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We apply the Lang-Firsov (LF) transformation to electron-boson coupled Hamiltonians and variationally optimize the transformation parameters and molecular orbital coefficients to determine the ground state. M\o{}ller-Plesset (MP-$n$, with…

Chemical Physics · Physics 2024-02-05 Zhi-Hao Cui , Arkajit Mandal , David R. Reichman

When electron correlations are important it is often necessary to use numerical methods to solve the Hamiltonian for a finite system (cluster) "exactly". Unfortunately, such methods are restricted to small systems. We propose to combine the…

Strongly Correlated Electrons · Physics 2009-10-31 Maciej M. Maska

We consider spectral clustering algorithms for community detection under a general bipartite stochastic block model (SBM). A modern spectral clustering algorithm consists of three steps: (1) regularization of an appropriate adjacency or…

Statistics Theory · Mathematics 2018-12-27 Zhixin Zhou , Arash A. Amini

A review of the coupled cluster method (CCM) applied to lattice quantum spin systems is presented here. The CCM formalism is explained and an application to the spin-half {\it XXZ} model on the square lattice is presented. Low orders of…

Strongly Correlated Electrons · Physics 2007-05-23 D. J. J. Farnell , R. F. Bishop

We show that a generalised sparse grid combination technique which combines multi-variate extrapolation of finite difference solutions with the standard combination formula lifts a second order accurate scheme on regular meshes to a fourth…

Numerical Analysis · Mathematics 2026-01-08 Julia Muñoz-Echániz , Christoph Reisinger

Finite mixture modelling is a popular method in the field of clustering and is beneficial largely due to its soft cluster membership probabilities. A common method for fitting finite mixture models is to employ spectral clustering, which…

Machine Learning · Statistics 2024-03-22 Liam Welsh , Phillip Shreeves

We extend Gor'kov theory to address superconducting pairing at high magnetic fields and general temperatures with arbitrary attractive interaction strength. This analysis begins with a new interpretation of the high-field Gor'kov gap…

Superconductivity · Physics 2013-10-25 Peter Scherpelz , Dan Wulin , Břetislav Šopík , K. Levin , A. K. Rajagopal

We extend coupled-cluster theory performed on top of a Slater determinant breaking rotational symmetry to allow for the exact restoration of the angular momentum at any truncation order. The main objective relates to the description of…

Nuclear Theory · Physics 2015-06-22 T. Duguet

The cluster mean-field approximations are performed, up to 13 cluster sizes, to study the critical behavior of the driven pair contact process with diffusion (DPCPD) and its precedent, the PCPD in one dimension. Critical points are…

Statistical Mechanics · Physics 2007-05-23 Su-Chan Park , Hyunggyu Park

Spectral clustering is one of the most popular clustering methods. However, the high computational cost due to the involved eigen-decomposition procedure can immediately hinder its applications in large-scale tasks. In this paper we use…

Machine Learning · Computer Science 2023-01-24 Yongyu Wang

We formulate a patch test consistent atomistic-to-continuum coupling (a/c) scheme that employs a second-order (potentially higher-order) finite element method in the material bulk. We prove a sharp error estimate in the energy-norm, which…

Numerical Analysis · Mathematics 2016-07-21 A. S. Dedner , C. Ortner , H. Wu

A variant of coupled-cluster theory is described here, wherein the degrees of freedom are fluctuations of fragments between internally correlated states. The effects of intra-fragment correlation on the inter-fragment interaction are…

Chemical Physics · Physics 2019-05-24 Yuhong Liu , Anthony D. Dutoi

Multiphysics problems involving two or more coupled physical phenomena are ubiquitous in science and engineering. This work develops a new partitioned exponential approach for the time integration of multiphysics problems. After a possible…

Numerical Analysis · Mathematics 2019-09-09 Mahesh Narayanamurthi , Adrian Sandu

A full coupled-cluster expansion suitable for sparse algebraic operations is developed by expanding the commutators of the Baker-Campbell-Hausdorff series explicitly for cluster operators in binary representations. A full coupled-cluster…

Chemical Physics · Physics 2018-09-13 Enhua Xu , Motoyuki Uejima , Seiichiro L. Ten-no

We formulate a general setting for the cluster expansion method and we discuss sufficient criteria for its convergence. We apply the results to systems of classical and quantum particles with stable interactions.

Mathematical Physics · Physics 2009-05-08 Suren Poghosyan , Daniel Ueltschi

We study the decomposition of the Coulomb integrals of periodic systems into a tensor contraction of six matrices of which only two are distinct. We find that the Coulomb integrals can be well approximated in this form already with small…

Chemical Physics · Physics 2017-04-05 Felix Hummel , Theodoros Tsatsoulis , Andreas Grüneis

We develop a static quantum embedding scheme that utilizes different levels of approximations to coupled cluster (CC) theory for an active fragment region and its environment. To reduce the computational cost, we solve the local fragment…

Chemical Physics · Physics 2024-11-13 Avijit Shee , Fabian M. Faulstich , Birgitta Whaley , Lin Lin , Martin Head-Gordon

The notion of "paired" fermions is central to important condensed matter phenomena such as superconductivity and superfluidity. While the concept is widely used and its physical meaning is clear there exists no systematic and mathematical…

Quantum Physics · Physics 2009-11-13 Christina V. Kraus , Michael M. Wolf , J. Ignacio Cirac , Geza Giedke

We apply the flow equation method for studying the fermion systems where pairing interactions can either trigger the BCS instability with the symmetry breaking manifested by the off-diagonal order parameter or lead to the gaped single…

Superconductivity · Physics 2008-09-26 T. Domanski

In quantum chemistry, one of the most important challenges is the static correlation problem when solving the electronic Schr\"odinger equation for molecules in the Born--Oppenheimer approximation. In this article, we analyze the tailored…

Numerical Analysis · Mathematics 2019-11-21 Fabian M. Faulstich , Andre Laestadius , Örs Legeza , Reinhold Schneider , Simen Kvaal