-consistent field calculations with Monte…
The long range properties of four-dimensional compact U(1) lattice gauge theory with the Wilson action in the confinement phase is studied by using the multi-level algorithm. The static potential, force and flux-tube profile between two…
The structure of flexible polymers endgrafted in cylindrical pores of diameter D is studied as a function of chain length N and grafting density \sigma, assuming good solvent conditions. A phenomenological scaling theory, describing the…
Brownian dynamics simulations are used to study highly entangled solutions of semiflexible polymers. Bending fluctuations of semiflexible rods are signficantly affected by entanglement only above a concentration $c^{**}$, where $c^{**}\sim…
The analytical probability distribution of finite systems obeying Bose-Einstein statistics in one, two, and three dimensions are investigated by using a canonical ensemble approach. Starting from the canonical partition function of the…
The effect of confining walls on the fluctuation of a nanoscale thin film's free surface is studied using stochastic thin-film equations (STFEs). Two canonical boundary conditions are employed to reveal the influence of the confinement: (1)…
We investigate the random close packing density, $\phi_\textrm{RCP}$, of polydisperse hard sphere systems using a theoretical framework based on the equilibrium model of crowding. We derive a closed-form solution for $\phi_\textrm{RCP}$ in…
Experiments using nanofluidic devices have proven effective in characterizing the physical properties of polymers confined to small cavities. Two recent studies using such methods examined the organization and dynamics of two DNA molecules…
The scalar potential, time component vector potential and flux tube quark confinements are studied in this paper. We find that the predictions of scalar confinement and time component vector confinement are in considerable conflict with…
We have performed confocal microscopy experiments and computer simulations of colloidal suspensions with moderate volume fraction confined between two quasi-parallel, rough walls [A. Villada-Balbuena et al., Soft Matter, 2022, 18,…
We study the stability and breakup behavior of an axisymmetric liquid thread which is surrounded by another viscous fluid layer through a long wave approximation. The two fluids are immiscible and confined in a concentrically placed…
We investigate the asymptotic properties of random polytopes arising as convex hulls of $n$ independent random points sampled from a family of block-beta distributions. Notably, this family includes the uniform distribution on a product of…
We study the position of a biased tracer particle (TP) in a bath of hardcore particles moving on a lattice of arbitrary dimension and in contact with a reservoir. Starting from the master equation satisfied by the joint probability of the…
We review a recently proposed theory of random packings. We describe the volume fluctuations in jammed matter through a volume function, amenable to analytical and numerical calculations. We combine an extended statistical mechanics…
Colloidal particles that are confined to an interface such as the air-water interface are an example of a two-dimensional fluid. Such dispersions have been observed to spontaneously form cluster and stripe morphologies in certain systems…