Related papers: Reaction Networks For Interstellar Chemical Modell…
We review the reactions between carbon chain molecules and radicals, namely Cn, CnH, CnH2, C2n+1O, CnN, HC2n+1N, with C, N and O atoms. Rate constants and branching ratios for these processes have been re-evaluated using experimental and…
Chemical reaction networks are central to all chemical models. Each rate coefficient has an associated uncertainty, which is generally not taken into account when calculating the chemistry. We performed the first uncertainty analysis of a…
We introduced a semi-analytic model to study the detail of radial related processes on galaxy disks. Based on this recipe, we can calculate neutral and molecular gas in interstellar medium, and include the molecular phase into star…
The degree of porosity in interstellar dust-grain material is poorly defined, although recent work has suggested that the grains could be highly porous. Aside from influencing the optical properties of the dust, porosity has the potential…
Context. Cosmic ray particles that hit interstellar grains in dark molecular cores may induce whole-grain heating. The high temperature of a CR-heated grain allows energy barriers for bulk diffusion and reactions to be overcome.…
The abundances of gas and dust (solids and complex molecules) in the interstellar medium (ISM) as well as their composition and structures impact practically all of astrophysics. Fundamental processes from star formation to stellar winds to…
Aims. We define a small and large chemical network which can be used for the quantitative simultaneous analysis of molecular emission from the near-IR to the submm. We revise reactions of excited molecular hydrogen, which are not included…
Processing by interstellar photons affects the composition of the icy mantles on interstellar grains. The rate of photodissociation in solids differs from that of molecules in the gas phase. The aim of this work was to determine an average,…
With the high-resolution spectroscopy now available in the optical and satellite UV, it is possible to determine the neutral/ionized column density ratios for several different elements in a single cloud. Assuming ionization equilibrium for…
Computational models of interstellar gas-grain chemistry have historically adopted a single dust-grain size of 0.1 micron, assumed to be representative of the size distribution present in the interstellar medium. Here, we investigate the…
Following the first pioneering efforts in the 1990s that have focused on the detection of the molecular interstellar medium in high redshift galaxies, recent years have brought great advances in our understanding of the actual physical…
Advanced telescopes, such as ALMA and JWST, are likely to show that the chemical universe may be even more complex than currently observed, requiring astrochemical modelers to improve their models to account for the impact of new data.…
In this work we investigate the effects of ion accretion and size-dependent dust temperatures on the abundances of both gas-phase and grain-surface species. While past work has assumed a constant areal density for icy species, we show that…
The atomic-to-molecular gas conversion is a critical step in the baryon cycle of galaxies, which sets the initial conditions for subsequent star formation and influences the multi-phase interstellar medium. We compiled a sample of 94 nearby…
Unlike gas-phase reactions, chemical reactions taking place on interstellar dust grain surfaces cannot always be modeled by rate equations. Due to the small grain sizes and low flux,these reactions may exhibit large fluctuations and thus…
In this paper, we present preliminary results illustrating the effect of cosmic rays on solid-phase chemistry in models of both TMC-1 and several sources with physical conditions identical to TMC-1 except for hypothetically enhanced…
We study conditions under which carbon clusters of different sizes form and stabilize. {We describe an approach to equilibrium by simulating tenuous carbon gas dynamics to long times.} First, we use reactive molecular dynamics simulations…
Among the silicon bearing species discovered in the interstellar medium, SiS and SiO stand out as key tracers due to their distinct chemistry and abundances in interstellar and circumstellar environments. Our objective is to enhance the…
Explosive nuclear burning in astrophysical environments produces unstable nuclei which again can be targets for subsequent reactions. In addition, it involves a large number of stable nuclides which are not fully explored by experiments,…
We present and test chemical models for three-dimensional hydrodynamical simulations of galaxies. We explore the effect of changing key parameters such as metallicity, radiation and non-equilibrium versus equilibrium metal cooling…