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We present a new method to solve the nuclear density functional theory (DFT) equations using a two-center harmonic oscillator for Skyrme-like functionals, incorporating pairing and Coulomb interactions. The goal is to efficiently determine…

Nuclear Theory · Physics 2025-07-08 Adrián Sánchez-Fernández , Jacek Dobaczewski , Xuwei Sun , Herlik Wibowo

A simple yet general method for constructing basis sets for molecular electronic structure calculations is presented. These basis sets consist of atomic natural orbitals from a multi-configurational self-consistent field calculation…

Materials Science · Physics 2015-05-19 F. R. Petruzielo , Julien Toulouse , C. J. Umrigar

We calculate complete basis set (CBS) limit extrapolated ionization potentials (IP) and electron affinities (EA) with Slater Type Basis sets for the molecules in the GW100 database. To this end, we present two new Slater Type orbital (STO)…

Chemical Physics · Physics 2021-07-14 Arno Förster , Lucas Visscher

The series expansion formulae are established for the one- and two-center charge densities over complete orthonormal sets of exponential type orbitals introduced by the author. Three-center overlap integrals of appearing in these relations…

Chemical Physics · Physics 2009-02-04 I. I. Guseinov

In a recent paper Ozdogan (Z. Naturforsch, 59a(2004)743) published formulas for evaluating the two-center overlap and nuclear attraction integrals over integer and noninteger Slater type orbitals. The purpose of this article is to point out…

Chemical Physics · Physics 2007-05-23 I. I. Guseinov

Quantum computation offers significant potential for accelerating the simulation of molecules and materials through algorithms such as quantum phase estimation (QPE). However, the expected speedup in ground-state energy estimation depends…

Quantum Physics · Physics 2025-06-17 Zhendong Li

An exponential interaction is constructed so that one-dimensional atoms and chains of atoms mimic the general behavior of their three-dimensional counterparts. Relative to the more commonly used soft-Coulomb interaction, the exponential…

Strongly Correlated Electrons · Physics 2016-03-07 Thomas E. Baker , E. Miles Stoudenmire , Lucas O. Wagner , Kieron Burke , Steven R. White

In the past decade, photoemission orbital tomography (POT) has evolved into a powerful tool to investigate the electronic structure of organic molecules adsorbed on surfaces. Here we show that POT allows for the comprehensive experimental…

We present a self-consistent electronic structure calculation method based on the {\it Exact Muffin-Tin Orbitals} (EMTO) Theory developed by O. K. Andersen, O. Jepsen and G. Krier (in {\it Lectures on Methods of Electronic Structure…

Materials Science · Physics 2007-05-23 L. Vitos , H. L. Skriver , B. Johansson , J. Kollár

A Monte Carlo method for evaluating multi-center two-electron-repulsion integrals over any type of orbitals (Slater, Sturmian, finite-range, numerical, etc.) is presented. The approach is based on a simple and universal…

Chemical Physics · Physics 2019-09-04 Michel Caffarel

Knowledge of the occupation ratio and the energy splitting of a two-level system yields a direct readout of its temperature. Based on this principle, the determination of the temperature of an individual two-level magnetic atom was…

Mesoscale and Nanoscale Physics · Physics 2024-10-10 Y. del Castillo , J. Fernández-Rossier

The tensor train approximation of electronic wave functions lies at the core of the QC-DMRG (Quantum Chemistry Density Matrix Renormalization Group) method, a recent state-of-the-art method for numerically solving the $N$-electron…

Numerical Analysis · Mathematics 2020-02-19 Mi-Song Dupuy , Gero Friesecke

Some typical overlap/potential energy integrals which occur in the use of extended Hylleraas-configuration interaction (E-Hy-CI) functions with Slater-type orbital (STO) basis for two-electron atomic structure calculations, have been…

Atomic Physics · Physics 2019-01-23 B Padhy

Starting from the second post-Keplerian (2PK) Hamiltonian describing the conservative part of the two-body dynamics in massless scalar-tensor (ST) theories, we build an effective-one-body (EOB) Hamiltonian which is a $\nu$-deformation…

General Relativity and Quantum Cosmology · Physics 2018-02-07 Félix-Louis Julié

On the basis of the multi-orbital dynamical mean field theory, a three-orbital Hubbard model with a relativistic spin-orbit coupling (SOC) is studied at five electrons per site. The numerical calculations are performed by employing the…

Strongly Correlated Electrons · Physics 2015-06-23 Toshihiro Sato , Tomonori Shirakawa , Seiji Yunoki

Complete waveform models able to account for arbitrary non-planar orbits represent a holy grail in current gravitational-wave astronomy. Here, we take a step towards this direction and present a simple yet efficient prescription to obtain…

General Relativity and Quantum Cosmology · Physics 2024-06-27 Rossella Gamba , Danilo Chiaramello , Sayan Neogi

We introduce an orbital dependent electron tunneling model and implement it within the atom superposition approach for simulating scanning tunneling microscopy (STM) and spectroscopy (STS). Applying our method, we analyze the convergence…

Materials Science · Physics 2012-12-20 Krisztián Palotás , Gábor Mándi , László Szunyogh

The problem of orbital relaxation in computational core-hole spectroscopies, including x-ray absorption and x-ray photoionization, has long plagued linear response approaches, including equation-of-motion coupled cluster with singles and…

Chemical Physics · Physics 2025-03-26 Megan E. Simons , Devin A. Matthews

Various properties of the general two-center two-electron integral over the explicitly correlated exponential function are analyzed for the potential use in high precision calculations for diatomic molecules. A compact one dimensional…

Chemical Physics · Physics 2015-06-11 Krzysztof Pachucki

Within the lowest-order relativistic approximation ($\sim v^2/c^2$) and to first order in $m_e/M$, the tensorial form of the relativistic corrections of the nuclear recoil Hamiltonian is derived, opening interesting perspectives for…

Atomic Physics · Physics 2015-05-28 E. Gaidamauskas , C. Nazé , P. Rynkun , G. Gaigalas , P. Jönsson , M. Godefroid