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Related papers: Confinement of knotted polymers in a slit

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We analyze static properties of a strongly confined semiflexible polymer, i.e. either trapped in a closed space or compressed by external forces, in an athermal solvent. Like a flexible polymer case, we can resort to an analogy with the…

Soft Condensed Matter · Physics 2009-11-13 Takahiro Sakaue

The role of the topology and its relation with the geometry of biopolymers under different physical conditions is a nontrivial and interesting problem. Aiming at understanding this issue for a related simpler system, we use Monte Carlo…

Statistical Mechanics · Physics 2009-10-22 Marco Baiesi , Enzo Orlandini , Stuart G. Whittington

In this paper the number and lengths of minimal length lattice knots confined to slabs of width $L$, is determined. Our data on minimal length verify the results by Sharein et.al. (2011) for the similar problem, expect in a single case,…

Soft Condensed Matter · Physics 2015-06-04 D. Gasumova , E. J. Janse van Rensburg , A. Rechnitzer

We present computer simulations to examine probability distributions of gyration radius for the no-thickness closed polymers of N straight segments of equal length. We are particularly interested in the conditional distributions when the…

Soft Condensed Matter · Physics 2007-05-23 N. T. Moore , R. Lua , A. Y. Grosberg

We investigate the effects of topological constraints (entanglements) on two dimensional polymer loops in the dense phase, and at the collapse transition (Theta point). Previous studies have shown that in the dilute phase the entangled…

Soft Condensed Matter · Physics 2009-11-10 Andreas Hanke , Ralf Metzler , Paul G. Dommersnes , Yacov Kantor , Mehran Kardar

Motivated by recent advances in single molecule manipulation techniques that enabled several groups to tie knots in individual polymer strands and to monitor their dynamics, we have used computer simulations to study "friction knots"…

Biological Physics · Physics 2007-05-23 Serdal Kirmizialtin , Dmitrii E. Makarov

Stochastic simulations are used to characterize the knotting distributions of random ring polymers confined in spheres of various radii. The approach is based on the use of multiple Markov chains and reweighting techniques, combined with…

Soft Condensed Matter · Physics 2009-11-11 C. Micheletti , D. Marenduzzo , E. Orlandini , D. W. Sumners

We employ computer simulations and thermodynamic integration to analyse the effects of bending rigidity and slit confinement on the free energy cost of tying knots, $\Delta F_{\rm knotting}$, on polymer chains under tension. A…

Soft Condensed Matter · Physics 2014-05-15 Peter Poier , Christos N. Likos , Richard Matthews

We report simulation results on melts of entangled linear polymers confined in a free-standing thin film. We study how the geometric constraints imposed by the confinement alter the entanglement state of the system compared to the…

Soft Condensed Matter · Physics 2019-03-06 Nicolás A. García , Jean-Louis Barrat

The (isothermic) compressibility of lattice knots can be examined as a model of the effects of topology and geometry on the compressibility of ring polymers. In this paper, the compressibility of minimal length lattice knots in the simple…

Soft Condensed Matter · Physics 2015-06-04 Esaias J Janse van Rensburg , Andrew Rechnitzer

Topological entanglements in polymers are mimicked by sliding rings (slip-links) which enforce pair contacts between monomers. We study the force-extension curve for linear polymers in which slip-links create additional loops of variable…

Statistical Mechanics · Physics 2009-11-07 Ralf Metzler , Yacov Kantor , Mehran Kardar

We present a computer simulation study of the compact self-avoiding loops as regards their length and topological state. We use a Hamiltonian closed path on the cubic-shaped segment of a 3D cubic lattice as a model of a compact polymer. The…

Soft Condensed Matter · Physics 2007-05-23 R. C. Lua , N. T. Moore , A. Yu. Grosberg

We discuss the entropy of a circular polymer under a topological constraint. We call it the {\it topological entropy} of the polymer, in short. A ring polymer does not change its topology (knot type) under any thermal fluctuations. Through…

Statistical Mechanics · Physics 2009-11-07 Miyuki K. Shimamura , Tetso Deguchi

We use computer simulations to compare the dynamical behaviour of torus and even-twist knots in polymers under tension. The knots diffuse through a mechanism similar to reptation. Their friction coefficients grow linearly with average knot…

Soft Condensed Matter · Physics 2010-07-27 R. Matthews , A. A. Louis , J. M. Yeomans

An extensive study of single block copolymer knots containing two kinds of monomers $A$ and $B$ is presented. The knots are in a solution and their monomers are subjected to short range interactions that can be attractive or repulsive. In…

Soft Condensed Matter · Physics 2016-04-08 Franco Ferrari

Topological constraints can affect both equilibrium and dynamic properties of polymer systems, and can play a role in the organization of chromosomes. Despite many theoretical studies, the effects of topological constraints on the…

Soft Condensed Matter · Physics 2014-12-12 Maxim Imakaev , Konstantin Tchourine , Sergei Nechaev , Leonid Mirny

Spontaneous formation of knots in long polymers at equilibrium is inevitable but becomes rare in sufficiently short chains. Here, we show that knotting and knot complexity increase by orders of magnitude in diblock polymers with a fraction…

Soft Condensed Matter · Physics 2024-07-11 Marin Vatin , Enzo Orlandini , Emanuele Locatelli

We revisit the classical problem of a polymer confined in a slit in both of its static and dynamic aspects. We confirm a number of well known scaling predictions and analyse their range of validity by means of comprehensive Molecular…

Nano-scale confinement of polymer in cone-shaped geometries occurs in many experimental situations. A flexible polymer confined in a cone-shaped nano-channel is studied theoretically and using molecular dynamics simulations. Distribution of…

Soft Condensed Matter · Physics 2016-02-24 Narges Nikoofard , Hossein Fazli

We probe the character of knotting in open, confined polymers, assigning knot types to open curves by identifying their projections as virtual knots. In this sense, virtual knots are transitional, lying in between classical knot types,…

Soft Condensed Matter · Physics 2020-01-29 Keith Alexander , Alexander J Taylor , Mark R Dennis