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We present calculations for the action of laser pulses on vibrational transfer within the H2+ and Na2 molecules in the presence of dissipation due to photodissociation of the molecule. The laser fields perform closed loops surrounding…

Quantum Physics · Physics 2013-06-28 Arnaud Leclerc , Georges Jolicard , John P. Killingbeck

In molecular photodissociation, some specific combinations of laser parameters (wavelength and intensity) lead to unexpected Zero-Width Resonances (ZWR), with in principle infinite lifetimes. Their interest in inducing basic quenching…

Quantum Physics · Physics 2016-10-19 Arnaud Leclerc , David Viennot , Georges Jolicard , Roland Lefebvre , Osman Atabek

Understanding and controlling the electronic as well as ro-vibrational motion and, thus, the entire chemical dynamics in molecules is the ultimate goal of ultrafast laser and imaging science. In photochemistry, laser-induced dissociation…

Laser cooling of molecules employing broadband optical pumping involves a timescale separation between laser excitation and spontaneous emission. Here, we optimize the optical pumping step using shaped laser pulses. We derive two…

Quantum Physics · Physics 2013-12-24 Daniel M. Reich , Christiane P. Koch

Molecular ions can be held in a chain of laser-cooled atomic ions by sympathetic cooling. This system is ideal for performing high-precision molecular spectroscopy with applications in astrochemistry and fundamental physics. Here we show…

Atomic Physics · Physics 2015-08-20 Ncamiso B. Khanyile , Gang Shu , Kenneth R. Brown

The laser control of photodissociation branching in a diatomic molecule is demonstrated to be effectively achieved with use of the complete reflection phenomenon. The phenomenon and the control condition can be nicely formulated by the…

Quantum Physics · Physics 2007-05-23 Hiroshi Fujisaki , Yoshiaki Teranishi , Hiroki Nakamura

We investigate the possibility of optical current control through single molecules which are weakly coupled to leads. A master equation approach for the transport through a molecule is combined with a Floquet theory for the time-dependent…

Chemical Physics · Physics 2016-09-08 Jörg Lehmann , Sébastien Camalet , Sigmund Kohler , Peter Hänggi

We report on a theoretical study of a Cs$_2$ molecule illuminated by two lasers and show how it can result in novel quantum dynamics. We reveal that these interactions facilitate the bypass of the non-crossing rule, forming Light-Induced…

Chemical Physics · Physics 2024-05-21 Edgar Barriga , Luis E. F. Foa Torres , Carlos Cárdenas

We propose and demonstrate a novel laser cooling mechanism applicable to particles with narrow-linewidth optical transitions. By sweeping the frequency of counter-propagating laser beams in a sawtooth manner, we cause adiabatic transfer…

We demonstrate that a near-dissociation photoassociation resonance can be used to create a deeply bound molecular sample of ultracold NaCs. To probe the resulting vibrational distribution of the sample, we use a new technique that can be…

Motivated by recent pump-probe spectroscopies, we study the effect of phonon dissipation and potential cooling on the nonequilibrium distribution function in a Floquet topological state. To this end, we apply a Floquet kinetic equation…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Hossein Dehghani , Takashi Oka , Aditi Mitra

We present a magnetically enhanced laser cooling scheme applicable to multi-level type-II transitions and further diatomic molecules with adiabatic transfer. An angled magnetic field is introduced to not only remix the dark states, but also…

Atomic Physics · Physics 2019-05-07 Qian Liang , Tao Chen , Wenhao Bu , Yuhe Zhang , Bo Yan

We have recently demonstrated that optical pumping methods combined with photoassociation of ultra-cold atoms can produce ultra-cold and dense samples of molecules in their absolute rovibronic ground state. More generally, both the external…

Atomic Physics · Physics 2013-08-01 I. Manai , R. Horchani , M. Hamamda , A. Fioretti , M. Allegrini , H. Lignier , P. Pillet , D. Comparat

Molecules have vibrational, rotational, spin-orbit and hyperfine degrees of freedom or quantum states, each of which responds in a unique fashion to external electromagnetic radiation. The control over superpositions of these quantum states…

Quantum Physics · Physics 2024-04-29 Svetlana Kotochigova , Qingze Guan , Eite Tiesinga , Vito Scarola , Brian DeMarco , Bryce Gadway

For experiments that require a quantum system to be in the ultra-cold regime, laser cooling is an essential tool. While techniques for laser cooling ions and neutral atoms have been refined and temperatures below the Doppler limit have been…

Atomic Physics · Physics 2024-10-31 Caleb Heuvel-Horwitz , S. F. Yelin

We study how fermions in molybdenum disulfide MoS$_2$ interact with a laser field and a static potential barrier, focusing on the transmission probability. Our aim is to understand and control photon-assisted quantum transport in this…

Mesoscale and Nanoscale Physics · Physics 2026-01-09 Rachid El Aitouni , Aotmane En Naciri , Clarence Cortes , David Laroze , Ahmed Jellal

We evaluate the shifts imparted to vibrational and rotational levels of a linear molecule by a nonresonant laser field at intensities of up to 10^12 W/cm^2. Both types of shift are found to be either positive or negative, depending on the…

Chemical Physics · Physics 2015-03-14 Mikhail Lemeshko , Bretislav Friedrich

We theoretically investigate the laser wavelength dependence of asymmetric dissociation of H$_2^+$. It is found that the electron localization in molecular dissociation is significantly manipulated by varying the wavelength of the driving…

Atomic and Molecular Clusters · Physics 2015-06-03 Kunlong Liu , Weiyi Hong , Qingbin Zhang , Peixiang Lu

Ultrafast manipulation of vibrational coherence is an emergent route to control the structure of solids. However, this strategy can only induce long-range correlations and cannot modify atomic structure locally, which is required in many…

Chemical reactions typically proceed via stochastic encounters between reactants. Going beyond this paradigm, we combine exactly two atoms into a single, controlled reaction. The experimental apparatus traps two individual laser-cooled…

Atomic Physics · Physics 2018-04-25 L. R. Liu , J. D. Hood , Y. Yu , J. T. Zhang , N. R. Hutzler , T. Rosenband , K. -K. Ni
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