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We review recent advances in the theoretical, numerical, and experimental studies of critical Casimir forces in soft matter, with particular emphasis on their relevance for the structures of colloidal suspensions and on their dynamics.…

Soft Condensed Matter · Physics 2023-12-27 Andrea Gambassi , S. Dietrich

We study theoretically and experimentally the solvent-mediated critical Casimir force acting on colloidal particles immersed in a binary liquid mixture of water and 2,6-lutidine and close to substrates which are chemically patterned with…

If a fluctuating medium is confined, the ensuing perturbation of its fluctuation spectrum generates Casimir-like effective forces acting on its confining surfaces. Near a continuous phase transition of such a medium the corresponding order…

Soft Condensed Matter · Physics 2011-02-15 A. Gambassi , A. Maciolek , C. Hertlein , U. Nellen , L. Helden , C. Bechinger , S. Dietrich

If colloidal solute particles are suspended in a solvent close to its critical point, they act as cavities in a fluctuating medium and thereby restrict and modify the fluctuation spectrum in a way which depends on their relative…

Soft Condensed Matter · Physics 2018-11-14 Anna Maciolek , Siegfried Dietrich

We investigate the behavior of colloidal particles immersed in a binary liquid mixture of water and 2,6-lutidine in the presence of a chemically patterned substrate. Close to the critical point of the mixture, the particles are subjected to…

Soft Condensed Matter · Physics 2009-11-13 F. Soyka , O. Zvyagolskaya , C. Hertlein , L. Helden , C. Bechinger

Colloids immersed in a critical or near-critical binary liquid mixture and close to a chemically patterned substrate are subject to normal and lateral critical Casimir forces of dominating strength. For a single colloid we calculate these…

Soft Condensed Matter · Physics 2010-08-18 M. Tröndle , S. Kondrat , A. Gambassi , L. Harnau , S. Dietrich

We study the normal and lateral effective critical Casimir forces acting on a spherical colloid immersed in a critical binary solvent and close to a chemically structured substrate with alternating adsorption preference. We calculate the…

Soft Condensed Matter · Physics 2009-12-17 M. Tröndle , S. Kondrat , A. Gambassi , L. Harnau , S. Dietrich

Critical Casimir forces emerge among particles or surfaces immersed in a near-critical fluid, with the sign of the force determined by surface properties and with its strength tunable by minute temperature changes. Here, we show how such…

Soft Condensed Matter · Physics 2024-09-16 Piotr Nowakowski , Nima Farahmand Bafi , Giovanni Volpe , Svyatoslav Kondrat , S. Dietrich

In soft and condensed matter physics, effective interactions often emerge as a result of the spatial confinement of a fluctuating field. For instance, microscopic particles in a binary liquid mixture are subject to critical Casimir forces…

The Casimir effect in quantum electrodynamics (QED) is perhaps the best-known example of fluctuation-induced long-ranged force acting on objects (conducting plates) immersed in a fluctuating medium (quantum electromagnetic field in vacuum).…

Statistical Mechanics · Physics 2009-07-13 Andrea Gambassi

Critical Casimir forces can play an important role for applications in nano-science and nanotechnology, owing to their piconewton strength, nanometric action range, fine tunability as a function of temperature, and exquisite dependence on…

Mesoscopic particles immersed in a critical fluid experience long-range Casimir forces due to critical fluctuations. Using field theoretical methods, we investigate the Casimir interaction between two spherical particles and between a…

Condensed Matter · Physics 2009-10-28 E. Eisenriegler , U. Ritschel

Spatial confinement of a near-critical medium changes its fluctuation spectrum and modifies the corresponding order parameter distribution. These effects result in effective, so-called critical Casimir forces (CCFs) acting on the confining…

Soft Condensed Matter · Physics 2014-03-24 T. F. Mohry , S. Kondrat , A. Maciolek , S. Dietrich

Percolation and critical phenomena show common features such as scaling and universality. Colloidal particles, immersed in a solvent close to criticality, experience long-range effective forces, named critical Casimir forces. %These…

Soft Condensed Matter · Physics 2014-07-16 Nicoletta Gnan , Emanuela Zaccarelli , Francesco Sciortino

The critical Casimir effect provides a thermodynamic analogue of the well-known quantum mechanical Casimir effect. It acts between two surfaces immersed in a critical binary liquid mixture, and results from the confinement of concentration…

Soft Condensed Matter · Physics 2015-06-15 Van Duc Nguyen , Suzanne Faber , Zhibing Hu , Gerard H. Wegdam , Peter Schall

In any medium there are fluctuations due to temperature or due to the quantum nature of its constituents. If a material body is immersed into such a medium, its shape and the properties of its constituents modify the properties of the…

Statistical Mechanics · Physics 2022-12-27 D. M. Dantchev , S. Dietrich

The manipulation of microscopic objects requires precise and controllable forces and torques. Recent advances have led to the use of critical Casimir forces as a powerful tool, which can be finely tuned through the temperature of the…

We consider an ensemble of spherical colloidal particles immersed in a near-critical solvent such as a binary liquid mixture close to its critical demixing point. The emerging long-ranged fluctuations of the corresponding order parameter of…

Soft Condensed Matter · Physics 2015-06-03 T. F. Mohry , A. Maciołek , S. Dietrich

In confined systems near a continuous phase transition the long-ranged fluctuations of the corresponding order parameter are subject to boundary conditions. These constraints result in so-called critical Casimir forces acting as effective…

Statistical Mechanics · Physics 2015-05-18 T. F. Mohry , A. Maciołek , S. Dietrich

Colloids immersed in a critical binary liquid mixture are subject to critical Casimir forces (CCFs) because they confine its concentration fluctuations and influence the latter via effective surface fields. To date, CCFs have only been…

Soft Condensed Matter · Physics 2013-09-04 Akira Furukawa , Andrea Gambassi , Siegfried Dietrich , Hajime Tanaka
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