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We study the efficiency fluctuations of a stochastic heat engine made of $N$ interacting unicyclic machines and undergoing a phase transition in the macroscopic limit. Depending on $N$ and on the observation time, the machine can explore…

Statistical Mechanics · Physics 2020-07-01 Hadrien Vroylandt , Massimiliano Esposito , Gatien Verley

Chemical gradients provide the primordial energy for biological functions by driving the mechanical movement of microscopic engines. Their thermodynamic properties remain elusive, especially concerning the dynamic change in energy demand in…

Statistical Mechanics · Physics 2025-04-01 Ruo-Xun Zhai , Hui Dong

The efficiency at maximum power (EMP) for tight-coupling molecular motors is investigated within the framework of irreversible thermodynamics. It is found that the EMP depends merely on the constitutive relation between the thermodynamic…

Statistical Mechanics · Physics 2013-12-13 Z. C. Tu

We study the efficiency of a simple quantum dot heat engine at maximum power. In contrast to the quasi-statically operated Carnot engine whose efficiency reaches the theoretical maximum, recent research on more realistic engines operated in…

Statistical Mechanics · Physics 2018-12-05 Sang Hoon Lee , Jaegon Um , Hyunggyu Park

Optimisation of heat engines at the micro-scale has applications in biological and artificial nano-technology, and stimulates theoretical research in non-equilibrium statistical physics. Here we consider non-interacting overdamped particles…

Soft Condensed Matter · Physics 2021-06-02 Giulia Gronchi , Andrea Puglisi

We study the maximum efficiency of a Carnot cycle heat engine based on a small system. It is revealed that due to the finiteness of the system, irreversibility may arise when the working substance contacts with a heat bath. As a result,…

Statistical Mechanics · Physics 2014-02-05 H. T. Quan

We discuss the efficiency of a heat engine operating in a nonequilibrium steady state maintained by two heat reservoirs. Within the general framework of linear irreversible thermodynamics we derive a universal upper bound on the efficiency…

Statistical Mechanics · Physics 2016-05-18 Artem Ryabov , Viktor Holubec

Odd materials feature antisymmetric response to perturbations. This anomalous property can stem from the nonequilibrium activity of their components, which is sustained by an external energy supply. These materials open the door to…

Statistical Mechanics · Physics 2022-01-03 Étienne Fodor , Anton Souslov

We consider the efficiency at maximum power of a quantum Otto engine, which uses a spin or a harmonic system as its working substance and works between two heat reservoirs at constant temperatures $T_h$ and $T_c$ $ (<T_h)$. Although the…

Statistical Mechanics · Physics 2015-06-22 Feilong Wu , Jizhou He , Yongli Ma , Jianhui Wang

The maximum efficiency of autonomous engines with finite chemical potential difference is investigated. We show that without a particular type of singularity autonomous engines cannot attain the Carnot efficiency. In addition, we…

Statistical Mechanics · Physics 2015-12-03 Naoto Shiraishi

We study how to achieve the ultimate power in the simplest, yet non trivial, model of a thermal machine, namely a two-level quantum system coupled to two thermal baths. Without making any prior assumption on the protocol, via optimal…

Quantum Physics · Physics 2019-11-07 Paolo Andrea Erdman , Vasco Cavina , Rosario Fazio , Fabio Taddei , Vittorio Giovannetti

Classical thermodynamics aimed to quantify the efficiency of thermodynamic engines by bounding the maximal amount of mechanical energy produced compared to the amount of heat required. While this was accomplished early on, by Carnot and…

Optimization and Control · Mathematics 2020-01-22 Rui Fu , Amirhossein Taghvaei , Yongxin Chen , Tryphon T. Georgiou

Nanoscale machines are strongly influenced by thermal fluctuations, contrary to their macroscopic counterparts. As a consequence, even the efficiency of such microscopic machines becomes a fluctuating random variable. Using geometric…

Statistical Mechanics · Physics 2019-04-16 Sreekanth K Manikandan , Lennart Dabelow , Ralf Eichhorn , Supriya Krishnamurthy

There are two paradigms to study nanoscale engines in stochastic and quantum thermodynamics. Autonomous models, which do not rely on any external time-dependence, and models that make use of time-dependent control fields, often combined…

Quantum Physics · Physics 2021-05-10 Philipp Strasberg , Christopher W. Wächtler , Gernot Schaller

In this paper, we derive a number of inequalities which express power-efficiency trade-offs that hold generally for thermodynamic machines operating in non-equilibrium stationary states. One of these inequalities concerns the output power,…

Statistical Mechanics · Physics 2019-09-04 Hadrien Vroylandt , David Lacoste , Gatien Verley

Biomolecular machines transduce between different forms of energy. These machines make directed progress and increase their speed by consuming free energy, typically in the form of nonequilibrium chemical concentrations. Machine dynamics…

Statistical Mechanics · Physics 2018-10-05 Aidan I Brown , David A Sivak

It is known that an engine with ideal efficiency ($\eta =1$ for a chemical engine and $e = e_{\rm Carnot}$ for a thermal one) has zero power because a reversible cycle takes an infinite time. However, at least from a theoretical point of…

Chemical Physics · Physics 2016-11-22 Jesper Koning , Joseph O. Indekeu

The widely debated feasibility of thermodynamic machines achieving Carnot efficiency at finite power has been convincingly dismissed. Yet, the common wisdom that efficiency can only be optimal in the limit of infinitely-slow processes…

Statistical Mechanics · Physics 2017-07-28 Matteo Polettini , Massimiliano Esposito

We study the optimal exergy efficiency and power for thermodynamic systems with Onsager-type "current-force" relationship describing the linear-response to external influences. We derive, in simple analytic forms, the maximum efficiency and…

Statistical Mechanics · Physics 2015-03-17 Jian-Hua Jiang

Active matter constantly dissipates energy to power the self-propulsion of its microscopic constituents. This opens the door to designing innovative cyclic engines without any equilibrium equivalent. We offer a consistent thermodynamic…

Soft Condensed Matter · Physics 2020-07-08 Timothy Ekeh , Michael E. Cates , Étienne Fodor