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An overview is given of the chemical processes that occur in primordial systems under the influence of radiation, metal abundances and dust surface reactions. It is found that radiative feedback effects differ for UV and X-ray photons at…

Astrophysics · Physics 2009-11-13 M. Spaans

Nitrogen-bearing molecules display variable isotopic fractionation levels in different astronomical environments such as in the interstellar medium or in the Solar System. Models of interstellar chemistry are unable to induce nitrogen…

Astrophysics of Galaxies · Physics 2020-12-15 Jean-Christophe Loison , Valentine Wakelam , Pierre Gratier , Kevin M. Hickson

Nuclear reactions govern major aspects of the chemical evolution od galaxies and stars. Analytic study of the reaction rates and reaction probability integrals is attempted here. Exact expressions for the reaction rates and reaction…

Astrophysics · Physics 2011-04-15 H. J. Haubold , A. M. Mathai

Context. Multi-wavelength studies of galaxies and galactic nuclei allow us to build a relatively more complete picture of the interstellar medium (ISM), especially in the dusty regions of starburst galaxies. An understanding of the physical…

We study the formation of water and methanol in the dense cloud conditions to find the dependence of its production rate on the binding energies, reaction mechanisms, temperatures, and grain site number. We wish to find the effective grain…

Astrophysics · Physics 2009-11-13 Ankan Das , Kinsuk Acharyya , Sonali Chakrabarti , Sandip Kumar Chakrabarti

CS is among the most abundant gas-phase S-bearing molecules in cold dark molecular clouds. It is easily observable with several transitions in the millimeter wavelength range, and has been widely used as a tracer of the gas density in the…

Context: Dust grains undergo significant growth in star-forming environments, especially in dense regions prone to gravitational collapse. Although dust is generally assumed to represent $1 \%$ of the gas mass, dust density variations are…

Astrophysics of Galaxies · Physics 2026-01-14 V. Vallucci-Goy , P. Hennebelle , U. Lebreuilly , G. Verrier

Context. Interstellar surface chemistry is a complex process that occurs in icy layers accumulated onto grains of different sizes. Efficiency of surface processes often depends on the immediate environment of adsorbed molecules. Aims. We…

Astrophysics of Galaxies · Physics 2024-07-31 Juris Kalvāns , Aija Kalniņa , Kristaps Veitners

We investigate the role of carbon monoxide ice in the chemical evolution of prestellar cores using astrochemical rate equation models. We constrain the ratios of the binding energies on CO ice and H$_{2}$O ice for a series of adsorbates…

Astrophysics of Galaxies · Physics 2024-08-14 Germán Molpeceres , Kenji Furuya , Yuri Aikawa

Dust grains play a central role in the physics and chemistry of cosmic environments. They influence the optical and thermal properties of the medium due to their interaction with stellar radiation; provide surfaces for the chemical…

Astrophysics of Galaxies · Physics 2021-05-05 Alexey Potapov , Martin McCoustra

We investigate the molecular evolution and D/H abundance ratios that develop as star formation proceeds from a dense-cloud core to a protostellar core, by solving a gas-grain reaction network applied to a 1-D radiative hydrodynamic model…

Astrophysics of Galaxies · Physics 2015-06-11 Yuri Aikawa , Valentine Wakelam , Franck Hersant , Robin T. Garrod , Eric Herbst

With the well-established correlation between the relative stabilities of isomers and their interstellar abundances coupled with the prevalence of isomeric species among the interstellar molecular species, isomerization remains a plausible…

Astrophysics of Galaxies · Physics 2023-02-14 Emmanuel E. Etim

Carbon containing molecules in cold molecular clouds show various levels of isotopic fractionation through multiple observations. To understand such effects, we have developed a new gas-grain chemical model with updated 13C fractionation…

Astrophysics of Galaxies · Physics 2020-10-07 Jean-Christophe Loison , Valentine Wakelam , Pierre Gratier , Kevin M. Hickson

A model of key processes influencing the evolution of a hydrocarbon grain of an arbitrary size under astrophysical conditions corresponding to ionized hydrogen regions (HII regions) and supernova remnants is presented. The considered…

Astrophysics of Galaxies · Physics 2016-12-07 M. S. Murga , S. A. Khoperskov , D. S. Wiebe

$Aims$: We revisit with new augmented accuracy the theoretical dynamics of basic isotope exchange reactions involved in the $^{12}$C/$^{13}$C, $^{16}$O/$^{18}$O, and $^{14}$N/$^{15}$N balance because these reactions have already been…

Astrophysics of Galaxies · Physics 2015-06-19 Mirjana Mladenović , Evelyne Roueff

We investigate chemistry in the compression layer behind the interstellar shock waves, where molecular cloud formation starts. We perform three-dimensional magnetohydrodynamics simulations of converging flows of atomic gas with shock…

Astrophysics of Galaxies · Physics 2024-11-20 Yuto Komichi , Yuri Aikawa , Kazunari Iwasaki , Kenji Furuya

Using the Planck far-infrared and Arecibo GALFA 21-cm line surveys, we identified a set of isolated interstellar clouds (approximately degree-sized on the sky and comprising 100 solar masses) and assessed the ratio of gas mass to dust mass.…

Astrophysics of Galaxies · Physics 2015-10-07 William T. Reach , Carl Heiles , Jean-Philippe Bernard

We present ROBO, a model and its companion code for the study of the interstellar medium (ISM). The aim is to provide an accurate description of the physical evolution of the ISM and to set the ground for an ancillary tool to be inserted in…

Astrophysics of Galaxies · Physics 2011-07-20 T. Grassi , P. Krstic , E. Merlin , U. Buonomo , L. Piovan , C. Chiosi

Recent results on nearby interstellar gas and interstellar byproducts within the solar system are used to select among the equilibrium radiative transfer models of the nearest interstellar material of Slavin and Frisch (2002). Assuming…

Astrophysics · Physics 2009-11-10 Priscilla C. Frisch Jonathan D. Slavin

We study the effects of grain surface reactions on the chemistry of protoplanetary disks where gas, ice surface layers and icy mantles of dust grains are considered as three distinct phases. Gas phase and grain surface chemistry is found to…

Astrophysics of Galaxies · Physics 2020-01-08 Maxime Ruaud , Uma Gorti