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Related papers: A variationally computed line list for hot NH3

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A new hot line list for $^{14}$NH$_3$ is presented. The line list CoYuTe was constructed using an accurate, empirically refined potential energy surface and a CCSD(T)/aug-cc-pVQZ ab initio dipole moment surface of ammonia, previously…

Solar and Stellar Astrophysics · Physics 2019-11-26 Phillip A. Coles , Sergei N. Yurchenko , Jonathan Tennyson

An accurate and comprehensive room temperature rotation-vibration transition line list for phosphine (31PH3) is computed using a newly refined potential energy surface and a previously constructed ab initio electric dipole moment surface.…

Earth and Planetary Astrophysics · Physics 2013-05-17 Clara Sousa-Silva , Sergei N. Yurchenko , Jonathan Tennyson

A new room temperature line list for $^{15}$NH$_3$ is presented. This line list comprised of transition frequencies and Einstein coefficients has been generated using the `spectroscopic' potential energy surface NH3-Y2010 and an ab initio…

Earth and Planetary Astrophysics · Physics 2015-03-02 Sergei N. Yurchenko

{\it Ab initio} potential energy and dipole moment surfaces are computed for sulfur trioxide (SO$_3$) at the CCSD(T)-F12b level of theory and appropriate triple-zeta basis sets. These surfaces are fitted and used, with a slight correction…

Earth and Planetary Astrophysics · Physics 2017-09-13 Daniel S. Underwood , Jonathan Tennyson , Sergei N. Yurchenko

A computed line list for formaldehyde, H$_2{}^{12}$C$^{16}$O, applicable to temperatures up to $T=1500$~K is presented. An empirical potential energy and {\it ab initio} dipole moment surfaces are used as the input to nuclear motion program…

Astrophysics of Galaxies · Physics 2015-06-02 Ahmed F. Al-Refaie , Andrey Yachmenev , Jonathan Tennyson , Sergei N. Yurchenko

We present line lists for ammonia (NH$_{3}$) at high temperatures obtained by recording Fourier transform infrared emission spectra. Calibrated line lists are presented for twelve temperatures (300 -- 1300$^{\circ}$C in 100$^{\circ}$C…

Instrumentation and Methods for Astrophysics · Physics 2015-05-28 R. J. Hargreaves , G. Li , P. F. Bernath

We present the first variational calculation of a hot temperature ab initio line list for the CH$_3$ radical. It is based on a high level ab initio potential energy surface and dipole moment surface of CH$_3$ in the ground electronic state.…

Chemical Physics · Physics 2019-05-15 Ahmad Y. Adam , Andrey Yachmenev , Sergei N. Yurchenko , Per Jensen

A new hot line list is calculated for $^{12}$CH$_4$ in its ground electronic state. This line list, called 10to10, contains 9.8 billion transitions and should be complete for temperatures up to 1500 K. It covers the wavelengths longer than…

Earth and Planetary Astrophysics · Physics 2014-06-27 Sergei N. Yurchenko , Jonathan Tennyson

A comprehensive, hyperfine-resolved rotation-vibration line list for the ammonia molecule ($^{14}$NH$_3$) is presented. The line list, which considers hyperfine nuclear quadrupole coupling effects, has been computed using robust, first…

Chemical Physics · Physics 2019-01-16 Phillip A. Coles , Alec Owens , Jochen Küpper , Andrey Yachmenev

A computed line list for hydrogen peroxide, H$_2{}^{16}$O$_2$, applicable to temperatures up to $T=1250$~K is presented. A semi-empirical high accuracy potential energy surface is constructed and used with an {\it ab initio} dipole moment…

Earth and Planetary Astrophysics · Physics 2016-07-05 Ahmed F. Al-Refaie , Oleg L. Polyansky , Roman I. Ovsyannikov , Jonathan Tennyson , Sergei N. Yurchenko

A theoretical line list for $^{15}$NH$_3$ CoYuTe-15 is presented based on the empirical potential energy and ab initio dipole moments surfaces developed and used for the production of the ExoMol line list CoYuTe for $^{14}$NH$_3$. The…

A Fourier Transform (FT) absorption spectrum of room temperature NH3 in the region 7400 - 8600 cm-1 is analysed using a variational line list and ground state energies determined using the MARVEL procedure. The spectrum was measured by Dr…

Chemical Physics · Physics 2016-07-05 Emma J. Barton , Sergei. N. Yurchenko , Jonathan Tennyson , S. Béguier , A. Campargue

A comprehensive, calculated line list of frequencies and transition probabilities for the singly deuterated isotopologue of H3+, H2D+, is presented. The line list, called ST1, contains over 22 million rotational-vibrational transitions…

Computational Physics · Physics 2010-05-11 Taha Sochi , Jonathan Tennyson

Nitric acid is a possible biomarker in the atmospheres of exoplanets. An accurate line list of rotational and rotational-vibrational transitions is computed for nitric acid (HNO$_3$). This line list covers wavelengths longer than 1.42…

Earth and Planetary Astrophysics · Physics 2015-08-06 Anatoly I. Pavlyuchko , Sergei N. Yurchenko , Jonathan Tennyson

This work presents the AYT2 line list: a comprehensive list of 114 million $^{1}$H$_2$$^{32}$S vibration-rotation transitions computed using an empirically-adjusted potential energy surface and an {\it ab initio} dipole moment surface. The…

Earth and Planetary Astrophysics · Physics 2016-07-05 Ala'a A. A. Azzam , Jonathan Tennyson , Sergei N. Yurchenko , Olga V. Naumenko

Accurate rotational-vibrational line lists for $^{31}$P$^{14}$N and $^{31}$P$^{15}$N in their ground electronic states are computed. The line lists are produced using an empirical potential energy curve obtained by fitting to the…

Astrophysics of Galaxies · Physics 2015-04-14 Leo Yorke , Sergei N. Yurchenko , Lorenzo Lodi , Jonathan Tennyson

A comprehensive hot line list is calculated for $^{31}$PH$_3$ in its ground electronic state. This line list, called SAlTY, contains almost 16.8 billion transitions between 7.5 million energy levels and it is suitable for simulating spectra…

Earth and Planetary Astrophysics · Physics 2015-04-13 Clara Sousa-Silva , Ahmed F. Al-Refaie , Jonathan Tennyson , Sergei N. Yurchenko

A new ro-vibrational line list for the ground electronic state of the main isotopologue of acetylene, $^{12}$C$_2$H$_2$, is computed as part of the ExoMol project. The aCeTY line list covers the transition wavenumbers up to 10,000 cm$^{-1}$…

Solar and Stellar Astrophysics · Physics 2020-02-05 Katy L. Chubb , Jonathan Tennyson , Sergey N. Yurchenko

A new hot line list for the main isotopologue of CO$_2$ is presented. The line list consists of almost 2.5 billion transitions between 3.5 million rotation-vibration states of CO$_2$ in its ground electronic state, covering the wavenumber…

Earth and Planetary Astrophysics · Physics 2020-07-10 S. N. Yurchenko , Thomas M. Mellor , Richard S. Freedman , J. Tennyson

A variationally computed $^{28}$SiH$_4$ rotation-vibration line list applicable for temperatures up to $T=1200\,$K is presented. The line list, called OY2T, considers transitions with rotational excitation up to $J=42$ in the wavenumber…

Chemical Physics · Physics 2017-12-29 A. Owens , A. Yachmenev , W. Thiel , J. Tennyson , S. N. Yurchenko
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