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Percolation of gold films of ~15 nm thickness was controlled to achieve the largest openings during Au deposition. Gold was evaporated on 300-nm-thick films of nanostructured porous and columnar SiO2, TiO2 and MgF2 which were deposited by…

A plasmonic nanostructure-based substrate, serving as a surface-enhanced Raman scattering (SERS) substrate, enhances the Raman scattering of molecules. By employing an electron beam lithography followed by our recently developed…

We demonstrate gold coated polymer surface enhanced Raman scattering (SERS) substrates with a pair of complementary structures--positive and inverted pyramids array structures fabricated by multiple-step molding and replication process. The…

Optics · Physics 2014-02-10 Zhida Xu , Logan Liu

A periodic arrangement of chains of gold discs shows pronounced plasmonic grating resonances. These have a clear impact on the Surface Enhanced Raman Scattering (SERS)-signal from 4-methylbenzenethiol molecules which form self-assembled…

The long-range action of surface-enhanced Raman scattering (SERS) is probed via distance-dependent measurements of molecular Raman spectra. To this end, identical SERS substrates composed of irregular silver nanoisland arrays were covered…

Materials Science · Physics 2015-06-12 V. I. Kukushkin , A. B. Van'kov , I. V. Kukushkin

Graphene devices require electric contacts with metals, particularly with gold. Scanning tunneling spectroscopy studies of electron local density of states performed on mono-, bi- and tri- graphene layer deposited on metallic conductive…

Materials Science · Physics 2009-01-05 Z. Klusek , P. Dabrowski , P. Kowalczyk , W. Kozlowski , P. Blake , M. Szybowicz , T. Runka , W. Olejniczak

This research describes the use of surface-enhanced Raman spectroscopy (SERS) substrates based on colloidal silver nanoparticles (AgNPs) produced by laser ablation of silver granules in pure water that are inexpensive, easy to make, and…

Optics · Physics 2023-04-26 A. M. Ondieki , Z. Birech , K. A. Kaduki , P. W. Mwangi

The low efficiency of Raman spectroscopy can be overcome by placing the active molecules in the vicinity of scatterers, typically rough surfaces or nanostructures with various shapes. This surface-enhanced Raman scattering (SERS) leads to…

Surface enhanced Raman scattering (SERS) effects on tin dioxide in the form of bulk material, nanostructured thin films and colloidal solutions were investigated. Raman spectra are characterized by the three Raman scattering peaks at 478,…

Materials Science · Physics 2015-06-03 Enza Fazio , Fortunato Neri , Salvatore Savasta , Salvatore Spadaro , Sebastiano Trusso

We synthesized three-dimensional nanoporous graphene films by a chemical vapor deposition method with nanoporous copper as a catalytic substrate. The resulting nanoporous graphene has the same average pore size as the underlying copper…

Materials Science · Physics 2015-04-20 Zhiqiang Tu , Shangfei Wu , Fan Yang , Yongfeng Li , Liqiang Zhang , Hongwen Liu , Hong Ding , Pierre Richard

A hybrid structure of a graphene nanomesh with the gold nanodisks is studied to enhance the light absorption by localized surface plasmon resonance. From the reflection spectra of the visible range for graphene nanomesh samples without and…

Materials Science · Physics 2017-02-02 Yang Wu , Jing Niu , Mohammad Danesh , Jingbo Liu , Yuanfu Chen , Lin Ke , Chengwei Qiu , Hyunsoo Yang

The combination of graphene with noble-metal nanostructures is currently being explored for strong light-graphene interaction enhanced by plasmons. We introduce a novel hybrid graphene-metal system for studying light-matter interactions…

Mesoscale and Nanoscale Physics · Physics 2013-10-10 Xiaolong Zhu , Lei Shi , Michael S. Schmidt , Anja Boisen , Ole Hansen , Jian Zi , Sanshui Xiao , N. Asger Mortensen

Trisoctahedral (TOH) shaped Au nanocrystals (NCs) have emerged as a new class of metal nanoparticles (MNP) due to its superior catalystic and SERS activities caused by the presence of high density atomic steps and dangling bonds on their…

Materials Science · Physics 2017-05-15 Achyut Maity , Arpan Maiti , Biswarup Satpati , Avinash Patsha , Sandip Dhara , Tapas Kumar Chini

Graphene on noble-metal nanostructures constitutes an attractive nanocomposite with possible applications in sensors or energy conversion. In this work we study the properties of hybrid graphene/gold nanoparticle structures by Raman…

Mesoscale and Nanoscale Physics · Physics 2018-06-14 András Pálinkás , Péter Kun , Antal A. Koós , Zoltán Osváth

Silver (Ag) is considered an ideal material for plasmonic applications in the visible wavelength regime due to its superior optical properties, but its use is limited by the poor chemical stability and structural quality of thermally…

Raman spectroscopic studies of graphene have attracted much interest. The G-band Raman intensity of a single layer graphene on Si substrate with 300 nm SiO2 capping layer is surprisingly strong and is comparable to that of bulk graphite. To…

Materials Science · Physics 2009-11-13 Yingying Wang , Zhenhua Ni , Zexiang Shen , Haomin Wang , Yihong Wu

The paper presents briefly some general points of the theory of Surface Enhanced Raman Scattering on metals, semiconductors, dielectrics and graphene. It is pointed out that the reason of SERS on graphene and some other 2D materials is not…

Optics · Physics 2017-01-17 V. P. Chelibanov , S. A. Ktitorov , A. M. Polubotko , Yu. A. Firsov

Surface-enhanced Raman spectroscopy is a powerful and versatile sensing method with a detection limit down to the single molecule level. In this article, we demonstrate how topology optimization (TopOpt) can be used for designing surface…

Mesoscale and Nanoscale Physics · Physics 2021-08-25 Ying Pan , Rasmus E. Christiansen , Jerome Michon , Juejun Hu , Steven G. Johnson

We report the excitation of a surface plasmon resonance (SPR) close to the orthogonal axis of a gold (Au) film on borosilicate glass. Direct spectroscopic measurement of SPR shifts using different liquids are made at ~5{\deg} incidence…

Enhanced diffusion of gold atoms into silicon substrate has been studied in Au thin films of various thicknesses (2.0, 5.3, 10.9 and 27.5 nm) deposited on Si(111) and followed by irradiation with 1.5 MeV Au2+ at a flux of 6.3x10^12 ions…

Materials Science · Physics 2009-11-13 J. Ghatak , B. Sundaravel , K. G. M. Nair , P. V. Satyam