Related papers: The chemistry of interstellar HnO+ beyond the Gala…
Early results from the Herschel Space Observatory revealed the water cation H2O+ to be an abundant ingredient of the interstellar medium. Here we present new observations of the H2O and H2O+ lines at 1113.3 and 1115.2 GHz using the Herschel…
In diffuse interstellar clouds the chemistry that leads to the formation of the oxygen bearing ions OH+, H2O+, and H3O+ begins with the ionization of atomic hydrogen by cosmic rays, and continues through subsequent hydrogen abstraction…
The H3+ ion plays a key role in the chemistry of dense interstellar gas clouds where stars and planets are forming. The low temperatures and high extinctions of such clouds make direct observations of H3+ impossible, but lead to large…
The H3O+ molecule probes the oxygen chemistry and the ionization rate of dense circumnuclear gas in galaxies. In particular, recent H3O+ observations show variations in the cosmic-ray ionization rate by factors of $>$10 within our Galaxy.…
We model the production of OH+, H2O+, and H3O+ in interstellar clouds, using a steady state photodissociation region code that treats the freeze-out of gas species, grain surface chemistry, and desorption of ices from grains. The code…
We report the detection of absorption lines by the reactive ions OH+, H2O+ and H3O+ along the line of sight to the submillimeter continuum source G10.6$-$0.4 (W31C). We used the Herschel HIFI instrument in dual beam switch mode to observe…
The presence of H3+ in the interstellar medium was forecast almost four decades ago. Almost three decades ago it was asserted that its reactions with neutral molecular and atomic species directly lead to the production of many of the…
The H3+ and H2D+ ions are important probes of the physical and chemical conditions in regions of the interstellar medium where new stars are forming. This paper reviews how observations of these species and of heavier ions such as HCO+ and…
The formation of interstellar water has been commonly accepted to occur on the surfaces of icy dust grains in dark molecular clouds at low temperatures (10-20 K), involving hydrogenation reactions of oxygen allotropes. As a result of the…
This paper reviews recent observations of water in Galactic interstellar clouds and nearby galactic nuclei. Two results are highlighted: (1) Multi-line H$_2$O mapping of the Orion Bar shows that the water chemistry in PDRs is driven by…
The HDO/H2O abundance ratio is thought to be a key diagnostic on the evolution of water during the star- and planet-formation process and thus on its origin on Earth. We here present millimeter-wavelength high angular resolution…
(Abridged) We present Herschel/HIFI spectra of the H2O 1113 GHz and H2O+ 1115 GHz lines toward five nearby prototypical starburst/AGN systems, and OH+ 971 GHz spectra toward three of these. The beam size of 20" corresponds to resolutions…
Interstellar CO2 is an important reservoir of carbon and oxygen, and one of the major constituents of the icy mantles of dust grains, but it is not observable directly in the cold gas because has no permanent dipole moment. Its protonated…
Water is observed throughout the universe, from diffuse interstellar clouds to protoplanetary disks around young stars, and from comets in our own solar system and exoplanetary atmospheres to galaxies at high redshifts. This review…
We use the H3O+ molecule to investigate the impact of starburst and AGN activity on the chemistry of the molecular interstellar medium. Using the JCMT, we have observed the 3+_2 - 2-_2 364 GHz line of p-H3O+ towards the centers of seven…
The molecular species hydrogen peroxide, HOOH, is likely to be a key ingredient in the oxygen and water chemistry in the interstellar medium. Our aim with this investigation is to determine how abundant HOOH is in the cloud core {\rho} Oph…
Snowlines are key ingredients for planet formation. Providing observational constraints on the locations of the major snowlines is therefore crucial for fully connecting planet compositions to their formation mechanism. Unfortunately, the…
We report the detection of absorption by interstellar hydroxyl cations and water cations, along the sight-line to the bright continuum source W49N. We have used Herschel's HIFI instrument, in dual beam switch mode, to observe the 972 GHz N…
We combine Herschel observations of a total of 12 sources to construct the most uniform survey of HF and H2O in our Galactic disk. Both molecules are detected in absorption along all sight lines. The high spectral resolution of the…
Along several sight lines within the Milky Way ArH+ has been ubiquitously detected with only one detection in extragalactic environments, namely along two sight lines in the red shift z=0.89 absorber towards the lensed blazar PKS 1830-211.…